Room temperature elastic moduli and Vickers hardness of hot-pressed LLZO cubic garnet
Source abstract
Abstract
Cubic garnet Li6.24La3Zr2Al0.24O11.98 (LLZO) is a candidate material for use as an electrolyte in Li–Air and Li–S batteries. The use of LLZO in practical devices will require LLZO to have good mechanical integrity in terms of scratch resistance (hardness) and an adequate stiffness (elastic modulus). In this paper, the powders were fabricated by powder processing of cast ingots. All specimens were then densified via hot pressing. The room temperature elastic moduli (Young’s modulus, shear modulus, bulk modulus, and Poisson’s ratio) and hardness were measured by resonant ultrasound spectroscopy, and Vickers indentation, respectively. For volume fraction porosity, P, the Young’s modulus was 149.8 ± 0.4 GPa (P = 0.03) and 132.6 ± 0.2 GPa (P = 0.06). The mean Vickers hardness was 6.3 ± 0.3 GPa for P = 0.03 and 5.2 ± 0.4 for P = 0.06.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Transition Metal Oxide Nanomaterials · Ferroelectric and Piezoelectric Materials · Glass properties and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (63)
Show source-provided references
1. Goodenough JB, Kim Y (2011) J Power Sources 196:668810.1016/j.jpowsour.2010.11.074 ↗
2. Kowalczk I, Read J, Salomon M (2007) Pure Appl Chem 79:85110.1351/pac200779050851 ↗
3. Visco SJ, Katz BD, Nimon YS, De Jonghe LC (2007) US Patent 7,282,295 B2
4. Wolfenstine J, Allen JL, Sumner J, Sakamoto J (2009) Solid State Ion 180:96110.1016/j.ssi.2009.03.021 ↗
5. Reddy JN (2006) An introduction to the finite element method, 3rd edn. McGraw-Hill Higher Education, New York
6. Shimonishi Y, Toda A, Zhang T, Hirano A, Imanishi N, Yamamoto O, Takeda Y (2011) Solid State Ion 183:4810.1016/j.ssi.2010.12.010 ↗
7. Kotobuki M, Munakata H, Kanamura K, Sato Y, Yoshida T (2010) J Electrochem Soc 157:A107610.1149/1.3474232 ↗
8. Kokal I, Somer M, Notten PHL, Hintzen HT (2011) Solid State Ion 185:4210.1016/j.ssi.2011.01.002 ↗
9. Geiger CA, Alekseev E, Lazic B, Fisch M, Armbruster T, Langner R, Fechtelkord M, Kim N, Pettke T, Weppner W (2011) Inorganic Chem 50:108910.1021/ic101914e ↗
10. Murugan R, Thangadurai V, Weppner W (2007) Angew Chem Int Ed 46:777810.1002/anie.200701144 ↗
11. Rangasamy E, Wolfenstine J, Sakamoto JS (2011) Solid State Ion 206:2810.1016/j.ssi.2011.10.022 ↗
12. Rietveld HM (1969) J Appl Crystallogr 2:6510.1107/S0021889869006558 ↗
13. Wachtman JB, Cannon WR, Matthewson MJ (2009) Mechanical properties of ceramics, 2nd edn. Wiley, Hoboken10.1002/9780470451519 ↗
14. Ren F, Case ED, Morrison A, Tafesse M, Baumann MJ (2009) Philos Mag 89:116310.1080/14786430902915388 ↗
15. Ni JE, Case ED, Khabir KN, Stewart RC, Wu C-I, Hogan TP, Timm EJ, Girard SN, Kanatzidis MG (2010) Mater Sci Eng B 170:5810.1016/j.mseb.2010.02.026 ↗
16. Ren F, Case ED, Sootsman JR, Kanatzidis MG, Kong H, Uher C, Lara-Curzio E, Trejo RM (2008) Acta Mater 56:595410.1016/j.actamat.2008.07.055 ↗
17. Ren F, Case ED, Ni JE, Timm EJ, Lara-Curzio E, Trejo RM, Lin C-H, Kanatzidis MG (2009) Philos Mag 89(2):14310.1080/14786430802607119 ↗
18. Vdovychenko OV, Voropaev VS, Slipenyuk AN (2006) J Mater Sci 41:8329. doi: 10.1007/s10853-006-1019-210.1007/s10853-006-1019-2 ↗
19. Ni JE, Ren F, Case ED, Timm EJ (2009) Mater Chem Phys 118:45910.1016/j.matchemphys.2009.08.018 ↗
20. Davulis PM, Shyam A, Lara-Curzio E, Pereira da Cunha M (2008) IEEE Int Ultrason Symp Proc 1–4:2150
21. Drymiotis FR (2010) Int J Mod Phys B 24:104710.1142/S0217979210055561 ↗
22. Lein HL, Andersen ØS, Vullum PE, Lara-Curzio E, Holmestad R, Einarsrud M-A, Grande T (2006) J Solid State Electrochem 10:63510.1007/s10008-006-0140-0 ↗
23. Pestka KA, Scott ES, Le Page Y (2011) AIP Adv 1:03215410.1063/1.3641248 ↗
