Plating on acrylonitrile–butadiene–styrene (ABS) plastic: a review
Source abstract
Abstract
ABS is an engineering plastic that has butadiene part uniformly distributed over the acrylonitrile-styrene matrix. It possesses excellent toughness, good dimensional stability, easy processing ability, chemical resistance, and cheapness. However, it suffers from inherent shortcomings in terms of mechanical strength and vulnerability to environmental conditions. Furthermore, it is non-conducting and easily fretted. Plating on ABS can serve to enhance the strength and structural integrity as well as to improve durability and thermal resistance resulting in metallic properties on the ABS material. ABS is described as the most suitable candidate for plating because it is possible to deposit an adherent metal coating on it by only the use of chemical pretreatment process and without the use of any mechanical abrasion. This article aims to review the history of ABS plastics, properties of ABS, processes and mechanisms of plating, and studies of plating on ABS involving mainly eco-friendly methods of plating by discussing the literature published in recent years. The details of electroplating of ABS carried out in the authors’ laboratory are also presented.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Electrodeposition and Electroless Coatings · Recycling and Waste Management Techniques · Additive Manufacturing and 3D Printing Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Wang W, Ji S, Lee I (2013) A facile method of nickel electroless deposition on various neutral hydrophobic polymer surfaces. Appl Surf Sci 283:309–320. doi: 10.1016/j.apsusc.2013.06.10810.1016/j.apsusc.2013.06.108 ↗
2. Tran V, Massardier V, Guyot A, Nguyen T (1993) Interactions in metal-polymer-metal interfaces. Polymer 34(15):3179–318310.1016/0032-3861(93)90387-P ↗
3. Grundmeier G, Stratmann M (2005) Adhesion and de-adhesion mechanisms at polymer/metal interfaces: mechanistic understanding based on in situ studies of buried interfaces. Annu Rev Mater Res 35:571–61510.1146/annurev.matsci.34.012703.105111 ↗
4. Holubar P, Jilek M, Sima M (2000) Present and possible future applications of superhard nanocomposite coatings. Surf Coat Technol 133:145–15110.1016/S0257-8972(00)00956-7 ↗
5. Long DP, Blackburn JM, Watkins JJ (2000) Chemical fluid deposition: a hybrid technique for low-temperature metallization. Adv Mater 12(12):913–91510.1002/1521-4095(200006)12:12<913::AID-ADMA913>3.0.CO;2-# ↗
6. Cheng K, Yang MH, Chiu WW, Huang CY, Chang J, Ying TF, Yang Y (2005) Ink-jet printing, self-assembled polyelectrolytes, and electroless plating: low cost fabrication of circuits on a flexible substrate at room temperature. Macromol Rapid Comm 26(4):247–26410.1002/marc.200400462 ↗
7. Garcia A (2011) Ligand induced electroless plating of polymers. PhD Dissertation, École Polytech
8. Arai S, Sato T, Endo M (2011) Fabrication of various electroless Ni–P alloy/multiwalled carbon nanotube composite films on an acrylonitrile butadiene styrene resin. Surf Coat Technol 205(10):3175–318110.1016/j.surfcoat.2010.11.030 ↗
9. Tengsuwan S, Ohshima M (2014) Environmentally benign electroless nickel plating using supercritical carbon-dioxide on hydrophilically modified acrylonitrile–butadiene–styrene. Appl Surf Sci 311:189–20010.1016/j.apsusc.2014.05.040 ↗
10. Dechasit P, Trakarnpruk W (2011) Ni electroless plating of ABS polymer by palladium and tin-free process. J Met Mater Min 21(2):19–27
11. Wang Z, Li Z, He Y, Wang Z (2011) Study of an environmentally friendly surface etching system of ABS for improving adhesion of electroless Cu film. J Electrochem Soc 158(11):D664–D67010.1149/2.063111jes ↗
