Anticorrosive and UV-blocking waterborne polyurethane composite coating containing novel two-dimensional Ti3C2 MXene nanosheets
Source abstract
Abstract
In this work, Ti3C2 MXene, a novel two-dimensional nanosheet, was introduced to waterborne polyurethane (WPU) coatings to prepare a composite coating. First, MAX phase materials were in situ etched by HF acid and further intercalated by water molecules to obtain exfoliated single-layer MXene nanosheet. And then, composite coatings were prepared via solution-blending low addition (0–0.4 wt%) of MXene, self-prepared waterborne polyacrylate emulsion (PAE) and isocyanate hardener, applying on Q235 mild steel. Results of AFM, XRD SEM and SEM–EDS confirm that single-layer MXene nanosheets with large lateral-to-thickness ratio are successfully prepared and achieved homogenous distribution within WPU matrix. With 0.4 wt% MXene incorporated, the WPU/Ti3C2 MXene composite coatings reach a lowest corrosion current of 2.143 × 10–6 A/cm2, a decrease of one order of magnitude compared with blank WPU (1.599 × 10–5 A/cm2) and own an excellent UV-blocking property (almost block the whole UV light).
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: MXene and MAX Phase Materials · Advanced Sensor and Energy Harvesting Materials · Dendrimers and Hyperbranched Polymers
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (46)
Show source-provided references
1. Xie Y, Chen M, Xie D, Zhong L, Zhang X (2017) A fast, low temperature zinc phosphate coating on steel accelerated by graphene oxide. Corros Sci 128:1–8. https://doi.org/10.1016/j.corsci.2017.08.03310.1016/j.corsci.2017.08.033 ↗
2. Geethanjali R, Subhashini S (2016) Synthesis of water-soluble acryl terpolymers and their anticorrosion properties on mild steel in 1mol·L−1 HCl. Chin J Chem Eng 24:543–552. https://doi.org/10.1016/j.cjche.2015.11.01910.1016/j.cjche.2015.11.019 ↗
3. Qian B, Zheng Z, Michailids M, Fleck N, Bilton M, Song Y, Li G, Shchukin D (2019) Mussel-inspired self-healing coatings based on polydopamine-coated nanocontainers for corrosion protection. ACS Appl Mater Interfaces 11:10283–10291. https://doi.org/10.1021/acsami.8b2119710.1021/acsami.8b21197 ↗
4. Yang N, Yang T, Wang W, Chen H, Li W (2019) Polydopamine modified polyaniline-graphene oxide composite for enhancement of corrosion resistance. J Hazard Mater 377:142–151. https://doi.org/10.1016/j.jhazmat.2019.05.06310.1016/j.jhazmat.2019.05.063 ↗
5. Habibiyan A, Ramezanzadeh B, Mahdavian M, Bahlakeh G, Kasaeian M (2020) Rational assembly of mussel-inspired polydopamine (PDA)-Zn (II) complex nanospheres on graphene oxide framework tailored for robust self-healing anti-corrosion coatings application. Chem Eng J 391:123630. https://doi.org/10.1016/j.cej.2019.12363010.1016/j.cej.2019.123630 ↗
6. Asaldoust S, Ramezanzadeh B (2020) Synthesis and characterization of a high-quality nanocontainer based on benzimidazole-zinc phosphate (ZP-BIM) tailored graphene oxides; a facile approach to fabricating a smart self-healing anti-corrosion system. J Colloid Interface Sci 564:230–244. https://doi.org/10.1016/j.jcis.2019.12.12210.1016/j.jcis.2019.12.122 ↗
7. Huang H, Wang H, Xie Y, Dong D, Jiang X, Zhang X (2019) Incorporation of boron nitride nanosheets in zinc phosphate coatings on mild steel to enhance corrosion resistance. Surf Coat Technol 374:935–943. https://doi.org/10.1016/j.surfcoat.2019.06.08210.1016/j.surfcoat.2019.06.082 ↗
8. Taheri NN, Ramezanzadeh B, Mahdavian M (2019) Application of layer-by-layer assembled graphene oxide nanosheets/polyaniline/zinc cations for construction of an effective epoxy coating anti-corrosion system. J Alloys Compd 800:532–549. https://doi.org/10.1016/j.jallcom.2019.06.10310.1016/j.jallcom.2019.06.103 ↗
