Adsorption and removal of organophosphorus pesticides from environmental water and soil samples by using magnetic multi-walled carbon nanotubes @ organic framework ZIF-8
Source abstract
Abstract
In this study, the functional adsorbent metal–organic framework ZIF-8/magnetic multi-walled carbon nanotubes (M-M-ZIF-8) was successfully prepared for removal of eight organophosphorus pesticides from environmental water and soil samples. The M-M-ZIF-8 was characterized and their adsorption capacity was evaluated based on their isothermal adsorption curves. The results suggest that ZIF-8 particles are deposited on the surface of the magnetic MWCNTs via coordination–polymerization strategy. In addition, M-M-ZIF-8 has high static adsorption capacities for organophosphorus pesticides because of its high specific surface area and porous structure. The static adsorption data fit the Freundlich adsorption model better than the Langmuir model. Under the optimized conditions, M-M-ZIF-8 was successfully applied to remove the eight organophosphorus pesticides from environmental water and soil samples. A possible mechanism is valence-electron-driven adsorption by sharing or exchanging of electrons between the organophosphorus pesticide molecules and the vacant active sites of M-M-ZIF-8. Therefore, M-M-ZIF-8 is a promising hybrid adsorbent for adsorption and removal of organic pollutions from the environment.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Adsorption and biosorption for pollutant removal · Metal-Organic Frameworks: Synthesis and Applications · Phosphorus and nutrient management
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (36)
Show source-provided references
1. Yu R, Liu Q, Liu J, Wang Q, Wang Y (2016) Concentrations of organophosphorus pesticides in fresh vegetables and related human health risk assessment in Changchun, Northeast China. Food Control 60:353–36010.1016/j.foodcont.2015.08.013 ↗
2. Boulanouar S, Combès A, Mezzache S, Pichon V (2017) Synthesis and application of molecularly imprinted polymers for the selective extraction of organophosphorus pesticides from vegetable oils. J Chromatogr A 1513:59–6810.1016/j.chroma.2017.07.067 ↗
3. Li W, Wu R, Duan J, Saint CP, van Leeuwen J (2016) Impact of prechlorination on organophosphorus pesticides during drinking water treatment: removal and transformation to toxic oxon byproducts. Water Res 105:1–1010.1016/j.watres.2016.08.052 ↗
4. Zhang W, Asiri AM, Liu D, Du D, Lin Y (2014) Nanomaterial-based biosensors for environmental and biological monitoring of organophosphorus pesticides and nerve agents. TrAC Trends Anal Chem 54:1–1010.1016/j.trac.2013.10.007 ↗
5. Handford CE, Elliott CT, Campbell K (2015) A review of the global pesticide legislation and the scale of challenge in reaching the global harmonization of food safety standards. Int Environ Assess Manag 11:525–53610.1002/ieam.1635 ↗
6. Masiá A, Campo J, Vázquez-Roig P, Blasco C, Picó Y (2013) Screening of currently used pesticides in water, sediments and biota of the Guadalquivir River Basin (Spain). J Hazard Mater 263:95–10410.1016/j.jhazmat.2013.09.035 ↗
7. Li Z, Wang Y, Ni Y, Kokot S (2014) Unmodified silver nanoparticles for rapid analysis of the organophosphorus pesticide, dipterex, often found in different waters. Sens Actuators B Chem 193:205–21110.1016/j.snb.2013.11.096 ↗
8. Dias EM, Petit C (2015) Towards the use of metal–organic frameworks for water reuse: a review of the recent advances in the field of organic pollutants removal and degradation and the next steps in the field. J Mater Chem A 3:22484–2250610.1039/C5TA05440K ↗
