Research progress on rare earth-containing heat-resistant magnesium alloys
Source abstract
Abstract
Magnesium alloys hold considerable promise for lightweight structural applications due to their low density and high specific strength. However, their intrinsic hexagonal close-packed crystal structure results in a limited number of active slip systems, inadequate high-temperature strength, poor creep resistance, and pronounced flammability. These inherent drawbacks significantly restrict their utilization in demanding high-temperature and severe service environments, such as those encountered in aerospace and transportation sectors. To overcome these performance limitations, alloying with rare earth elements has proven to be an effective strategy. This article provides a detailed analysis of the regulatory effects and underlying mechanisms by which rare earth elements influence the microstructure of magnesium alloys. It further examines the critical roles and mechanisms by which RE additions significantly enhance properties such as creep resistance, superplasticity, fatigue life, and flame retardancy. The discussion also extends to the synergistic effects achieved by composite alloying with elements such as Al, Zn, and Ag, or by the incorporation of nanoparticle /metallic particles, which collectively contribute to multiple strengthening mechanisms. Future research should focus on the design of Mg alloys with low or even zero heavy rare earth content, the in-depth elucidation of multiscale structure-property relationships, the integration of advanced processing technologies, and the development of lifetime prediction models under extreme environments. These efforts will be essential for promoting the reliable application of magnesium alloys in a wider range of high-temperature structural scenarios.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Magnesium Alloys: Properties and Applications · Advanced Welding Techniques Analysis · Metallurgical and Alloy Processes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Comprehensive study of magnesium based metal matrix composite10.1016/j.matpr.2021.04.062 ↗
2. Magnesium research and applications: past, present and future10.1016/j.jma.2023.11.007 ↗
3. Development and prospects of degradable magnesium alloys for structural and functional applications in the fields of environment and energy10.1016/j.jma.2023.09.013 ↗
4. Fatigue characteristics of sand-cast AZ91D magnesium alloy10.1016/j.jma.2017.03.001 ↗
5. Enhanced ductility in high-pressure die casting Mg-4Ce-xAl-0.5Mn alloys via modifying second phase10.1016/j.msea.2019.138870 ↗
6. Effects of thermal treatment on microstructure and mechanical properties of a Mg-Gd-based alloy plate10.1016/j.msea.2016.02.032 ↗
7. A high-strength Mg-RE alloy fabricated by directed energy deposition: microstructural evolution and strengthening mechanism10.1016/j.msea.2025.148072 ↗
8. Current progress of research on heat-resistant Mg alloys: a review10.1007/s12613-023-2802-7 ↗
9. Regulating microstructure and improving precipitation hardening response of fine-grained Mg-RE-Ag hot-extruded alloy by extreme short-time heat treatment10.1016/j.msea.2023.146059 ↗
10. Quantitative prediction of Mg-RE-Ni alloy corrosion behavior by machine learning10.1016/j.corsci.2024.112324 ↗
11. Effects of La and Ce on the microstructure, thermal conductivity and strength synergy of the as-extruded Mg-Mn-RE alloys10.1016/j.jma.2024.05.022 ↗
12. Hazards and optimal utilization of iron in low-carbon recycled aluminum alloys10.1007/s12613-025-3271-y ↗
13. Effect of Y and Sm microalloying substituting 1 wt.% Ca on the evolution of laves phases and mechanical properties in Mg-Al-Ca alloys10.1016/j.jallcom.2026.186095 ↗
14. Effects of annealing on twin boundary segregation and strengthening in Mg–Gd alloys10.1016/j.jmrt.2025.12.321 ↗