9. Wang H, Guo R, Shen Y, Shao Y, Fei G, Zhu K (2019) Waterborne polyaniline-graft-alkyd for anticorrosion coating and comparison study with physical blend. Prog Org Coat 126:187–195. https://doi.org/10.1016/j.porgcoat.2018.10.01310.1016/j.porgcoat.2018.10.013 ↗
10. Wu Y, He Y, Zhou T, Chen C, Zhong F, Xia Y, Xie P, Zhang C (2020) Synergistic functionalization of h-BN by mechanical exfoliation and PEI chemical modification for enhancing the corrosion resistance of waterborne epoxy coating. Prog Org Coat 142:105541. https://doi.org/10.1016/j.porgcoat.2020.10554110.1016/j.porgcoat.2020.105541 ↗
11. Huang H, Sheng X, Tian Y, Zhang L, Chen Y, Zhang X (2020) Two-dimensional nanomaterials for anticorrosive polymeric coatings: a review. Ind Eng Chem Res 59:15424–15446. https://doi.org/10.1021/acs.iecr.0c0287610.1021/acs.iecr.0c02876 ↗
12. Li J, Gan L, Liu Y, Mateti S, Lei W, Chen Y, Yang J (2018) Boron nitride nanosheets reinforced waterborne polyurethane coatings for improving corrosion resistance and antifriction properties. Eur Polym J 104:57–63. https://doi.org/10.1016/j.eurpolymj.2018.04.04210.1016/j.eurpolymj.2018.04.042 ↗
13. Haladu SA, Umoren SA, Ali SA, Solomon MM, Mohammed A-RI (2019) Synthesis, characterization and electrochemical evaluation of anticorrosion property of a tetrapolymer for carbon steel in strong acid media. Chin J Chem Eng 27:965–978. https://doi.org/10.1016/j.cjche.2018.07.01510.1016/j.cjche.2018.07.015 ↗
14. Cai K, Zuo S, Luo S, Yao C, Liu W, Ma J, Mao H, Li Z (2016) Preparation of polyaniline/graphene composites with excellent anti-corrosion properties and their application in waterborne polyurethane anticorrosive coatings. RSC Adv 6:95965–95972. https://doi.org/10.1039/C6RA19618G10.1039/C6RA19618G ↗
15. Mohammadi A, Barikani M, Doctorsafaei AH, Isfahani AP, Shams E, Ghalei B (2018) Aqueous dispersion of polyurethane nanocomposites based on calix[4]arenes modified graphene oxide nanosheets: preparation, characterization, and anti-corrosion properties. Chem Eng J 349:466–480. https://doi.org/10.1016/j.cej.2018.05.11110.1016/j.cej.2018.05.111 ↗
16. Wang H, He Y, Fei G, Wang C, Shen Y, Zhu K, Sun L, Rang N, Guo D, Wallace GG (2019) Functionalizing graphene with titanate coupling agents as reinforcement for one-component waterborne poly(urethane-acrylate) anticorrosion coatings. Chem Eng J 359:331–343. https://doi.org/10.1016/j.cej.2018.11.13310.1016/j.cej.2018.11.133 ↗
17. Huang T-C, Lai G-H, Li C-E, Tsai M-H, Wan P-Y, Chung Y-H, Lin M-H (2017) Advanced anti-corrosion coatings prepared from α-zirconium phosphate/polyurethane nanocomposites. RSC Adv 7:9908–9913. https://doi.org/10.1039/C6RA27588E10.1039/C6RA27588E ↗
18. Mo Q, Li W, Yang H, Gu F, Chen Q, Yang R (2019) Water resistance and corrosion protection properties of waterborne polyurethane coating enhanced by montmorillonite modified with Ce3+. Prog Org Coat 136:105213. https://doi.org/10.1016/j.porgcoat.2019.10521310.1016/j.porgcoat.2019.105213 ↗
19. Javidparvar AA, Naderi R, Ramezanzadeh B (2019) Epoxy-polyamide nanocomposite coating with graphene oxide as cerium nanocontainer generating effective dual active/barrier corrosion protection. Compos B 172:363–375. https://doi.org/10.1016/j.compositesb.2019.05.05510.1016/j.compositesb.2019.05.055 ↗
20. Ye Y, Zhang D, Liu T, Liu Z, Pu J, Liu W, Zhao H, Li X, Wang L (2019) Superior corrosion resistance and self-healable epoxy coating pigmented with silanzied trianiline-intercalated graphene. Carbon 142:164–176. https://doi.org/10.1016/j.carbon.2018.10.05010.1016/j.carbon.2018.10.050 ↗
