Geopolymer technology: the current state of the art
Source abstract
Abstract
A brief history and review of geopolymer technology is presented with the aim of introducing the technology and the vast categories of materials that may be synthesized by alkali-activation of aluminosilicates. The fundamental chemical and structural characteristics of geopolymers derived from metakaolin, fly ash and slag are explored in terms of the effects of raw material selection on the properties of geopolymer composites. It is shown that the raw materials and processing conditions are critical in determining the setting behavior, workability and chemical and physical properties of geopolymeric products. The structural and chemical characteristics that are common to all geopolymeric materials are presented, as well as those that are determined by the specific interactions occurring in different systems, providing the ability for tailored design of geopolymers to specific applications in terms of both technical and commercial requirements.
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Research context
OpenAlex topics: Concrete and Cement Materials Research · Innovative concrete reinforcement materials · Nuclear materials and radiation effects
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Davidovits J (1991) J Therm Anal 37:163310.1007/BF01912193 ↗
2. Van Wazer JR (1970) Inorg Macromol Rev 1:89
3. Gartner E (2004) Cem Conc Res 34:148910.1016/j.cemconres.2004.01.021 ↗
4. Rahier H, Van Mele B, Biesemans M, Wastiels J, Wu X (1996) J Mater Sci 31:7110.1007/BF00355128 ↗
5. Palomo A, De La Fuente JIL (2003) Cem Conc Res 33:28110.1016/S0008-8846(02)00963-8 ↗
6. Krivenko PV (1994) In: Krivenko PV (ed) Proceedings of the first international conference on alkaline cements, concretes. VIPOL Stock Company, Kiev, Ukraine, pp 11–129
7. Mallicoat S, Sarin P, Kriven WM (2005) Ceram Eng Sci Proc 26:3710.1002/9780470291283.ch5 ↗
8. Sofi M, Van Deventer JSJ, Mendis PA, Lukey GC (2006) J Mater Sci (this issue)
9. Bao Y, Grutzeck MW, Jantzen CM (2005) J Am Ceram Soc 88:328710.1111/j.1551-2916.2005.00775.x ↗
10. Phair JW, Smith JD, Van Deventer JSJ (2003) Mater Lett 57:435610.1016/S0167-577X(03)00325-2 ↗
11. Gordon M, Bell JL, Kriven WM (2005) Ceram Trans 165:9510.1002/9781118408353.ch9 ↗
12. Xu H, Van Deventer JSJ (2000) Int J Miner Proc 59:24710.1016/S0301-7516(99)00074-5 ↗
13. Purdon AO (1940) J Soc Chem Ind Trans Commun 59:19110.1002/jctb.5000591202 ↗
14. Roy D (1999) Cem Conc Res 29:24910.1016/S0008-8846(98)00093-3 ↗
15. Iwahiro T, Nakamura Y, Komatsu R, Ikeda K (2001) J Eur Ceram Soc 21:251510.1016/S0955-2219(01)00273-4 ↗
16. Wagh AS (2005) Ceram Trans 165:10710.1002/9781118408353.ch10 ↗
17. Duxson P, Provis JL, Lukey GC, Mallicoat SW, Kriven WM, Van Deventer JSJ (2005) Colloid Surf A 269:4710.1016/j.colsurfa.2005.06.060 ↗
18. Duxson P, Mallicoat SW, Lukey GC, Kriven WM, Van Deventer JSJ (2006) Coll Surf A (in press), DOI: 10.1016/j.colsurfa.2006.05.04410.1016/j.colsurfa.2006.05.044 ↗
19. Rowles M, O’connor B (2003) J Mater Chem 13:116110.1039/b212629j ↗
20. Glukhovsky VD (1959) Soil silicates. Gosstroyizdat, Kiev, 154pp
21. Fernández-Jiménez A, Palomo A, Criado M (2005) Cem Conc Res 35:120410.1016/j.cemconres.2004.08.021 ↗
22. Fernández-Jiménez A, Palomo A, Sobrados I, Sanz J (2006) Micropor Mesopor Mater 91:11110.1016/j.micromeso.2005.11.015 ↗
23. Provis JL, Lukey GC, Van Deventer JSJ (2005) Chem Mater 17:307510.1021/cm050230i ↗
24. Provis JL, Duxson P, Van Deventer JSJ, Lukey GC (2005) Chem Eng Res Des 83:85310.1205/cherd.04329 ↗