9. Di J, Xia J, Ji M, Wang B, Yin S, Zhang Q, Chen Z, Li H (2016) Advanced photocatalytic performance of graphene-like BN modified BiOBr flower-like materials for the removal of pollutants and mechanism insight. Appl Catal B 183:254–26210.1016/j.apcatb.2015.10.036 ↗
10. Jin W, Du H, Zheng S, Zhang Y (2016) Electrochemical processes for the environmental remediation of toxic Cr(VI): a review. Electrochim Acta 191:1044–105510.1016/j.electacta.2016.01.130 ↗
11. Zhang J, Yu H, Quan X, Chen S, Zhang Y (2016) Ceramic membrane separation coupled with catalytic ozonation for tertiary treatment of dyestuff wastewater in a pilot-scale study. Chem Eng J 301:19–2610.1016/j.cej.2016.04.148 ↗
12. Trellu C, Mousset E, Pechaud Y, Huguenot D, Van Hullebusch ED, Esposito G, Oturan MA (2016) Removal of hydrophobic organic pollutants from soil washing/flushing solutions: a critical review. J Hazard Mater 306:149–17410.1016/j.jhazmat.2015.12.008 ↗
13. Liu G, Li L, Xu D, Huang X, Xu X, Zheng S, Zhang Y, Lin H (2017) Metal–organic framework preparation using magnetic graphene oxide-β-cyclodextrin for neonicotinoid pesticide adsorption and removal. Carbohydr Polym 175:584–59110.1016/j.carbpol.2017.06.074 ↗
14. Nodeh HR, Ibrahim WAW, Kamboh MA, Sanagi MM (2017) New magnetic graphene-based inorganic–organic sol-gel hybrid nanocomposite for simultaneous analysis of polar and non-polar organophosphorus pesticides from water samples using solid-phase extraction. Chemosphere 166:21–3010.1016/j.chemosphere.2016.09.054 ↗
15. Liu G, Yang X, Li T, She Y, Wang S, Wang J, Zhang M, Jin F, Jin M, Shao H (2015) Preparation of a magnetic molecularly imprinted polymer using gC3N4–Fe3O4 for atrazine adsorption. Mater Lett 160:472–47510.1016/j.matlet.2015.07.157 ↗
16. Dontsova D, Pronkin S, Wehle M, Chen Z, Fettkenhauer C, Clavel G, Antonietti M (2015) Triazoles: a new class of precursors for the synthesis of negatively charged carbon nitride derivatives. Chem Mater 27:5170–517910.1021/acs.chemmater.5b00812 ↗
17. Dehghani MH, Niasar ZS, Mehrnia MR, Shayeghi M, Al-Ghouti MA, Heibati B, McKay G, Yetilmezsoy K (2017) Optimizing the removal of organophosphorus pesticide malathion from water using multi-walled carbon nanotubes. Chem Eng J 310:22–3210.1016/j.cej.2016.10.057 ↗
18. Qin Y, Zhao P, Fan S, Han Y, Li Y, Zou N, Song S, Zhang Y, Li F, Li X (2015) The comparison of dispersive solid phase extraction and multi-plug filtration cleanup method based on multi-walled carbon nanotubes for pesticides multi-residue analysis by liquid chromatography tandem mass spectrometry. J Chromatogr A 1385:1–1110.1016/j.chroma.2015.01.066 ↗
19. Liu X, Zhang H, Ma Y, Wu X, Meng L, Guo Y, Yu G, Liu Y (2013) Graphene-coated silica as a highly efficient sorbent for residual organophosphorus pesticides in water. J Mater Chem A 1:1875–188410.1039/C2TA00173J ↗
20. Li N, Chen J, Shi Y-P (2015) Magnetic graphene solid-phase extraction for the determination of carbamate pesticides in tomatoes coupled with high performance liquid chromatography. Talanta 141:212–21910.1016/j.talanta.2015.04.018 ↗
21. Zheng X, He L, Duan Y, Jiang X, Xiang G, Zhao W, Zhang S (2014) Poly (ionic liquid) immobilized magnetic nanoparticles as new adsorbent for extraction and enrichment of organophosphorus pesticides from tea drinks. J Chromatogr A 1358:39–4510.1016/j.chroma.2014.06.078 ↗
22. Pinto MCE, Gonçalves RGL, dos Santos RMM, Araújo EA, Perotti GF, dos Santos Macedo R, Bizeto MA, Constantino VRL, Pinto FG, Tronto J (2016) Mesoporous carbon derived from a biopolymer and a clay: preparation, characterization and application for an organochlorine pesticide adsorption. Microporous Mesoporous Mater 225:342–35410.1016/j.micromeso.2016.01.012 ↗