21. Huang H, Li M, Tian Y, Xie Y, Sheng X, Jiang X, Zhang X (2020) Exfoliation and functionalization of α-zirconium phosphate in one pot for waterborne epoxy coatings with enhanced anticorrosion performance. Prog Org Coat 138:105390. https://doi.org/10.1016/j.porgcoat.2019.10539010.1016/j.porgcoat.2019.105390 ↗
22. Xia Z, Liu G, Dong Y, Zhang Y (2019) Anticorrosive epoxy coatings based on polydopamine modified molybdenum disulfide. Prog Org Coat 133:154–160. https://doi.org/10.1016/j.porgcoat.2019.04.05610.1016/j.porgcoat.2019.04.056 ↗
23. Zhang C, He Y, Li F, Di H, Zhang L, Zhan Y (2016) h-BN decorated with Fe3O4 nanoparticles through mussel-inspired chemistry of dopamine for reinforcing anticorrosion performance of epoxy coatings. J Alloys Compd 685:743–751. https://doi.org/10.1016/j.jallcom.2016.06.22010.1016/j.jallcom.2016.06.220 ↗
24. Naguib M, Kurtoglu M, Presser V, Lu J, Niu J, Heon M, Hultman L, Gogotsi Y, Barsoum MW (2011) Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv Mater 23:4248–4253. https://doi.org/10.1002/adma.20119014710.1002/adma.201190147 ↗
25. Huang H, Dong D, Li W, Zhang X, Zhang L, Chen Y, Sheng X, Lu X (2020) Synergistic effect of MXene on the flame retardancy and thermal degradation of intumescent flame retardant biodegradable poly (lactic acid) composites. Chin J Chem Eng 28:1981–1993. https://doi.org/10.1016/j.cjche.2020.04.01410.1016/j.cjche.2020.04.014 ↗
26. Sun R, Zhang HB, Liu J, Xie X, Yang R, Li Y, Hong S, Yu ZZ (2017) Highly conductive transition metal carbide/carbonitride (MXene)@polystyrene nanocomposites fabricated by electrostatic assembly for highly efficient electromagnetic interference shielding. Adv Funct Mater 27:1702807. https://doi.org/10.1002/adfm.20170280710.1002/adfm.201702807 ↗
27. Wang L, Chen L, Song P, Liang C, Lu Y, Qiu H, Zhang Y, Kong J, Gu J (2019) Fabrication on the annealed Ti3C2Tx MXene/Epoxy nanocomposites for electromagnetic interference shielding application. Compos B 171:111–118. https://doi.org/10.1016/j.compositesb.2019.04.05010.1016/j.compositesb.2019.04.050 ↗
28. Yan H, Li W, Li H, Fan X, Zhu M (2019) Ti3C2 MXene nanosheets toward high-performance corrosion inhibitor for epoxy coating. Prog Org Coat 135:156–167. https://doi.org/10.1016/j.porgcoat.2019.06.01310.1016/j.porgcoat.2019.06.013 ↗
29. Zou Y, Fang L, Chen T, Sun M, Lu C, Xu Z (2018) Near-Infrared light and solar light activated self-healing epoxy coating having enhanced properties using MXene flakes as multifunctional fillers. Polymers 10:474. https://doi.org/10.3390/polym1005047410.3390/polym10050474 ↗
30. Lin P, Xie J, He Y, Lu X, Li W, Fang J, Yan S, Zhang L, Sheng X, Chen Y (2020) MXene aerogel-based phase change materials toward solar energy conversion. Sol Energy Mater Sol Cells 206:110229. https://doi.org/10.1016/j.solmat.2019.11022910.1016/j.solmat.2019.110229 ↗
31. Sheng X, Zhao Y, Zhang L, Lu X (2019) Properties of two-dimensional Ti3C2 MXene/thermoplastic polyurethane nanocomposites with effective reinforcement via melt blending. Compos Sci Technol 181:107710. https://doi.org/10.1016/j.compscitech.2019.10771010.1016/j.compscitech.2019.107710 ↗
32. Zeng W, Huang H, Song L, Jiang X, Zhang X (2020) A novel hydroxyl polyacrylate latex modified by OvPOSS and its application in two-component waterborne polyurethane coatings. J Coat Technol Res 17:181–191. https://doi.org/10.1007/s11998-019-00256-910.1007/s11998-019-00256-9 ↗
33. Wang C, Sheng X, Xie D, Zhang X, Zhang H (2016) High-performance TiO2/polyacrylate nanocomposites with enhanced thermal and excellent UV-shielding properties. Prog Org Coat 101:597–603. https://doi.org/10.1016/j.porgcoat.2016.10.00710.1016/j.porgcoat.2016.10.007 ↗
