Capture and reversible storage of volatile iodine by porous carbon with high capacity
Source abstract
Abstract
The capture of iodine using porous materials has attracted considerable interest. In this work, porous carbon with a special surface area of 1973 m2 g−1 was prepared by simple activation method. As an adsorbent, the adsorption capacity of the resulting porous carbon could reach up to 376 wt% for iodine vapor and 460 mg g−1 for iodine uptake in cyclohexane, which both are among the highest values reported up to now. Taking advantages of its high special surface area, easy preparation, low cost, as well as good regeneration, the resulting porous carbon shows great potential in the removal of radioactive iodine at different states.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Membrane Separation and Gas Transport
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (33)
Show source-provided references
1. Ewing RC, von Hippel FN (2009) Nuclear waste management in the United States—starting over. Science 325:151–15210.1126/science.1174594 ↗
2. Sigen A, Zhang Y, Li Z, Xia H, Xue M, Liu X, Mu Y (2014) Highly efficient and reversible iodine capture using a metalloporphyrin-based conjugated microporous polymer. Chem Commun 50:8495–849810.1039/C4CC01783H ↗
3. Sava DF, Rodriguez MA, Chapman KW, Chupas PJ, Greathouse JA, Crozier PS, Nenoff TM (2011) Capture of volatile iodine, a gaseous fission product, by zeolitic imidazolate framework-8. J Am Chem Soc 133:12398–1240110.1021/ja204757x ↗
4. Riley BJ, Chun J, Ryan JV, Matyáš J, Li XS, Matson DW, Sundaram SK, Strachan DM, Vienna JD (2011) Chalcogen-based aerogels as a multifunctional platform for remediation of radioactive iodine. RSC Adv 1:1704–171510.1039/c1ra00351h ↗
5. Chapman KW, Chupas PJ, Nenoff TM (2010) Radioactive iodine capture in silver-containing mordenites through nanoscale silver iodide formation. J Am Chem Soc 132:8897–889910.1021/ja103110y ↗
6. Liu Q, Ma J, Dong Y (2011) Highly efficient iodine species enriching and guest-driven tunable luminescent properties based on a cadmium(II)-triazole MOF. Chem Commun 47:7185–718710.1039/c1cc11402f ↗
7. Huang P, Kuo C, Hsieh C, Horng Y (2012) Selective capture of volatile iodine using amorphous molecular organic solids. Chem Commun 48:3227–322910.1039/c2cc17716a ↗
8. Zeng M, Wang Q, Tan Y, Hu S, Zhao H, Long L, Kurmoo M (2010) Rigid pillars and double walls in a porous metal-organic framework: single-crystal to single-crystal, controlled uptake and release of iodine and electrical conductivity. J Am Chem Soc 132:2561–256310.1021/ja908293n ↗
9. Yin Z, Wang Q, Zeng M (2012) Iodine release and recovery, influence of polyiodide anions on electrical conductivity and nonlinear optical activity in an interdigitated and interpenetrated bipillared-bilayer metal-organic framework. J Am Chem Soc 134:4857–486310.1021/ja211381e ↗
10. Yu F, Li D, Cheng L, Yin Z, Zeng M, Kurmoo M (2015) Porous supramolecular networks constructed of one-dimensional metal-organic chains: carbon dioxide and iodine capture. Inorg Chem 54:1655–166010.1021/ic502650z ↗
11. Sun F, Yin Z, Wang Q, Sun D, Zeng M, Kurmoo M (2013) Tandem postsynthetic modification of a metal-organic framework by thermal elimination and subsequent bromination: effects on absorption properties and photoluminescence. Angew Chem Int Ed 52:4538–454310.1002/anie.201300821 ↗
12. Tom H, Schmidtmann M, Cooper AI (2011) Molecular doping of porous organic cages. J Am Chem Soc 133:14920–1492310.1021/ja205969q ↗
13. Chen Y, Sun H, Yang R, Wang T, Pei C, Xiang Z, Zhu Z, Liang W, Li A, Deng W (2015) Synthesis of conjugated microporous polymer nanotubes with large surface areas as absorbents for iodine and CO2 uptake. J Mater Chem A 3:87–9110.1039/C4TA04235B ↗