15. Recrystallization behavior of Mg-Gd-Y-Zn-Zr alloys with minor Ag and Nd additions
16. Influence of Gd element content (9, 13 wt%) on the hot deformation behavior and microstructure evolution of Mg-Gd-Y-Zn-Zr alloys10.1016/j.jmrt.2025.10.161 ↗
17. Study on the synergistic effect of Y and Nd to significantly improve the corrosion resistance of Mg-Zn-Gd series alloy10.1016/j.jallcom.2025.181917 ↗
18. Simultaneous enhancement of strength and plasticity in extruded Mg-4Gd-0.5Zr alloys: tailoring grain size and precipitated phases via Nd and Y addition10.1016/j.jmrt.2025.09.155 ↗
19. Improving the mechanical properties of a WE54 magnesium alloy through severe friction stir processing and rapid cooling10.1016/j.msea.2022.143963 ↗
20. Evolution of the microstructure and mechanical properties of WE43 magnesium alloy during multipass hot rolling10.1007/s12613-024-2983-8 ↗
21. Improved grain refinement and thermal stability in wire arc additive manufactured Mg-RE-Al alloys via Al2RE heteronucleation10.1016/j.jallcom.2025.183432 ↗
22. Effect of Nd on microstructure and mechanical properties of Mg-7Gd-0.5Zr alloy10.1016/j.jallcom.2022.168278 ↗
23. Effect of cerium alloying on microstructure, texture and mechanical properties of magnesium during cold-rolling process10.1016/j.jre.2023.05.012 ↗
24. Microstructure and mechanical properties of repair welds of low-pressure sand-cast Mg–Y–RE–Zr alloy by tungsten inert gas welding10.1016/j.jma.2020.07.009 ↗
25. Effect of Ce on microstructure and corrosion behavior of as cast ZK60 alloy
26. Effects of samarium (Sm) additions on the microstructure and mechanical properties of as-cast and hot-extruded Mg-5wt%Al-3wt%Ca-based alloys10.1016/j.jallcom.2008.06.016 ↗
27. Enhancing overall static/dynamic/damping/ignition response of magnesium through the addition of lower amounts (<2%) of yttrium10.1016/j.jallcom.2016.07.324 ↗
28. Effect of Zr modification on solidification behavior and mechanical properties of Mg–Y–RE (WE54) alloy10.1016/j.jma.2013.12.001 ↗
29. Improvement in grain refinement efficiency of Mg–Zr master alloy for magnesium alloy by friction stir processing10.1016/j.jma.2014.09.001 ↗
30. Effect of ultrasonic treatment on the alloying and grain refinement efficiency of a Mg – Zr master alloy added to magnesium at hypo- and hyper-peritectic compositions10.1016/j.jcrysgro.2019.02.004 ↗
31. Engineering a more efficient zirconium grain refiner for magnesium
32. Exceptional grain refinement of Mg-Zr master alloy treated by tungsten inert gas arc re-melting with ultra-high frequency pulses10.1016/j.scriptamat.2022.114700 ↗
33. Genetic effects of Mg-Zr master alloy in extruded thick sheets of ZK60 magnesium alloy10.1016/j.matlet.2023.134084 ↗
34. Grain refinement of magnesium alloys by Mg–Zr master alloys: the role of alloy chemistry and Zr particle number density10.1002/adem.201200297 ↗
35. The loss of dissolved zirconium in zirconium-refined magnesium alloys after remelting10.1007/s11661-009-9928-8 ↗
36. Recent advances in the grain refinement effects of Zr on Mg alloys: a review10.3390/met12081388 ↗
37. Grain refinement of magnesium alloys10.1007/s11661-005-0030-6 ↗
38. Grain refinement of magnesium alloys by zirconium: formation of equiaxed grains10.1016/j.scriptamat.2005.11.002 ↗
39. Settling of undissolved zirconium particles in pure magnesium melts10.1016/S1471-5317(01)00009-8 ↗
40. Effect of soluble and insoluble zirconium on the grain refinement of magnesium alloys10.4028/www.scientific.net/MSF.419-422.593 ↗
41. Microstructural evolution and deformation mechanisms in pre-deformed Mg-RE alloys: from non-schmid twinning to stacking fault-dislocation interactions10.1016/j.jallcom.2026.186066 ↗
42. Rare-earth containing magnesium alloys: a review of precipitation behavior and its impact on fatigue performance10.1016/j.jma.2025.05.010 ↗
