journal article·2020-05

Metal/metal oxide decorated graphene synthesis and application as supercapacitor: a review

Debabrata Nandi, Velram Balaji Mohan, Anil K. Bhowmick, Debes Bhattacharyya

Journal of Materials Science· Volume 55· Issue 15
Publisher page

Abstract

Metal/metal oxides and conductive polymers are common supercapacitor electrode materials, revealing high power density as well as long cycle life. In composites, graphene and metal oxides displayed the combination of the excellent cycle stability of graphene and the high-capacity properties of metal oxides which remarkably improve the comprehensive properties of nanocomposites. The current developments of metal/metal oxide decorated graphene (MGr) composites in the field of electrochemical capacitors are elucidated here on account of their synergistic properties. It is demonstrated that, in comparison with their individual influences, MGr composites have attained substantial improvement in rate capability, capacity, and cycling stability. Mainly, an overview of the characteristics, preparation approaches, and application of graphene (Gr) is outlined. Mechanism of different types of electrochemical capacitance is described explicitly. Finally, the future prospects and challenges of MGr composites have been discussed for energy storage.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advancements in Battery Materials · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Choi W, Lahiri I, Seelaboyina R et al (2010) Synthesis of graphene and its applications: a review. Crit Rev Solid State Mater Sci 35:52–7110.1080/10408430903505036 ↗
2. Wang HL, Casalongue HS, Liang YY et al (2010) Ni(OH)2 nanoplates grown on graphene as advanced electrochemical pseudocapacitor materials. J Am Chem Soc 132:7472–747710.1021/ja102267j ↗
3. Sengupta R, Bhattacharya M, Bhowmick AK et al (2011) A review on the mechanical and electrical properties of graphite and modified graphite reinforced polymer composites. Prog Polym Sci 36:638–67010.1016/j.progpolymsci.2010.11.003 ↗
4. Min S, Zhao C, Chen G et al (2014) One-pot hydrothermal synthesis of reduced graphene oxide/Ni(OH)2 films on nickel foam for high performance supercapacitors. Electrochim Acta 115:155–16410.1016/j.electacta.2013.10.140 ↗
5. Li L, Seng KH, Liu H et al (2013) Synthesis of Mn3O4-anchored graphene sheet nanocomposites via a facile, fast microwave hydrothermal method and their supercapacitive behavior. Electrochim Acta 87:801–80810.1016/j.electacta.2012.08.127 ↗
6. Zhu JW, Chen S, Zhou H et al (2012) Fabrication of a low defect density graphene-nickel hydroxide nanosheet hybrid with enhanced electrochemical performance. Nano Res 5:11–1910.1007/s12274-011-0179-9 ↗
7. Li D, Liu Y, Lin B et al (2015) Graphene/metal oxide composites as electrode material for supercapacitors. Prog Chem 27:404–415
8. Chen S, Duan JJ, Jaroniec M et al (2013) Hierarchically porous graphene-based hybrid electrodes with excellent electrochemical performance. J Mater Chem A 1:9409–941310.1039/c3ta00133d ↗
9. Zhang HT, Zhang X, Zhang DC et al (2013) One-step electrophoretic deposition of reduced graphene oxide and Ni(OH)2 composite films for controlled syntheses supercapacitor electrodes. J Phys Chem B 117:1616–162710.1021/jp305198j ↗
10. Wang B, Park J, Wang CY et al (2010) Mn3O4 nanoparticles embedded into graphene nanosheets: Preparation, characterization, and electrochemical properties for supercapacitors. Electrochim Acta 55:6812–681710.1016/j.electacta.2010.05.086 ↗