24. Pestka KA, Maynard JD, Soukiassian A, Xi XX, Schlom DG, Le Page Y, Bernhagen M, Reiche P, Uecker R (2008) Appl Phys Lett 92:11191510.1063/1.2901881 ↗
25. Pham HH, Williams ME, Mahaffey P, Radovic M, Arroyave R, Cagin T (2011) Phys Rev B 84:06410110.1103/PhysRevB.84.064101 ↗
26. Radovic M, Lara-Curzio E (2004) J Am Ceram Soc 87:224210.1111/j.1151-2916.2004.tb07499.x ↗
27. Radovic M, Barsoum MW, Ganguly A, Zhen T, Finkel P, Kalidindi SR, Lara-Curzio E (2006) Acta Mater 54:275710.1016/j.actamat.2006.02.019 ↗
28. Salvador JR, Yang J, Shi X, Wang H, Wereszczak AA, Kong H, Uher C (2009) Philos Mag 89:151710.1080/14786430903019099 ↗
29. Flynn K, Radovic M (2011) J Mater Sci 46:2548. doi: 10.1007/s10853-010-5107-y10.1007/s10853-010-5107-y ↗
30. Gudlur P, Forness A, Lentz J, Radovic M, Muliana A (2012) Mater Sci Eng A 531:1810.1016/j.msea.2011.10.001 ↗
31. Barsoum MW, Radovic M, Zhen T, Finkel P, Kalidindi SR (2005) Phys Rev Lett 94:08550110.1103/PhysRevLett.94.085501 ↗
32. McClellan KJ, Chu F, Roper JM, Shindo I (2001) J Mater Sci 36:3403. doi: 10.1023/A:101794762578410.1023/A:1017947625784 ↗
33. Fullman RL (1953) Trans AIME 197:447
34. Houston B, Strakna RE, Belson HS (1968) J Appl Phys 39:391310.1063/1.1656874 ↗
35. Einspruch NG, Manning RJ (1963) J Acoust Soc Am 35:21510.1121/1.1918434 ↗
36. Simmons G, Wang H (1971) Single crystal elastic constants and calculated aggregate properties: a handbook. The MIT Press, Cambridge
37. Chou HM, Case ED (1988) J Mater Sci Lett 7:121710.1007/BF00722341 ↗
38. Sharma PU, Modi KB (2010) Phys Scr 81:01560110.1088/0031-8949/81/01/015601 ↗
39. Dey A, Mukhopadhyay AK (2011) Int J Appl Ceram Technol 8:57210.1111/j.1744-7402.2010.02538.x ↗
40. Rice RW (1998) Porosity of ceramics. Marcel Dekker Inc., New York
41. Hoepfner TP, Case ED (2003) Ceram Int 29:69910.1016/S0272-8842(02)00220-1 ↗
42. Gilman JJ (1969) Micromechanics of flow in solids. McGraw Hill, New York
43. Gilman JJ (2009) Chemistry and physics of mechanical hardness. Wiley, Hoboken10.1002/9780470446836 ↗
44. Wooster WA (1953) Rep Prog Phys 16:6210.1088/0034-4885/16/1/302 ↗
45. Gilman JJ (1963) Natl Bureau Stand Monogr 59: 79
46. Ruffa AR (1963) Phys Rev 130:141210.1103/PhysRev.130.1412 ↗
47. Sirdeshmukh DB, Subhadra KG, Rag KK, Rao TT (1995) Cryst Res Technol 30:86110.1002/crat.2170300625 ↗
48. Winkler HGF (1955) Struktur und Eigenshaften der Kristalle. Springer Vaerlag, Berlin10.1007/978-3-642-94658-5 ↗
49. Liu M, Shi B, Guo J, Cai X, Song H (2003) Scr Mater 49:16710.1016/S1359-6462(03)00211-2 ↗
50. Vijh AK (1975) J Mater Sci 10:1087. doi: 10.1007/BF0082322710.1007/BF00823227 ↗
51. Ravinder D, Vijaya Kumar K, Boyanov BS (1999) Mater Lett 38:2210.1016/S0167-577X(98)00126-8 ↗
52. Makishima A, Mackenzie JD (1973) J Non-Cryst Solids 12:3510.1016/0022-3093(73)90053-7 ↗
53. Graham LJ, Change R (1970) J Appl Phys 41:224710.1063/1.1659197 ↗
54. Bateman TB (1966) J Appl Phys 37:219410.1063/1.1708773 ↗
55. Clark AE, Strakna RE (1961) J Appl Phys 32:117210.1063/1.1736184 ↗
56. Mezeix L, Green DJ (2006) Int J Appl Ceram Technol 3:16610.1111/j.1744-7402.2006.02068.x ↗
57. Saunders GA, Parker SC, Benbattouche N, Alberts HI (1992) Phys Rev B 46:875610.1103/PhysRevB.46.8756 ↗
58. Gilman JJ (1973) In: Westbrook JH, Conrad H (eds) The science of hardness testing and it’s research applications. American Society for Metals, Metals Park, p 51
59. Rice RW (2000) Mechanical properties of ceramics and composites. Marcel Dekker Inc., New York10.1201/9780203908471 ↗
60. Boccaccini AR (1994) J Am Ceram Soc 77:277910.1111/j.1151-2916.1994.tb04679.x ↗
61. Verma RK (1960) J Geophys Res 65:75710.1029/JZ065i002p00757 ↗
62. Soga N (1967) J Geophys Res 72:422710.1029/JZ072i016p04227 ↗
63. Birke P, Salam F, Doring S, Weppner W (1998) Solid State Ion 91:149