43. A Study of the Decomposition of Supersaturated Mg-Y-Nd, Mg“, and Mg-Nd Alloys/Eine Untersuchung des Zerfalls übersättigter Mg-Y-Nd-, Md-Y- und Mg-Nd-Legierungen10.1515/ijmr-1988-790511 ↗
44. Characterisation of strengthening precipitate phases in a Mg–Y–Nd alloy10.1016/S1359-6454(00)00013-6 ↗
45. A brand-new comprehension to the nucleation and growth of β 1 precipitate in rare earth magnesium alloys10.1016/j.jallcom.2023.171137 ↗
46. Nano-scale precipitation and phase growth in Mg-Gd binary alloy: an atomic-scale investigation using HAADF-STEM10.1016/j.matdes.2017.10.042 ↗
47. Precipitation in Mg-Sm binary alloy during isothermal ageing: atomic-scale insights from scanning transmission electron microscopy10.1016/j.msea.2016.05.096 ↗
48. Achieving high strength in ZK60 based Mg alloy with a low RE content though numerous precipitates10.1016/j.jallcom.2025.180118 ↗
49. Structure evolution of a WE43 Mg alloy submitted to different thermal treatments10.1016/j.msea.2007.06.016 ↗
50. Achieving high ductility and strength in magnesium alloy through cryogenic-hot forming10.1016/j.jma.2023.09.002 ↗
51. Deformation twinning in rolled WE43-T5 rare earth magnesium alloy: influence on strain hardening and texture evolution10.1016/j.actamat.2017.03.075 ↗
52. Fabrication of high-density twins and precipitates in a rare-earth magnesium alloy with superior work hardening and ultimate strength
53. Enhancing high-temperature mechanical performance of Mg-Gd-Y alloys via multi-pass cold rolling induced deformation twins10.1016/j.jallcom.2025.183859 ↗
54. The role of {10–12} tensile twinning in plastic deformation and fracture prevention of magnesium alloys10.1016/j.msea.2022.143678 ↗
55. Enhanced strength-ductility synergy achieved through twin boundary pinning in a bake-hardened Mg–2Zn-0.5Ca alloy10.1016/j.msea.2021.142239 ↗
56. Effect of rare earth element yttrium on migration behavior of twin boundary in magnesium alloys: a molecular dynamics study10.1016/j.jmrt.2023.04.202 ↗
57. Effect of yttrium on the twinning and plastic deformation of AE magnesium alloy under ballistic impact10.1016/j.msea.2014.11.025 ↗
58. Origin of profuse {1121} deformation twins in Mg-Gd alloys10.1016/j.scriptamat.2020.08.041 ↗
59. Effect of Sm on twinning behavior of Mg-Gd-Y-Zr alloy at room temperature compression10.1016/j.jmrt.2023.06.113 ↗
60. The influence of gadolinium concentration on the twin propagation rate in magnesium alloys10.1016/j.jallcom.2023.169635 ↗
61. Texture traits and mechanical anisotropy of AZ31 magnesium alloy sheet by hard plate cross rolling
62. The origin of “rare earth” texture development in extruded Mg-based alloys and its effect on tensile ductility10.1016/j.msea.2008.05.045 ↗
63. Competitive twinning behavior in magnesium and its impact on recrystallization and texture formation10.1016/j.msea.2017.09.053 ↗
64. Twin recrystallization mechanisms in magnesium-rare earth alloys10.1016/j.actamat.2015.05.044 ↗
65. Micro-alloying Mg with Y, Ce, Gd and La for texture modification—A comparative study10.1016/j.msea.2009.12.036 ↗
66. Quasi-in-situ observing the rare earth texture evolution in an extruded Mg-Zn-Gd alloy with bimodal microstructure10.1016/j.jma.2020.09.001 ↗
67. The texture and its optimization in magnesium alloy10.1016/j.jmst.2019.10.010 ↗
68. Tensile-compressive yield asymmetries in high strength wrought magnesium alloys10.1016/0956-716X(94)90159-7 ↗
69. Effect of rare earth additions on microstructure and texture development of magnesium alloy sheets10.1016/j.scriptamat.2009.12.033 ↗
70. Grain growth and texture evolution during annealing in an indirect-extruded Mg–1Gd alloy10.1016/j.jallcom.2013.09.028 ↗
71. Explaining texture weakening and improved formability in magnesium rare earth alloys10.1179/1743284714Y.0000000632 ↗
72. Mechanistic origin of the enhanced strength and ductility in Mg-rare earth alloys10.1016/j.actamat.2022.118550 ↗