11. Rakhi RB, Chen W, Cha D et al (2011) High performance supercapacitors using metal oxide anchored graphene nanosheet electrodes. J Mater Chem 21:16197–1620410.1039/c1jm12963e ↗
12. Wang HW, Hu ZA, Chang YQ (2010) Facile solvothermal synthesis of a graphene nanosheet–bismuth oxide composite and its electrochemical characteristics. Electrochim Acta 55:8974–898010.1016/j.electacta.2010.08.048 ↗
13. Liu CL, Chang KH, Hu CC et al (2012) Microwave-assisted hydrothermal synthesis of Mn3O4/reduced graphene oxide composites for high power supercapacitors. J Power Sour 217:184–19210.1016/j.jpowsour.2012.05.109 ↗
14. Pendashteh A, Mousavi MF, Rahmanifar MS (2013) Fabrication of anchored copper oxide nanoparticles on graphene oxide nanosheets via an electrostatic coprecipitation and its application as supercapacitor. Electrochim Acta 88:347–35710.1016/j.electacta.2012.10.088 ↗
15. Xia XH, Chao D, Fan ZX et al (2014) A new type of porous graphite foams and their integrated composites with oxide/polymer core/shell nanowires for supercapacitors: structural design, fabrication, and full supercapacitor demonstrations. Nano Lett 14:1651–165810.1021/nl5001778 ↗
16. Lee JS, Lee C, Jun J et al (2014) A metal-oxide nanofiber-decorated three-dimensional graphene hybrid nanostructured flexible electrode for high-capacity electrochemical capacitors. J Mater Chem A 2:11922–1192910.1039/C4TA01695E ↗
17. Huang Y, Liang JJ, Chen YS (2012) An overview of the applications of graphene-based materials in supercapacitors. Small 8:1805–183410.1002/smll.201102635 ↗
18. Tan YB, Lee JM (2013) Graphene for supercapacitor applications. J Mater Chem A 1:14814–1484310.1039/c3ta12193c ↗
19. Meyyappan M (2013) Nanostructured materials for supercapacitors. J Vac Sci Technol, A 31:05080310.1116/1.4802772 ↗
20. Zhu LX, Zhang S, Cui YH et al (2013) One step synthesis and capacitive performance of graphene nanosheets/Mn3O4 composite. Electrochim Acta 89:18–2310.1016/j.electacta.2012.10.157 ↗
21. Roy N, Sengupta R, Bhowmick AK (2012) Modifications of carbon for polymer composites and nanocomposites. Prog Polym Sci 37:781–81910.1016/j.progpolymsci.2012.02.002 ↗
22. Xiao Y, Huanga L, Zhang Q et al (2015) Gravure printing of hybrid MoS2@S-rGO interdigitated electrodes for flexible microsupercapacitors. Appl Phys Lett 107:013906
23. Mondal T, Bhowmick AK, Krishnamoorti R et al (2014) Butyl lithium assisted direct grafting of polyoligomeric silsesquioxane onto grapheme. RSC Adv 4:8649–865610.1039/c3ra47373b ↗
24. Purushothaman KK, Saravanakumar B, Babu IM et al (2014) Nanostructured CuO/reduced graphene oxide composite for hybrid supercapacitors. RSC Adv 4:23485–2349110.1039/c4ra02107j ↗
25. Ejigu A, Fujisawa K, Spencer BF et al (2018) On the role of transition metal salts during electrochemical exfoliation of graphite: antioxidants or metal oxide decorators for energy storage applications. Adv Funct Mater 28:1804357(1-12)10.1002/adfm.201804357 ↗
26. Liu Y, Ying YL, Mao YY et al (2013) CuO nanosheets/rGO hybrid lamellar films with enhanced capacitance. Nanoscale 5:9134–914010.1039/c3nr02737f ↗
27. Chen S, Xing W, Duan JJ (2013) Nanostructured morphology control for efficient supercapacitor electrodes. J Mater Chem A 1:2941–295410.1039/C2TA00627H ↗
28. Liu Z, Zhao Z, Miyauch M (2009) Efficient visible light active CaFe2O4/WO3 based composite photocatalysts: effect of interfacial modification. J Phys Chem C 113:17132–1713710.1021/jp906195f ↗