12. Kim GG, Kang JA, Kim JH, K-y Lee, Kim SJ, Kim S-J (2007) Photocatalytic pretreatment of acrylonitrile–butadiene–styrene polymer for electroless plating. Scripta Mater 56(5):349–35110.1016/j.scriptamat.2006.11.030 ↗
13. Di L, Liu B, Song J, Shan D, Yang D-A (2011) Effect of chemical etching on the Cu/Ni metallization of poly (ether ether ketone)/carbon fiber composites. Appl Surf Sci 257(9):4272–427710.1016/j.apsusc.2010.12.035 ↗
14. Ferreira ODS, Stevens A, Schrauwen C (2009) Quantitative comparison of adhesion in metal-to-plastic systems. Thin Solid Films 517(10):3070–307410.1016/j.tsf.2008.11.117 ↗
15. Ma Z, Tan K, Kang E (2000) Electroless plating of palladium and copper on polyaniline films. Synth Met 114(1):17–2510.1016/S0379-6779(00)00207-1 ↗
16. Kulkarni MV, Elangovan K, Hemachandra RK (2013) Effects of electroplating on the mechanical properties of injection molded thermoplastics. Int J Plast Technol. doi: 10.1007/s12588-013-9056-6
17. Vander Togt RT (2011) Bumper and process to bond ionomers to plastic. US Patent 4,999,227
18. Teixeira LAC, Santini MC (2005) Surface conditioning of ABS for metallization without the use of chromium baths. J Mater Process Technol 170(1):37–4110.1016/j.jmatprotec.2005.04.075 ↗
19. Shu Z, Wang X (2012) Environment-friendly Pd free surface activation technics for ABS surface. Appl Surf Sci 258(14):5328–533110.1016/j.apsusc.2012.01.141 ↗
20. Bazzaoui M, Martins J, Bazzaoui E, Albourine A (2012) Environmentally friendly process for nickel electroplating of ABS. Appl Surf Sci 258(20):7968–797510.1016/j.apsusc.2012.04.146 ↗
21. Tang X, Cao M, Bi C, Yan L, Zhang B (2008) Research on a new surface activation process for electroless plating on ABS plastic. Mater Lett 62(6):1089–109110.1016/j.matlet.2007.07.055 ↗
22. Skelly J (2008) Decorative plating processes for common plastic resins: resin selection as well as plastic part design is critical to matching the right finishing method with the intended application. Met Finish 106(6):61–6510.1016/S0026-0576(08)80166-3 ↗
23. Haba B, Sugai K, Morishige Y, Kishida S (1994) Large scale two-step selective aluminum CVD on laser patterned palladium lines. Appl Surf Sci 79:381–38410.1016/0169-4332(94)90440-5 ↗
24. Chen Y, Reisman A, Turlik I, Temple D (1995) Cu CVD from copper (II) hexafluoroacetylacetonate II. Laser-assisted selective area deposition. J Electrochem Soc 142(11):3911–391810.1149/1.2048433 ↗
25. Seeböck R, Esrom H, Charbonnier M, Romand M, Kogelschatz U (2001) Surface modification of polyimide using dielectric barrier discharge treatment. Surf Coat Technol 142:455–45910.1016/S0257-8972(01)01085-4 ↗
26. Tóth Z, Szörényi T, Toth A (1993) Ar+ laser-induced forward transfer (LIFT): a novel method for micrometer-size surface patterning. Appl Surf Sci 69(1):317–32010.1016/0169-4332(93)90525-G ↗
27. McCaskie JE, Tsiamis C (1985) Metal plating on plastics. US Patent 4,520,046
28. Yang C-Y (2012) Method for preparing electronic component-mounting device. US Patent App. 13/471,108
29. Hooke R (2014) Method of making shaped charges and explosively formed projectiles. US Patent 8,813,651
30. Hoyt R, Wrobel J, Cushing J, Jaster M, Voronka N, Frank S, Slostad J, Paritsky L (2014) Structures with internal microstructures to provide multifunctional capabilities. US Patent 14/462,541
31. Nath J, Shen Y, Nealis E (2014) Systems and methods for manufacturing passive waveguide components. US Patent App. 14/453,563
32. McCaskie JE (2006) Plating on plastics: a survey of mechanisms for adhering metal films to plastic surfaces. Met Finish 104(5):31–3910.1016/S0026-0576(06)80204-7 ↗
33. Mallory GO, Hajdu JB (1990) Electroless plating: fundamentals and applications. William Andrew, New York