34. Sheng X, Xie D, Wang C, Zhang X, Zhong L (2016) Synthesis and characterization of core/shell titanium dioxide nanoparticle/polyacrylate nanocomposite colloidal microspheres. Colloid Polym Sci 294:463–469. https://doi.org/10.1007/s00396-015-3807-110.1007/s00396-015-3807-1 ↗
35. Riazi H, Anayee M, Hantanasirisakul K, Shamsabadi AA, Anasori B, Gogotsi Y, Soroush M (2020) Surface modification of a MXene by an aminosilane coupling agent. Adv Mater Interfaces 7:1902008. https://doi.org/10.1002/admi.20190200810.1002/admi.201902008 ↗
36. Quain E, Mathis TS, Kurra N, Maleski K, Van Aken KL, Alhabeb M, Alshareef HN, Gogotsi Y (2019) Direct writing of additive-free MXene-in-water ink for electronics and energy storage. Adv Mater Technol 4:1800256. https://doi.org/10.1002/admt.20180025610.1002/admt.201800256 ↗
37. Naguib M, Unocic RR, Armstrong BL, Nanda J (2015) Large-scale delamination of multi-layers transition metal carbides and carbonitrides “MXenes.” Dalton Trans 44:9353–9358. https://doi.org/10.1039/c5dt01247c10.1039/c5dt01247c ↗
38. Chen G, Guan X, Xu R, Tian J, He M, Shen W, Yang J (2016) Synthesis and characterization of UV-curable castor oil-based polyfunctional polyurethane acrylate via photo-click chemistry and isocyanate polyurethane reaction. Prog Org Coat 93:11–16. https://doi.org/10.1016/j.porgcoat.2015.12.01510.1016/j.porgcoat.2015.12.015 ↗
39. Lin P, Meng L, Huang Y, Liu L, Fan D (2015) Simultaneously functionalization and reduction of graphene oxide containing isocyanate groups. Appl Surf Sci 324:784–790. https://doi.org/10.1016/j.apsusc.2014.11.03810.1016/j.apsusc.2014.11.038 ↗
40. Parhizkar N, Ramezanzadeh B, Shahrabi T (2018) Corrosion protection and adhesion properties of the epoxy coating applied on the steel substrate pre-treated by a sol-gel based silane coating filled with amino and isocyanate silane functionalized graphene oxide nanosheets. Appl Surf Sci 439:45–59. https://doi.org/10.1016/j.apsusc.2017.12.24010.1016/j.apsusc.2017.12.240 ↗
41. Huang H, Du Z, Huang X, Jiang X, Zhang X (2020) Development of enhanced multiwalled carbon nanotube (MWCNT) conductive polymeric nanocomposites by using acidified derivative of MWCNT as dispersant. J Appl Phys 127:035501. https://doi.org/10.1063/1.513065110.1063/1.5130651 ↗
42. Cui J, Xu J, Li J, Qiu H, Zheng S, Yang J (2020) A crosslinkable graphene oxide in waterborne polyurethane anticorrosive coatings: experiments and simulation. Compos B 188:107889. https://doi.org/10.1016/j.compositesb.2020.10788910.1016/j.compositesb.2020.107889 ↗
43. Amrollahi S, Ramezanzadeh B, Yari H, Ramezanzadeh M, Mahdavian M (2019) Synthesis of polyaniline-modified graphene oxide for obtaining a high performance epoxy nanocomposite film with excellent UV blocking/anti-oxidant/anti-corrosion capabilities. Compos B 173:106804. https://doi.org/10.1016/j.compositesb.2019.05.01510.1016/j.compositesb.2019.05.015 ↗
44. Karthika M, Chi H, Li T, Wang H, Thomas S (2019) Super-hydrophobic graphene oxide-azobenzene hybrids for improved hydrophobicity of polyurethane. Compos B 173:106978. https://doi.org/10.1016/j.compositesb.2019.10697810.1016/j.compositesb.2019.106978 ↗
45. Huang H, Huang X, Xie Y, Tian Y, Jiang X, Zhang X (2019) Fabrication of h-BN-rGO@PDA nanohybrids for composite coatings with enhanced anticorrosion performance. Prog Org Coat 130:124–131. https://doi.org/10.1016/j.porgcoat.2019.01.05910.1016/j.porgcoat.2019.01.059 ↗
46. Tian Y, Xie Y, Dai F, Huang H, Zhong L, Zhang X (2020) Ammonium-grafted graphene oxide for enhanced corrosion resistance of waterborne epoxy coatings. Surf Coat Technol 383:125227. https://doi.org/10.1016/j.surfcoat.2019.12522710.1016/j.surfcoat.2019.125227 ↗