25. Van Deventer JSJ, Provis JL, Duxson P, Lukey GC (2006) J Hazard Mater (in press), DOI 10.1016/j.jhazmat.2006.02.044
26. Blum AE, Lasaga AC (1988) Nature 331:43110.1038/331405a0 ↗
27. Walther JV (1996) Am J Sci 296:69310.2475/ajs.296.7.693 ↗
28. Oelkers EH (2001) Geochim Cosmochim Acta 65:370310.1016/S0016-7037(01)00710-4 ↗
29. Smith JV (1998) Proc Natl Acad Sci USA 95:336610.1073/pnas.95.7.3366 ↗
30. Swaddle TW Salerno J, Tregloan PA (1994) Chem Soc Rev 23:31910.1039/cs9942300319 ↗
31. Swaddle TW (2001) Coord Chem Rev 219:221–66510.1016/S0010-8545(01)00362-9 ↗
32. Aiello R, Crea F, Nastro A, Subotić B, Testa F (1991) Zeolites 11:76710.1016/S0144-2449(05)80054-5 ↗
33. Ivanova II, Aiello R, Nagy JB, Crea F, Derouane EG, Dumont N, Nastro A, Subotić B, Testa F (1994) Micropor Mater 3:24510.1016/0927-6513(94)00036-0 ↗
34. Faimon J (1996) Geochim Cosmochim Acta 60:290110.1016/0016-7037(96)00130-5 ↗
35. Provis JL, Van Deventer JSJ (2006) J Mater Sci (this issue)
36. Provis JL (2006) PhD Thesis, University Of Melbourne, 310pp
37. Duxson P, Lukey GC, Van Deventer JSJ (2006) J Mater Sci (this issue)
38. Lee WKW, Van Deventer JSJ (2002) Cem Conc Res 32:57710.1016/S0008-8846(01)00724-4 ↗
39. Alonso S, Palomo A (2001) Mater Lett 47:5510.1016/S0167-577X(00)00212-3 ↗
40. Yip CK, Lukey GC, Van Deventer JSJ (2003) Ceram Trans 153:18710.1002/9781118406892.ch13 ↗
41. Yip CK, Van Deventer JSJ (2003) J Mater Sci 38:385110.1023/A:1025904905176 ↗
42. Granizo ML, Alonso S, Blanco-Varela MT, Palomo A (2002) J Am Ceram Soc 85:22510.1111/j.1151-2916.2002.tb00070.x ↗
43. Duxson P (2006) PhD Thesis, University Of Melbourne, 287pp
44. Davidovits J (1988) In: Davidovits J, Orlinski J (eds) Proceedings of geopolymer ‘88—first European conference on soft mineralurgy. Universite De Technologie De Compeigne, Compeigne, France, pp 149–166
45. Duxson P, Lukey GC, Separovic F, Van Deventer JSJ (2005) Ind Eng Chem Res 44:83210.1021/ie0494216 ↗
46. Palomo A, Alonso S, Fernández-Jiménez A, Sobrados I, Sanz J (2004) J Am Ceram Soc 87:114110.1111/j.1551-2916.2004.01141.x ↗
47. Duxson P, Provis JL, Lukey GC, Separovic F, Van Deventer JSJ (2005) Langmuir 21:302810.1021/la047336x ↗
48. Klinowski J (1984) Prog NMR Spec 16:23710.1016/0079-6565(84)80007-2 ↗
49. Engelhardt G, Michel D (1987) High-resolution solid-state NMR of silicates and zeolites. Wiley, New York, 485pp
50. Lee SK, Stebbins JF (1999) Am Miner 84:93710.2138/am-1999-5-630 ↗
51. Provis JL, Duxson P, Lukey GC, Van Deventer JSJ (2005) Chem Mater 17:297610.1021/cm050219i ↗
52. Fernández-Jiménez A, De La Torre AG, Palomo A, López-Olmo G, Alonso MM, Aranda MAG (2006) Fuel 85:62510.1016/j.fuel.2005.08.014 ↗
53. Fernández-Jiménez A, De La Torre AG, Palomo A, López-Olmo G, Alonso MM, Aranda MAG (2006) Fuel 85: 196010.1016/j.fuel.2006.04.006 ↗
54. Kriven WM, Bell JL, Gordon M (2003) Ceram Trans 153:22710.1002/9781118406892.ch15 ↗
55. Barbosa VFF, Mackenzie KJD, Thaumaturgo C (2000) Int J Inorg Mater 2:30910.1016/S1466-6049(00)00041-6 ↗
56. Alonso S, Palomo A (2001) Cem Conc Res 31:2510.1016/S0008-8846(00)00435-X ↗
57. Brinker CJ, Scherer GW (1990) Sol-Gel science: the chemistry and physics of Sol-Gel processing. Academic, London, 980pp
58. Yang S, Navrotsky A, Phillips BL (2000) J Phys Chem B 104:607110.1021/jp9944278 ↗
59. Palomo A, Glasser FP (1992) Br Ceram Trans J 91:107
60. Van Jaarsveld JGS, Van Deventer JSJ (1999) Cem Conc Res 29:118910.1016/S0008-8846(99)00032-0 ↗
61. Barrer RM, Mainwaring DE (1972) J Chem Soc Dalton Trans 125410.1039/dt9720001254 ↗
62. Barrer RM, Mainwaring DE (1972) J Chem Soc Dalton Trans 253410.1039/dt9720002534 ↗