34. Arnold JR (2003) High quality copper-nickel-chromium plating on plastics: a continuous process and its challenges. Plat Surf Finish 91:355–379
35. Kulkarni MV, Elangovan K, Hemachandra Reddy K (2012) Improvements in impact resistance property of metal plated abs and Nylon6 thermoplastics. FS J Eng Res 1(1):31–33
36. Equbal AAKS (2014) Metallization on FDM parts using the chemical deposition technique. Coatings 4:574–586. doi: 10.3390/coatings403057410.3390/coatings4030574 ↗
37. Tang X, Wang J, Wang C, Shen B (2011) A novel surface activation method for Ni/Au electroless plating of acrylonitrile–butadiene–styrene. Surf Coat Technol 206(6):1382–138810.1016/j.surfcoat.2011.08.064 ↗
38. Garcia A, Berthelot T, Viel P, Mesnage A, Jégou P, Nekelson F, Roussel S, Palacin S (2010) ABS polymer electroless plating through a one-step poly(acrylic acid) covalent grafting. ACS Appl Mater Interfaces 2(4):1177–118310.1021/am1000163 ↗
39. Kuzmik JJ (1990) Electroless plating: fundamentals and applications (Reprint Edition). In: Mallory GO, Hajdu JB (eds). The American Electroplaters and Surface Finishers Society, Orlanda, FL, pp 377–399
40. Hanna F, Hamid ZA, Aal AA (2004) Controlling factors affecting the stability and rate of electroless copper plating. Mater Lett 58(1):104–10910.1016/S0167-577X(03)00424-5 ↗
41. Equbal A, Sood AK (2014) Electroless plating of copper on different shaped ABS parts: a comparison. Int J Adv Mater Manuf Charact 4(1):32–41. doi: 10.11127/ijammc.2014.03.05
42. Li D, Goodwin K, Yang C-L (2008) Electroless copper deposition on aluminum-seeded ABS plastics. J Mater Sci 43(22):7121–7131. doi: 10.1007/s10853-008-3031-110.1007/s10853-008-3031-1 ↗
43. Liu H-P, Li N, Bi S-F, Li D-Y, Zou Z-L (2008) Effect of organic additives on the corrosion resistance properties of electroless nickel deposits. Thin Solid Films 516(8):1883–188910.1016/j.tsf.2007.10.008 ↗
44. Lu G, Li X, Jiang H (1996) Electrical and shielding properties of ABS resin filled with nickel-coated carbon fibers. Compos Sci Technol 56(2):193–20010.1016/0266-3538(95)00143-3 ↗
45. Walsh F, De León CP, Kerr C, Court S, Barker B (2008) Electrochemical characterisation of the porosity and corrosion resistance of electrochemically deposited metal coatings. Surf Coat Technol 202(21):5092–510210.1016/j.surfcoat.2008.05.008 ↗
46. Agarwala RC, Agarwala V, Sharma R (2006) Electroless ni-p based nanocoating technology—a review. Synth React Inorg Met-Org Nano-Met Chem 36(6):493–51510.1080/15533170600596030 ↗
47. Balaraju J, Narayanan TS, Seshadri S (2003) Electroless Ni–P composite coatings. J Appl Electrochem 33(9):807–81610.1023/A:1025572410205 ↗
48. Tzeng S-S, Chang F-Y (2001) EMI shielding effectiveness of metal-coated carbon fiber-reinforced ABS composites. Mater Sci Eng A 302(2):258–26710.1016/S0921-5093(00)01824-4 ↗
49. Charbonnier M, Romand M, Goepfert Y (2006) Ni direct electroless metallization of polymers by a new palladium-free process. Surf Coat Technol 200(16):5028–503610.1016/j.surfcoat.2005.05.006 ↗
50. Sahoo P, Das SK (2011) Tribology of electroless nickel coatings—a review. Mater Des 32(4):1760–177510.1016/j.matdes.2010.11.013 ↗
51. Sudagar J, Lian J, Sha W (2013) Electroless nickel, alloy, composite and nano coatings—a critical review. J Alloys Compd 571:183–20410.1016/j.jallcom.2013.03.107 ↗
52. Agarwala R, Agarwala V (2003) Electroless alloy/composite coatings: a review. Sadhana 28(3–4):475–49310.1007/BF02706445 ↗
53. Equbal A, Dixit NK, Sood AK (2013) Electroless plating on plastic. IJSER 410.11127/ijammc.2014.03.05 ↗