73. Research progress on texture regulation of rare-earth magnesium alloys10.3390/solids6010011 ↗
74. Hot deformation behavior and microstructure evolution of Mg–Gd–Sm(–Zn)–Zr alloys10.1007/s12613-024-2982-9 ↗
75. Unusual twin induced recrystallization and corresponding texture optimization in a cold rolled Mg-Gd-Zr alloy during annealing10.1016/j.jma.2024.04.015 ↗
76. Simultaneous enhancement of extrudability and mechanical properties in a new Mg-Al-Mn-Ca-Ce alloy via multi-element microalloying and pre-treatment10.1016/j.jallcom.2025.185868 ↗
77. Enhancing the strength and stiffness of hot-extruded Mg-Al-Zn-Cu-Ca alloys via tailoring Al content10.1016/j.jallcom.2025.185327 ↗
78. Effects of pre-compression on formation of dynamic precipitates and creep anisotropy of hot-extruded AZ91—2Y magnesium alloy10.1016/S1003-6326(22)66038-2 ↗
79. Creep behavior and microstructure evolution of heat-resistant Mg-Sm-Yb-Zn-Zr alloy10.1016/j.msea.2022.143358 ↗
80. On the exceptional creep resistance in a die-cast Gd-containing Mg alloy with Al addition10.1016/j.actamat.2022.117957 ↗
81. New HPDC Mg-RE based alloy with exceptional strength and creep resistance at elevated temperature10.1016/j.msea.2022.142921 ↗
82. Creep behavior and precipitation evolution of Mg-13Gd-2Y-0.5Zr alloy10.1016/j.matchar.2024.113868 ↗
83. Creep behavior and dynamic precipitation of highly heat-resistant Mg alloy with low rare-earth content10.1016/j.jallcom.2024.174960 ↗
84. Fabrication of exceptionally high-strength Mg-4Sm-0.6Zn-0.4Zr alloy via low-temperature extrusion10.1016/j.msea.2021.142565 ↗
85. Significant improvement in creep property of a Mg–Yb based alloy via introducing nano-spaced stacking faults10.1016/j.msea.2022.143238 ↗
86. Current development of creep-resistant magnesium cast alloys: a review10.1016/j.matdes.2018.06.032 ↗
87. A comparative study on the effects of Gd, Y and La rare-earth elements on the microstructure and creep behavior of AZ81 Mg alloy10.1016/j.msea.2020.139712 ↗
88. Tensile creep mechanisms of laser powder bed fused WE43 alloy with heterogeneous microstructure: evolution in dislocations and precipitates10.1016/j.jmst.2025.02.063 ↗
89. A review of superplastic magnesium alloys: focusing on alloying strategy, grain structure control and deformation mechanisms10.1016/j.jmst.2024.06.002 ↗
90. Critical review of superplastic magnesium alloys with emphasis on tensile elongation behavior and deformation mechanisms10.1016/j.jma.2022.02.009 ↗
91. Enhanced superplasticity of ultrafine-grained WEQ612 magnesium alloy via the coupling effect of grain boundary segregation and dense precipitation10.1016/j.msea.2024.146337 ↗
92. Excellent superplastic properties achieved in Mg–4Y–3RE alloy in high strain rate regime10.1016/j.msea.2020.139314 ↗
93. Achieving excellent superplasticity in an ultrafine-grained QE22 alloy at both high strain rate and low-temperature regimes10.1016/j.jallcom.2018.02.294 ↗
94. Superplastic behavior of an ultrafine-grained Mg-13Zn-1.55Y alloy with a high volume fraction of icosahedral phases prepared by high-ratio differential speed rolling10.1016/j.jmst.2017.05.003 ↗
95. Superplastic deformation mechanisms of coarse-grained rolled Mg-4Y-3RE magnesium alloy10.1016/j.jma.2024.11.006 ↗
96. Creep strength of Mg-Y-Zn alloys containing long-period stacking ordered structures10.1016/j.jallcom.2025.180110 ↗
97. Superplastic behavior and microstructure evolution of a fine-grained Mg-Nd-Zn-Zr alloy processed by hot extrusion10.1016/j.msea.2022.143314 ↗
98. Effects of bimodal-grained microstructure on the superplasticity of a Mg-Gd-based alloy10.1016/j.jmst.2026.04.039 ↗
99. Study on the competitive mechanisms of pre-tension strengthening and fatigue damage in AZ31B magnesium alloy10.1016/j.ijfatigue.2025.109326 ↗
100. Enhancing plastic deformability of Mg and its alloys—A review of traditional and nascent developments10.1016/j.jma.2017.11.001 ↗