29. Wei W, Cui X, Chen W et al (2011) Manganese oxide-based materials as electrochemical supercapacitor electrodes. Chem Soc Rev 40:1697–172110.1039/C0CS00127A ↗
30. Stankovich S, Dikin DA, Dommett GHB et al (2006) Graphene-based composite materials. Nature 442:282–28610.1038/nature04969 ↗
31. Senthilkumar B, Khan Z, Park S et al (2015) Highly porous graphitic carbon and Ni2P2O7 for a high performance aqueous hybrid supercapacitor. J Mater Chem A 3:21553–2156110.1039/C5TA04737D ↗
32. Burt R, Birkett G, Zhao XS (2014) A review of molecular modelling of electric double layer capacitors. Phys Chem Chem Phys 16:6519–653810.1039/c3cp55186e ↗
33. Chen S, Liu Y, Chen J (2014) Heterogeneous electron transfer at nanoscopic electrodes: importance of electronic structures and electric double layers. Chem Soc Rev 43:5372–538610.1039/C4CS00087K ↗
34. Zheng X, Luo J, Lv W et al (2015) Two-dimensional porous carbon: synthesis and ion-transport properties. Adv Mater 27:525410.1002/adma.201570238 ↗
35. Simon P, Gogotsi Y (2012) Capacitive energy storage in nanostructured carbon–electrolyte systems. Acc Chem Res 46:1094–110310.1021/ar200306b ↗
36. Chee WK, Lim HN, Zainal Z (2016) Flexible graphene based supercapacitors: a review. J Phys Chem C 120:4153–417210.1021/acs.jpcc.5b10187 ↗
37. Ke Q, Wang J (2016) Graphene-based materials for supercapacitor electrodes—a review. J Materiom 2:37–5410.1016/j.jmat.2016.01.001 ↗
38. Brousse T, Belanger D, Long JW (2015) To be or not to be pseudocapacitive? J Electrochem Soc 162(5):A5185–A518910.1149/2.0201505jes ↗
39. DeSouza VRH, Oliveira MM, Zarbin AJG (2014) Thin and flexible all-solid supercapacitor prepared from novel single wall carbon nanotubes/polyaniline thin films obtained in liquid–liquid interfaces. J Power Sour 260:34–4210.1016/j.jpowsour.2014.02.070 ↗
40. Li Z, Xu Z, Tan X et al (2014) Colossal pseudocapacitance in a high functionality-high surface area carbon anode doubles the energy of an asymmetric supercapacitor. Energy Environ Sci 7:1708–171810.1039/C3EE43979H ↗
41. Chen X, Wang H, Yi H et al (2014) Anthraquinone on porous carbon nanotubes with improved supercapacitor performance. J Phys Chem C 118:8262–827010.1021/jp5009626 ↗
42. Liu X, Zhang Z (2014) One-step electrochemical deposition of nickel sulfide/graphene and its use for supercapacitors. Ceram Int 40:8189–819310.1016/j.ceramint.2014.01.015 ↗
43. Nandi D, Gnanaseelan M, Simona F et al (2017) Unique nanopetals of nickel vanadate: crystal structure elucidation and supercapacitive. New J Chem 41:5620–562710.1039/C6NJ03427F ↗
44. Mirghni A, Madito Oyedotun KO et al (2018) A high energy density asymmetric supercapacitor utilizing a nickel phosphate/graphene foam composite as the cathode and carbonized iron cations adsorbed onto polyaniline as the anode. RSC Adv 8:11608–1162110.1039/C7RA12028A ↗
45. Hong WH, Xu YX, Lu GW et al (2008) Transparent graphene/PEDOT-PSS composite films as counter electrodes of dye-sensitized solar cells. Electrochem Commun 10:1555–155810.1016/j.elecom.2008.08.007 ↗
46. Ng YH, Iwase A, Kudo A et al (2010) Reducing graphene oxide on a visible-light BiVO4 photocatalyst for an enhanced photoelectrochemical water splitting. J Phys Chem Lett 1:2607–261210.1021/jz100978u ↗
47. Yang S, Feng X, Ivanovici S et al (2010) Fabrication of graphene-encapsulated oxide nanoparticles: towards high-performance anode materials for lithium storage. Angew Chem 49:8408–841110.1002/anie.201003485 ↗
48. Yang NL, Zhai J, Wang D et al (2010) Two-dimensional graphene bridges enhanced photoinduced charge transport in dye-sensitized solar cells. ACS Nano 4:887–89410.1021/nn901660v ↗
