journal article·2026-07Open access

Atmospheric plasma spray yttria stabilized zirconia - lanthanum zirconate composite coated inconel −718: High temperature erosive wear studies

A. Balamurugan, P. Jeyapandiarajan

Abstract

High temperature erosion is a critical degradation mechanism influencing the durability of thermal barrier coatings in aerospace and energy applications. The aerospace industry is advancing the development of new TBC materials to improve resistance to high temperature erosion. In this study, atmospheric plasma spray technique (APS) was used to deposit composite TBC on Inconel-718 substrate. Four coating systems, namely 100%YSZ, 100%LZ, 80%YSZ/20%LZ, and 60%YSZ/40%LZ, were applied over a NiCrAlY bond coat. As sprayed coatings were characterized using XRD, FESEM, surface roughness, hardness and porosity to evaluate phase stability and microstructural features. Erosion tests were conducted at 1000°C under impact angles of 30° and 90°. The coatings were evaluated based on mass loss per unit erodent mass. The substrate exhibited the highest erosion rates of 4.581 g/kg at 30° and 4.201g/kg at 90°, due to its lower hardness and absence of a protective microstructure. Among the coatings, YSZ exhibited the lowest erosion rates of 2.038 g/kg (30°) and 2.208 g/kg (90°) due to its dense microstructure and strong inter splat bonding, while LZ exhibited higher erosion rates of 3.135 g/kg (30°) and 3.220 g/kg (90°) due to increased porosity and brittle fracture. The composite coatings showed intermediate performance, with 80%YSZ/20%LZ demonstrating improved resistance (2.261g/kg and 2.423g/kg), whereas 60%YSZ/40%LZ exhibited higher erosion (2.781 and 3.051 g/kg). Failure analysis indicated brittle fracture, splat delamination, and interlamellar delamination as dominant mechanisms. These findings highlight the importance of composite coatings in enhancing erosion resistance of APS deposited TBC.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: High-Temperature Coating Behaviors · Erosion and Abrasive Machining · Advanced ceramic materials synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (56)