63. Barrer RM (1982) Hydrothermal chemistry of zeolites. Academic, London, 360pp
64. Baerlocher C, Meier WM, Olson DH (2001) Atlas of zeolite framework types, 5th revised edition. Elsevier, Amsterdam, 308pp10.1016/B978-044450701-3/50351-7 ↗
65. Provis JL, Duxson P, Lukey GC, Separovic F, Kriven WM, Van Deventer JSJ (2005) Ind Eng Chem Res 44:889910.1021/ie050700i ↗
66. Kollman PA, Kuntz ID (1972) J Am Chem Soc 94:923610.1021/ja00781a049 ↗
67. Swier S, Van Assche G, Van Hemelrijck A, Rahier H, Verdonck E, Van Mele B (1998) J Therm Anal 54:58510.1023/A:1010150711172 ↗
68. Palomo A, Fernández-Jiménez A, Criado M (2004) Mater Construc 54:7710.3989/mc.2004.v54.i275.249 ↗
69. Desiraju GR (2003) Nature 423: 48510.1038/423485a ↗
70. Corradini P, Auriemma F, De Rosa C (2006) Acc Chem Res 39:31410.1021/ar040288n ↗
71. Lee WKW, Van Deventer JSJ (2002) Colloid Surf A 211:4910.1016/S0927-7757(02)00237-6 ↗
72. Provis JL, P, Duxson, Lukey GC, Van Deventer JSJ (2005) Chem Mater 17:297610.1021/cm050219i ↗
73. Criado M, Fernández-Jiménez A, Palomo A (2007) Micropor Mesopor Mater (submitted)
74. Criado M, Fernández-Jiménez A, Palomo A, Sobrados I, J Sanz (2007) Micropor Mesopor Mater (submitted)
75. Svensson IL, Sjöberg S, Öhman LO (1986) J Chem Soc Faraday Trans I 82:363510.1039/f19868203635 ↗
76. Rahier H, Simons W, Van Mele B, Biesemans M (1997) J Mater Sci 32:223710.1023/A:1018563914630 ↗
77. Sindhunata, Van Deventer JSJ, Lukey GC, Xu H (2006) Ind Eng Chem Res 45:3559–7310.1021/ie051251p ↗
78. Criado M (2007) PhD Thesis, Eduardo Torroja Institute (in progress)
79. Mccormick AV, Bell AT, Radke CJ (1989) J Phys Chem 93:174110.1021/j100342a015 ↗
80. Lee WKW, Van Deventer JSJ (2003) Langmuir 19:872610.1021/la026127e ↗
81. Fernández-Jiménez A, Palomo A (2005) Cem Concr Res 35:198410.1016/j.cemconres.2005.03.003 ↗
82. Hos JP, Mccormick PG, Byrne LT (2002) J Mater Sci 37:231110.1023/A:1015329619089 ↗
83. Xu H, Van Deventer JSJ (2002) Miner Eng 15:113110.1016/S0892-6875(02)00255-8 ↗
84. Oelkers EH, Gislason SR (2001) Geochim Cosmochim Acta 65:367110.1016/S0016-7037(01)00664-0 ↗
85. Oelkers EH, Schott J, Devidal JL (1994) Geochim Cosmochim Acta 58:201110.1016/0016-7037(94)90281-X ↗
86. Xu H, Van Deventer JSJ (2003) Colloid Surf A 216:2710.1016/S0927-7757(02)00499-5 ↗
87. Van Jaarsveld JGS, Van Deventer JSJ (1999) Ind Eng Chem Res 38:393210.1021/ie980804b ↗
88. Fernández-Jiménez A, Palomo A, Criado M (2006) Mater Construc 56:51
89. Barrer RM, White EAD (1952) J Chem Soc 156110.1039/jr9520001561 ↗
90. Barrer RM, Baynham JW (1956) J Chem Soc 288210.1039/jr9560002882 ↗
91. Barrer RM, Mccallum N (1953) J Chem Soc 402910.1039/JR9530004029 ↗
92. Barrer RM, White EAD (1951) J Chem Soc 126710.1039/jr9510001267 ↗
93. Rahier H, Denayer JF, Van Mele B (2003) J Mater Sci 38:313110.1023/A:1024733431657 ↗
94. Cockrell CF, Muter RB, Leonard JW, Anderson RE (1970) Potential for recovering unreacted lime from limestone-modified fly ash by agglomerate. Coal Res. Bur.,West Virginia Univ., Morgantown, 267 pp
95. Fernández-Jiménez A, Palomo A (2005) Micropor Mesopor Mater 86:20710.1016/j.micromeso.2005.05.057 ↗
96. Keyte LM, Lukey GC, Van Deventer JSJ (2005) In: Nzihou A (ed) Wasteeng 2005. Albi, France. CD-ROM Proceedings
97. Fernández-Jiménez A, Palomo A (2003) Fuel 82:225910.1016/S0016-2361(03)00194-7 ↗
98. Ejaz T, Jones AG, Graham P (1999) J Chem Eng Data 44:57410.1021/je980164j ↗
99. Gasteiger HA, Frederick WJ, Streisel RC (1992) Ind Eng Chem Res 31:118310.1021/ie00004a031 ↗
100. Dent LS Glasser, Harvey G (1984) J Chem Soc Chem Commun 125010.1039/c39840001250 ↗