49. Sun YQ, Li C, Xu YX et al (2010) Chemically converted graphene as substrate for immobilizing and enhancing the activity of a polymeric catalyst. Chem Commun 46:4740–474210.1039/c001635g ↗
50. Paek S, Yoo E, Honma I (2009) Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure. Nano Lett 9:72–7510.1021/nl802484w ↗
51. Williams G, Seger B, Kamat PV (2008) TiO2-graphene nanocomposites. UV-assisted photocatalytic reduction of graphene oxide. ACS Nano 2:1487–149110.1021/nn800251f ↗
52. Kim H, Seo M, Park MH (2010) A critical size of silicon nano-anodes for lithium rechargeable batteries. Angew Chem Int Ed 49:2146–214910.1002/anie.200906287 ↗
53. Chen XY, Zhu HL, Chen YC et al (2012) MWCNT/V2O5 Core/shell sponge for high areal capacity and power density Li-ion cathodes. ACS Nano 6:7948–795510.1021/nn302417x ↗
54. Li XF, Meng XB, Liu J et al (2012) Batteries: tin oxide with controlled morphology and crystallinity by atomic layer deposition onto graphene nanosheets for enhanced lithium storage. Adv Func Mater 22:1647–165410.1002/adfm.201101068 ↗
55. Boukhalfa S, Evanoff K, Yushin G (2012) Atomic layer deposition of vanadium oxide on carbon nanotubes for high-power supercapacitor electrodes. Energy Environ Sci 5:6872–687910.1039/c2ee21110f ↗
56. Sun X, Zhou C, Xie M et al (2014) Synthesis of ZnO quantum dot/graphene nanocomposites by atomic layer deposition with high lithium storage capacity. J Mater Chem A 2:7319–732610.1039/C4TA00589A ↗
57. Wu ZS, Wang DW, Ren W et al (2010) Anchoring hydrous RuO2 on graphene sheets for high-performance electrochemical capacitors. Adv Funct Mater 20:3595–360210.1002/adfm.201001054 ↗
58. Du J, Lai XY, Yang NL et al (2011) Hierarchically ordered macro-mesoporous TiO2-graphene composite films: improved mass transfer, reduced charge recombination, and their enhanced photocatalytic activities. ACS Nano 5:590–59610.1021/nn102767d ↗
59. Wang D, Choi D, Li J et al (2009) Self-assembled TiO2–graphene hybrid nanostructures for enhanced Li-ion insertion. ACS Nano 3:907–91410.1021/nn900150y ↗
60. Li B, Cao XH, Ong HG et al (2010) All-carbon electronic devices fabricated by directly grown single-walled carbon nanotubes on reduced graphene oxide electrodes. Adv Mater 22:3058–306110.1002/adma.201000736 ↗
61. Zhou G, Wang D, Li F et al (2010) Graphene wrapped Fe3O4 anode material with improved reversible capacity and cyclic stability for lithium ion batteries. Chem Mater 22:5306–531310.1021/cm101532x ↗
62. Tang YB, Lee CS, Xu J et al (2010) Incorporation of graphenes in nanostructured TiO2 films via molecular grafting for dye-sensitized solar cell application. ACS Nano 4:3482–348810.1021/nn100449w ↗
63. El-Houta SI, Chen C, Liang T (2017) Cetyltrimethylammonium bromide assisted hydrothermal synthesis of cobalt oxide nanowires anchored on graphene as an efficient electrode material for supercapacitor applications. Mater Chem Phys 198:99–10610.1016/j.matchemphys.2017.05.051 ↗
64. Shen JF, Yan B, Shi M et al (2011) One step hydrothermal synthesis of TiO2-reduced graphene oxide sheets. J Mater Chem 21:3415–342110.1039/c0jm03542d ↗
65. Zhu JX, Sharma YK, Zeng ZY et al (2011) Cobalt oxide nanowall arrays on reduced graphene oxide sheets with controlled phase, grain size, and porosity for li-ion battery electrodes. J Phys Chem C 115:8400–840610.1021/jp2002113 ↗
66. Huang XD, Zhou XF, Zhou L et al (2011) A facile one-step solvothermal synthesis of SnO2/graphene nanocomposite and its application as an anode material for lithium-Ion batteries. Chem Phys Phys Chem 12:278–28110.1002/cphc.201000376 ↗