54. Maul J, Frushour BG, Kontoff JR, Eichenauer H, Ott K-H, Schade C (2000) Polystyrene and styrene copolymers. In: Ullmann’s encyclopedia of industrial chemistry. Wiley, New York. doi: 10.1002/14356007.a21_615.pub210.1002/14356007.a21_615.pub2 ↗
55. Federation BP (2015) A history of plastics. British Plastics Federation. http://www.bpf.co.uk/plastipedia/plastics_history/Default.aspx
56. Brickipedia (2015) Acrylonitrile butadiene styrene. Brickipedia. http://lego.wikia.com/wiki/Brickipedia:Brickipedians
57. Truss R, Chadwick G (1976) Tensile deformation behaviour of ABS polymers. J Mater Sci 11(1):111–117. doi: 10.1007/BF0054108110.1007/BF00541081 ↗
58. Truss R, Chadwick G (1977) The fracture behaviour of ABS polymers. J Mater Sci 12:503–508. doi: 10.1007/BF0054027410.1007/BF00540274 ↗
59. Bucknall C, Clayton D, Keast WE (1972) Rubber-toughening of plastics- Part 2 Creep mechanisms in HIPS/PPO blends. J Mater Sci 7(12):1443–1453. doi: 10.1007/BF0057493610.1007/BF00574936 ↗
60. Kulich DM, Gaggar S, Lowry V, Stepien R (2004) Acrylonitrile–butadiene–styrene (ABS) polymers. Kirk-Othmer Encyclopedia of Chemical Technology10.1002/0471238961.01021911211209.a01.pub2 ↗
61. Moore J (1973) Acrylonitrile–butadiene–styrene (ABS)-a review. Composites 4(3):118–13010.1016/0010-4361(73)90585-5 ↗
62. ABS material data sheet. teststandard.com/data_sheets/ABS_Data_sheet.pdf
63. Lifton VA, Lifton G, Simon S (2014) Options for additive rapid prototyping methods (3D printing) in MEMS technology. Rapid Prototyp J 20(5):403–41210.1108/RPJ-04-2013-0038 ↗
64. Huang SH, Liu P, Mokasdar A, Hou L (2013) Additive manufacturing and its societal impact: a literature review. Int J Adv Manuf Technol 67:1191–1203. doi: 10.1007/s00170-012-4558-510.1007/s00170-012-4558-5 ↗
65. Yuan L (2008) A preliminary research on development of a fiber-composite, curved FDM system. National University of Singapore
66. Wong KV, Hernandez A (2012) A review of additive manufacturing. ISRN Mech Eng. doi: 10.5402/2012/208760
67. Yan XG, Gu PENG (1996) A review of rapid prototyping technologies and systems. Comput Aided Des 28(4):307–31810.1016/0010-4485(95)00035-6 ↗
68. Diegel O, Reay S, Singamneni S, Withell A (2010) Tools for sustainable product design: additive manufacturing. J Sustain Dev 3(3):68–7510.5539/jsd.v3n3p68 ↗
69. Stereolithography; S-PCHPi, http://spie.org/x91418.xml . Accessed 27 Sept 2015
70. 3DSystems. 30 years of innovation. http://www.3dsystems.com/30-years-innovation . Accessed 27 Sept 2015
71. Crump SS (1992) Apparatus and method for creating three-dimensional objects. US Patent 5,121,329
72. Sachs EM, Haggerty JS, Cima MJ, Williams PA (1993) Three-dimensional printing techniques. US Patent 5,204,055
73. Gross BC, Erkal JL, Lockwood SY, Chen C, Spence DM (2014) Evaluation of 3D printing and its potential impact on biotechnology and the chemical sciences. Anal Chem. doi: 10.1021/ac403397r
74. Chen S, Patel N, Schaffer D, Maharbiz M (2011) Trap and corral: a two-step approach for constructing and constraining dynamic cell contact events in differentiating progenitor cell populations. J Micromech Microeng 21(5):05402710.1088/0960-1317/21/5/054027 ↗
75. Kannan S, Senthilkumaran D (2014) Assessment of mechanical properties of Ni-coated abs plastics using FDM process. IJMME-IJENS 14(3):30–35
76. Monzon MD, Diaz N, Benitez AN, Marrero MD, Hernandez PM (2010) Advantages of fused deposition modeling for making electrically conductive plastic. Int Conf Manuf Autom. doi: 10.1109/ICMA.2010.36
77. Kannan S, Senthilkumaran D, Elangovan, K. (2013) Development of composite materials by rapid prototyping technology using FDM method. IEEE, 281–28310.1109/ICCTET.2013.6675966 ↗
78. Chandrasekhar U, Venkatesh K, Elangovan K, Rangaswamy T (2011) Integrated use of rapid prototyping and metal plating techniques for development of micro air vehicles. IJEST 3(1):188–193