23. Xu J, Liu X, Lowry GV, Cao Z, Zhao H, Zhou JL, Xu X (2016) Dechlorination mechanism of 2, 4-dichlorophenol by magnetic MWCNTs supported Pd/Fe nanohybrids: rapid adsorption, gradual dechlorination, and desorption of phenol. ACS Appl Mater Interfaces 8:7333–734210.1021/acsami.5b11859 ↗
24. Nandasiri MI, Jambovane SR, McGrail BP, Schaef HT, Nune SK (2016) Adsorption, separation, and catalytic properties of densified metal-organic frameworks. Coord Chem Rev 311:38–5210.1016/j.ccr.2015.12.004 ↗
25. Abdelhameed RM, Emam HE, Rocha J, Silva AM (2017) Cu-BTC metal–organic framework natural fabric composites for fuel purification. Fuel Process Technol 159:306–31210.1016/j.fuproc.2017.02.001 ↗
26. Abdelhameed RM, Abdel-Gawad H, Elshahat M, Emam HE (2016) Cu–BTC@ cotton composite: design and removal of ethion insecticide from water. RSC Adv 6:42324–4233310.1039/C6RA04719J ↗
27. Abdelhameed RM, Abdel-Gawad H, Silva CM, Rocha J, Hegazi B, Silva AMS (2017) Kinetic and equilibrium studies on the removal of 14C-ethion residues from wastewater by copper-based metal–organic framework. Int J Environ Sci Technol. https://doi.org/10.1007/s13762-017-1624-410.1007/s13762-017-1624-4 ↗
28. Yang Q, Wang Y, Wang J, Liu F, Hu N, Pei H, Yang W, Li Z, Suo Y, Wang J (2018) High effective adsorption/removal of illegal food dyes from contaminated aqueous solution by Zr–MOFs (UiO-67). Food Chem 254:241–24810.1016/j.foodchem.2018.02.011 ↗
29. Yang Q, Wang J, Zhang W, Liu F, Yue X, Liu Y, Yang M, Li Z, Wang J (2017) Interface engineering of metal organic framework on graphene oxide with enhanced adsorption capacity for organophosphorus pesticide. Chem Eng J 313:19–2610.1016/j.cej.2016.12.041 ↗
30. Yang Q, Wang J, Chen X, Yang W, Pei H, Hu N, Li Z, Suo Y, Li T, Wang J (2018) The simultaneous detection and removal of organophosphorus pesticides by a novel Zr-MOF based smart adsorbent. J Mater Chem A 6:2184–219210.1039/C7TA08399H ↗
31. Canivet J, Fateeva A, Guo Y, Coasne B, Farrusseng D (2014) Water adsorption in MOFs: fundamentals and applications. Chem Soc Rev 43:5594–561710.1039/C4CS00078A ↗
32. Han Z, Jiang K, Fan Z, Di Mavungu JD, Dong M, Guo W, Fan K, Campbell K, Zhao Z, Wu Y (2017) Multi-walled carbon nanotubes-based magnetic solid-phase extraction for the determination of zearalenone and its derivatives in maize by ultra-high performance liquid chromatography-tandem mass spectrometry. Food Control 79:177–18410.1016/j.foodcont.2017.03.044 ↗
33. Yu F, Ma J, Wang J, Zhang M, Zheng J (2016) Magnetic iron oxide nanoparticles functionalized multi-walled carbon nanotubes for toluene, ethylbenzene and xylene removal from aqueous solution. Chemosphere 146:162–17210.1016/j.chemosphere.2015.12.018 ↗
34. Min X, Yang W, Hui Y-F, Gao C-Y, Dang S, Sun Z-M (2017) Fe3O4@ ZIF-8: a magnetic nanocomposite for highly efficient UO2 2+ adsorption and selective UO2 2+/Ln3+ separation. Chem Commun 53:4199–420210.1039/C6CC10274C ↗
35. Zou Z, Wang S, Jia J, Xu F, Long Z, Hou X (2016) Ultrasensitive determination of inorganic arsenic by hydride generation-atomic fluorescence spectrometry using Fe3O4@ ZIF-8 nanoparticles for preconcentration. Microchem J 124:578–58310.1016/j.microc.2015.10.005 ↗
36. Calle-Vallejo F, Loffreda D, Koper MT, Sautet P (2015) Introducing structural sensitivity into adsorption–energy scaling relations by means of coordination numbers. Nat Chem 7:403–41010.1038/nchem.2226 ↗