67. Lv W, Sun F, Tang DM et al (2011) A sandwich structure of graphene and nickel oxide with excellent supercapacitive performance. J Mater Chem 21:9014–901910.1039/c1jm10400d ↗
68. Wang DH, Kou R, Choi DW et al (2010) Ternary self-assembly of ordered metal oxide-graphene nanocomposites for electrochemical energy storage. ACS Nano 4:1587–159510.1021/nn901819n ↗
69. Kim IY, Lee JM, Kim TW et al (2012) A strong electronic coupling between graphene nanosheets and layered titanate nanoplates: a soft-chemical route to highly porous nanocomposites with improved photocatalytic activity. Small 8:1038–104810.1002/smll.201101703 ↗
70. Sun W, Li H, Wang Y (2015) Microwave-assisted synthesis of graphene nanocomposites: recent developments on lithium-ion batteries. Rep Electrochem 5:1–19
71. Chen SQ, Wang Y (2010) Microwave-assisted synthesis of a Co3O4–graphene sheet-on-sheet nanocomposite as a superior anode material for Li-ion batteries. J Mater Chem 20:9735–973910.1039/c0jm01573c ↗
72. Rai AK, Anh LT, Gim J (2013) Facile approach to synthesize CuO/reduced graphene oxide nanocomposite as anode materials for lithium-ion battery. J Power Sourc 244:435–44110.1016/j.jpowsour.2012.11.112 ↗
73. Hu T, Xie M, Zhong J et al (2014) Porous Fe2O3 nanorods anchored on nitrogen-doped graphenes and ultrathin Al2O3 coating by atomic layer deposition for long-lived lithium ion battery anode. Carbon 76:141–14710.1016/j.carbon.2014.04.060 ↗
74. Madhu R, Dinesh B, Chen SM et al (2015) An electrochemical synthesis strategy for composite based ZnO microspheres–Au nanoparticles on reduced graphene oxide for the sensitive detection of hydrazine in water samples. RSC Adv 5:54379–5438610.1039/C5RA05612H ↗
75. Yin Z, Wu S, Zhou X et al (2010) Electrochemical deposition of ZnO nanorods on transparent reduced graphene oxide electrodes for hybrid solar cells. Small 6:307–31210.1002/smll.200901968 ↗
76. Hurtado RB, Cortez-Valadez M, Aragon-Guajardo JR et al (2017) One-step synthesis of reduced graphene oxide/gold nanoparticles under ambient conditions. Arab J Chem. https://doi.org/10.1016/j.arabjc.2017.12.02110.1016/j.arabjc.2017.12.021 ↗
77. Zhang H, Hines D, Akins DL et al (2014) Synthesis of a nanocomposite composed of reduced graphene oxide and gold nanoparticles. Dalton Trans 43:2670–267510.1039/C3DT52573B ↗
78. Lim EJ, Choi SM, Seo MH et al (2013) Highly dispersed Ag nanoparticles on nanosheets of reduced graphene oxide for oxygen reduction reaction in alkaline media. Electrochem Commun 28:100–10310.1016/j.elecom.2012.12.016 ↗
79. Subrahmanyam KS, Manna AK, Pati SK (2010) A study of graphene decorated with metal nanoparticles. Chem Phys Lett 497:70–7510.1016/j.cplett.2010.07.091 ↗
80. Lee B, Ma Z, Zhang ZT et al (2009) Influences of synthesis conditions and mesoporous structures on the gold nanoparticles supported on mesoporous silica hosts. Microporous Mesoporous Mater 122:160–16710.1016/j.micromeso.2009.02.029 ↗
81. Dong X, Wang L, Wang D (2012) Layer-by-layer engineered CoAl hydroxide nanosheets/graphene multilayer films as flexible electrode for supercapacitor. Langmuir 28:293–29810.1021/la2038685 ↗
82. Wu ZS, Ren W, Wang DW et al (2010) High-energy MnO2 nanowire/graphene and graphene asymmetric electrochemical capacitors. ACS Nano 4:5835–584210.1021/nn101754k ↗
83. Zhang J, Jiang J, Zhao XS et al (2011) Synthesis and capacitive properties of manganese oxide nanosheets dispersed on functionalized graphene sheets. J Phys Chem C 115:6448–645410.1021/jp200724h ↗