79. Equbal A, Sood AK (2015) Investigations on metallization in FDM build ABS part using electroless deposition method. J Manuf Process 19:22–3110.1016/j.jmapro.2015.03.002 ↗
80. Saleh N, Hopkinson N, Hague RJ, Wise S (2004) Effects of electroplating on the mechanical properties of stereolithography and laser sintered parts. Rapid Prototyp J 10(5):305–31510.1108/13552540410562340 ↗
81. Kannan S, Senthilkumaran D (2014) Investigating the influence of electroplating layer thickness on the tensile strength for fused deposition processed ABS thermoplastics. IJET 6(2):1047–1052
82. Lurie KL, Smith GT, Khan SA, Liao JC, Ellerbee AK (2014) Three-dimensional, distendable bladder phantom for optical coherence tomography and white light cystoscopy. J Biomed Opt 19(3):03600910.1117/1.JBO.19.3.036009 ↗
83. Stremsdoerfer G, Ghanem F, Saikali Y, Fares-Karam A (2003) Copper deposition by dynamic chemical plating. J Mater Sci 38(15):3285–3291. doi: 10.1023/A:102519002206910.1023/A:1025190022069 ↗
84. Weng D, Landau U (1995) Direct electroplating on nonconductors. J Electrochem Soc 142(8):2598–260410.1149/1.2050060 ↗
85. Krishnan KH, John S, Srinivasan K, Praveen J, Ganesan M, Kavimani P (2006) An overall aspect of electroless Ni–P depositions—a review article. Metall Mater Trans A 37(6):1917–192610.1007/s11661-006-0134-7 ↗
86. Feldstein N (1981) Dispersions for activating non-conductors for electroless plating. US Patent 4,282,271
87. Feldstein N (1982) Electroless plating. US Patent 4,321,285
88. Equbal A, Equbal A, Sood AK (2014) Metallization on FDM processed parts using electroless procedure. Proc Mater Sci 6:1197–1206. doi: 10.1016/j.mspro.2014.07.19310.1016/j.mspro.2014.07.193 ↗
89. Kirman T (1972) Electroless nickel plating process for nonconductors. US Patent 3,684,572
90. Feldstein N (1976) Electroless plating process employing non-noble metal hydrous oxide catalyst. US Patent 3,993,799
91. Elmore G, Davis K (1969) Mechanism of bonding electroless metal to organic substrates. J Electrochem Soc 116(10):1455–145810.1149/1.2411561 ↗
92. Abu-Isa IA (1973) Metal plating of polymeric surfaces. Polym-Plast Technol Eng 2(1):29–6510.1080/03602557308545013 ↗
93. Metal plating of thermoplastics (1971). US Patent 3,620,804
94. Magallón-Cacho L, Pérez-Bueno J, Meas-Vong Y, Stremsdoerfer G, Espinoza-Beltrán F (2011) Surface modification of acrylonitrile-butadiene-styrene (ABS) with heterogeneous photocatalysis (TiO2) for the substitution of the etching stage in the electroless process. Surf Coat Technol 206(6):1410–141510.1016/j.surfcoat.2011.09.005 ↗
95. Krulik GA (1980) Method for electroless plating on nonconductive substrates using palladium/tin catalyst in aqueous solution containing a hydroxy substituted organic acid. US Patent 4,182,784
96. Daneshmand S, Aghanajafi C, Nadooshan AA (2010) The effect of chromium coating in RP technology for airfoil manufacturing. Sadhana 35(5):569–58410.1007/s12046-010-0036-7 ↗
97. Gabe D (1977) Corrosion and protection of sintered metal parts. Powder Metall 20(4):227–23110.1179/pom.1977.20.4.227 ↗
98. Conlan W, Dutkewych O (1973) Pre-etch treatment of acrylonitrile-butadiene-styrene resins for electroless plating. US Patent 3,769,061
99. Weakley-Bollin SC (2010) The effect of injection molding conditions on the near-surface rubber morphology, surface chemistry and adhesion performance of semi-crystalline and amorphous polymers. University of Michigan, Ann Arbor
100. Beacom SE, Wedel RG (1970) Scanning electron microscopy of plastic surfaces as related to metal deposition. J Colloid Interface Sci 34(3):375–38610.1016/0021-9797(70)90196-7 ↗