14. Chien C-C, Huang Y-P, Wang W-C, Chao J-H, Wei Y-Y (2011) Efficiency of moso bamboo charcoal and activated carbon for adsorbing radioactive iodine. Clean Soil Air Water 39:103–10810.1002/clen.201000012 ↗
15. Zhou J, Hao S, Gao L, Zhang Y (2014) Study on adsorption performance of coal based activated carbon to radioactive iodine and stable iodine. Ann Nucl Energy 72:237–24110.1016/j.anucene.2014.05.028 ↗
16. Mianowski A, Owczarek M, Marecka A (2007) Surface area of activated carbon determined by the iodine adsorption number. Energy Sources Part A 29:839–85010.1080/00908310500430901 ↗
17. Raipur B, Bansal RC (1965) Iodine adsorption method for measuring surface area of carbon blacks. Carbon 3:227–30010.1016/0008-6223(65)90055-2 ↗
18. González-García CM, González JF, Román S (2011) Removal efficiency of radioactive methyl iodide on TEDA-impregnated activated carbons. Fuel Process Technol 92:247–25210.1016/j.fuproc.2010.04.014 ↗
19. Wang H, Gao Q, Hu J (2009) High hydrogen storage capacity of porous carbons prepared by using activated carbon. J Am Chem Soc 131:7016–702210.1021/ja8083225 ↗
20. Wang R, Wang P, Yan X, Lang J, Peng C, Xue Q (2012) Promising porous carbon derived from celtuce leaves with outstanding supercapacitance and CO2 capture performance. ACS Appl Mater Interfaces 4:5800–580610.1021/am302077c ↗
21. Sun H, Li A, Zhu Z, Liang W, Zhao X, La P, Deng W (2013) Superhydrophobic activated carbon-coated sponges for separation and absorption. ChemSusChem 6:1057–106210.1002/cssc.201200979 ↗
22. Liu Y, Xue JS, Zheng T, Dahn JR (1996) Mechanism of lithium insertion in hard carbons prepared by pyrolysis of epoxy resins. Carbon 34:193–20010.1016/0008-6223(96)00177-7 ↗
23. Cuesta A, Dhamelincourt P, Laureyns J, Martinez-Alonso A, Tascon JMD (1994) Raman microprobe studies on carbon materials. Carbon 32:1523–153210.1016/0008-6223(94)90148-1 ↗
24. Pimenta MA, Dresselhaus G, Dresselhaus MS, Cancado LG, Jorio A, Saito R (2007) Studying disorder in graphite-based systems by Raman spectroscopy. Phys Chem Chem Phys 9:1276–129110.1039/B613962K ↗
25. Dresselhaus MS, Jorio A, Hofmann M, Dresselhaus G, Saito R (2010) Perspectives on carbon nanotubes and graphene Raman spectroscopy. Nano Lett 10:751–75810.1021/nl904286r ↗
26. Li M, Liu C, Cao H, Zhao H, Zhang Y, Fan Z (2014) KOH self-templating synthesis of three-dimensional hierarchical porous carbon materials for high performance supercapacitors. J Mater Chem A 2:14844–1485110.1039/C4TA02167C ↗
27. Qu D (2008) Investigation of hydrogen physisorption active sites on the surface of porous carbonaceous materials. Chem Eur J 14:1040–104610.1002/chem.200701042 ↗
28. Yu J, Gu M, Bian C, Xu X, Tang TB (2013) An impedance spectroscopy study of the rotation and reorientation of water molecules in hydrated graphite. Carbon 61:367–37210.1016/j.carbon.2013.05.018 ↗
29. Qin H, Gao P, Wang F, Zhao L, Zhu J, Wang A, Zhang T, Wu R, Zou H (2011) Highly efficient extraction of serum peptides by ordered mesoporous carbon. Angew Chem Int Ed 50:12218–1222110.1002/anie.201103666 ↗
30. Choi M, Ryoo R (2007) Mesoporous carbons with KOH activated framework and their hydrogen adsorption. J Mater Chem 17:4204–420910.1039/b704104g ↗
31. Zhu Y, Murali S, Stoller MD, Ganesh KJ, Cai W, Ferreira PJ, Pirkle A, Wallace RM, Cychosz KA, Thommes M, Su D, Stach EA, Ruoff RS (2011) Carbon-based supercapacitors produced by activation of graphene. Science 332:1537–154110.1126/science.1200770 ↗
32. Raymundo-Piñeroa E, Azaïs P, Cacciaguerra T, Cazorla-Amorós D, Linares-Solano A, Béguin F (2005) KOH and NaOH activation mechanisms of multiwalled carbon nanotubes with different structural organization. Carbon 43:786–79510.1016/j.carbon.2004.11.005 ↗
33. Portet C, Lillo-Ródenas MÁ, Linares-Solano A, Gogotsi Y (2009) Capacitance of KOH activated carbide-derived carbons. Phys Chem Chem Phys 11:4943–494510.1039/b816514a ↗