84. Ye XR, Jia DZ, Yu ZQ et al (1999) One-step solid-state reactions at ambient temperatures: a novel approach to nanocrystals synthesis. Adv Mater 11:941–94210.1002/(SICI)1521-4095(199908)11:11<941::AID-ADMA941>3.0.CO;2-T ↗
85. Sun Z, Lu X (2012) A solid-state reaction route to anchoring Ni(OH)2 nanoparticles on reduced graphene oxide sheets for supercapacitors. Ind Eng Chem Res 51:9973–997910.1021/ie202706h ↗
86. Zhang Y, Yuan X, Wang Y et al (2012) One-pot photochemical synthesis of graphene composites uniformly deposited with silver nanoparticles and their high catalytic activity towards the reduction of 2-nitroaniline. J Mater Chem 22:7245–725110.1039/c2jm16455h ↗
87. Qin J, Cao M, Li N et al (2011) Graphene-wrapped WO3 nanoparticles with improved performances in electrical conductivity and gas sensing properties. J Mater Chem 21:17167–1717410.1039/c1jm12692j ↗
88. Yu A, Park HW, Davies A (2011) Free-standing layer-by-layer hybrid thin film of graphene–MnO2 nanotube as anode for lithium ion batteries. J Phys Chem Lett 2:1855–186010.1021/jz200836h ↗
89. Al-Marri AH, Khan M, Khan M et al (2016) Green synthesis of Pd@graphene nanocomposite: catalyst for the selective oxidation of alcohols. Arab J Chem 9:835–84510.1016/j.arabjc.2015.12.007 ↗
90. Xu C, Wang X, Zhu J et al (2008) Graphene − metal particle nanocomposites. J Phys Chem C 112(50):19841–1984510.1021/jp807989b ↗
91. Huang X, Qi X, Boey F (2012) Graphene-based composites. Chem Soc Rev 41(2):666–68610.1039/C1CS15078B ↗
92. Zhai D, Li B, Du H et al (2012) The preparation of graphene decorated with manganese dioxide nanoparticles by electrostatic adsorption for use in supercapacitors. Carbon 50(14):5034–504310.1016/j.carbon.2012.06.033 ↗
93. Yu G, Hu L, Vosgueritchian M et al (2011) Solution-processed graphene/MnO2 nanostructured textiles for high-performance electrochemical capacitors. Nano Lett 11:2905–291110.1021/nl2013828 ↗
94. Beka LG, Li X, Liu W et al (2017) Nickel Cobalt Sulfide core/shell structure on 3D graphene for supercapacitor application. Sci Rep 7(1):210510.1038/s41598-017-02309-8 ↗
95. Maaoui H, Singh SK, Teodorescu F (2017) Copper oxide supported on three-dimensional ammonia-doped porous reduced graphene oxide prepared through electrophoretic deposition for non-enzymatic glucose sensing. Electrochim Acta 224:346–35410.1016/j.electacta.2016.12.078 ↗
96. Jaikumar A, Santhanam KS, Kandlikar SG, Raya I, Raghupathi P (2015) Electrochemical deposition of copper on graphene with high heat transfer coefficient. ECS Trans 66:55–6410.1149/06630.0055ecst ↗
97. Dhibar S, Das CK (2017) Silver nanoparticles decorated polypyrrole/graphene nanocomposite: a potential candidate for next-generation supercapacitor electrode material. J Appl Polym Sci 134:1610.1002/app.44724 ↗
98. Zhang Q, Zhang Y, Gao Z et al (2013) A facile synthesis of platinum nanoparticle decorated graphene by one-step [gamma]-ray induced reduction for high rate supercapacitors. J Mater Chem C 1(2):321–32810.1039/C2TC00078D ↗
99. Hassan HK, Atta NF, Hamed MM et al (2017) Ruthenium nanoparticles-modified reduced graphene prepared by a green method for high-performance supercapacitor application in neutral electrolyte. RSC Adv 7(19):11286–1129610.1039/C6RA27415C ↗
100. Gigot A, Fontana M, Pirri CF et al (2017) Graphene/ruthenium active species aerogel as electrode for supercapacitor applications. Materials 11(1):5710.3390/ma11010057 ↗