Show source-provided references
1. Nanostructured thermal barrier coatings: enhancing performance for high-temperature applications: a comprehensive review
2. Microstructure development and mold metal reactions during investment casting of nickel superalloys—a review10.1007/s00170-025-16579-4 ↗
3. In-situ TiC particle-reinforced Hastelloy X superalloy fabricated by laser additive manufacturing10.1016/j.jmrt.2025.03.161 ↗
4. A review on the thermal barrier coatings in hot corrosion protection: innovations and future directions for high-temperature alloys10.1007/s11668-025-02185-9 ↗
5. The role of La and Nd in enhancing CMAS corrosion resistance of high-entropy (La, Nd, Tm, Yb, Lu)2Zr2O7 thermal barrier coating materials10.1016/j.jeurceramsoc.2025.117466 ↗
6. Investigation of ternary rare earth oxide-doped YSZ and its high temperature stability10.1016/j.jallcom.2019.07.198 ↗
7. Composite ceramics thermal barrier coatings of yttria stabilized zirconia for aero-engines10.1016/j.jmst.2019.08.003 ↗
8. Thermophysical properties and cyclic lifetime of plasma sprayed SrAl 12 O 19 for thermal barrier coating applications10.1111/jace.17319 ↗
9. Thermal insulation properties of YSZ coatings: suspension Plasma Spraying (SPS) versus Electron beam Physical vapor deposition (EB-PVD) and atmospheric Plasma Spraying (APS)10.1016/j.surfcoat.2016.06.010 ↗
10. HVOF-sprayed AlSi50 alloy coatings as a novel electrothermal Anti-icing/De-icing system for polymer-based composite structures10.1007/s11666-021-01243-6 ↗
11. Improve durability of plasma-splayed thermal barrier coatings by decreasing sintering-induced stiffening in ceramic coatings10.1016/j.jeurceramsoc.2019.11.074 ↗
12. The effect of high strain rate impact in Yttria stabilized zirconia10.1016/j.matdes.2023.111908 ↗
13. Microstructure evolution and thermochemical interaction of dysprosia stabilized zirconia with CMAS attack10.1016/j.matchar.2025.115331 ↗
14. Degradation of LaPO4-8YSZ composite thick thermal barrier coatings by molten calcium-magnesium-aluminosilicate10.1016/j.jeurceramsoc.2024.116863 ↗
15. Low thermal conductivity and thermal radiation of La2Zr2O7 ceramics with hierarchical structure above 1000 K10.1016/j.ceramint.2023.05.136 ↗
16. Rare earth oxides stabilized La2Zr2O7 TBCs: EB-PVD, thermal conductivity and thermal cycling life10.1016/j.surfcoat.2018.10.045 ↗
17. Lanthanum zirconate ceramic toughened by ferroelastic domain switching of LaAlO310.1016/j.ceramint.2018.06.016 ↗
18. Effects of atom- and phase-scale compressive stress on fracture toughness in yttrium-doped lanthanum zirconate solid solutions10.1016/j.ceramint.2018.01.062 ↗
19. Evaluation of high temperature oxidation behavior of LZ, CSZ, and LZ-CSZ composite thermal barrier coatings10.1016/j.ceramint.2023.10.039 ↗
20. Influence of nano-Y2O3 addition on microstructure, mechanical properties, and oxidation resistance of laser-directed energy deposited Inconel 62510.1016/j.jallcom.2026.187224 ↗
21. Comparative study of the sintering behaviors between YSZ and LZ/YSZ composite10.1016/j.matlet.2016.12.105 ↗
22. The effect of sintering temperature on the microstructure and phase transformation in tetragonal YSZ and LZ/YSZ composites10.1016/j.ceramint.2015.10.046 ↗
23. Study on thermal, mechanical, microstructural properties and failure analyses of lanthanum zirconate based thermal barrier coatings: a review10.1016/j.matpr.2021.02.672 ↗
24. Erosion behavior of YSZ, LZC, and LZC/YSZ double-ceramic-layers thermal barrier coatings by EB-PVD under high-temperature gas streams with entrained solid particles
25. Crack-healing behaviour of MoSi2 dispersed Yb2Si2O7 environmental barrier coatings10.1016/j.ceramint.2022.06.258 ↗
26. Porosity and microstructural features of plasma sprayed Yttria stabilized Zirconia thermal barrier coatings10.1016/j.ceramint.2015.07.102 ↗
27. Study on intrinsic mechanical behavior and erosion resistance of multi-rare earth doped La2Zr2O7 coating10.1016/j.triboint.2023.108551 ↗
28. Erosion of atmospheric plasma sprayed rare earth oxide coatings under air suspended corundum particles10.1016/j.ceramint.2012.06.077 ↗
29. Particle erosion behavior of La2(ZrxCe1-x)2O7/YSZ double ceramic layers TBCs deposited by electron beam-physical vapor deposition
30. A chemo-thermo-mechanically constitutive theory for thermal barrier coatings under CMAS infiltration and corrosion10.1016/j.jmps.2019.103710 ↗
31. Comparison of CMAS corrosion and sintering induced microstructural characteristics of APS thermal barrier coatings10.1016/j.jmst.2018.09.046 ↗
32. Effect of reflectivity and porosity analysis of plasma sprayed lanthanum zirconate/yttria stabilized zirconia based thermal barrier coating: design of experimental approach10.1007/s12008-025-02235-4 ↗
33. Optimization of plasma spray process variables to attain the minimum porosity and maximum hardness of the LZ/YSZ thermal barrier coatings utilizing the response surface approach10.1088/2053-1591/ac8857 ↗
34. Impact of atmospheric plasma spraying parameters on microstructure, mechanical properties and thermal cycling performance of YSZ coatings10.1016/j.ceramint.2024.10.253 ↗
35. Microstructural characterization of modified plasma spray LZ/YSZ thermal barrier coating by laser glazing10.1016/j.matpr.2020.04.145 ↗
36. Sintering behavior and phase transformation of YSZ-LZ composite coatings10.1016/j.ceramint.2019.09.093 ↗
37. High entropy alloy bond coats for thermal barrier coatings: a review10.1007/s11666-023-01701-3 ↗
38. Thermal expansion and solubility limits of cerium-doped lanthanum zirconates10.1016/j.jallcom.2012.02.077 ↗
39. Interface failure behavior of yttria stabilized zirconia (YSZ), La2Zr2O7, Gd2Zr2O7, YSZ/La2Zr2O7 and YSZ/Gd2Zr2O7 thermal barrier coatings (TBCs) in thermal cyclic exposure10.1016/j.matchar.2019.110072 ↗
40. Service life assessment of yttria stabilized zirconia (YSZ) based thermal barrier coating through wear behaviour10.1016/j.heliyon.2023.e16107 ↗
41. Mechanical and tribological properties of Alumina toughened Zirconia composites through conventional sintering and microwave sintering10.1007/s12666-020-02001-y ↗
42. Production and characterization of Nd and Dy doped lanthanum zirconate-based thermal barrier coatings10.1016/j.surfcoat.2020.125864 ↗
43. Evolution of microstructural and mechanical properties of lanthanum zirconate thermal barrier coatings at high temperature10.1016/j.surfcoat.2014.07.067 ↗
44. Influence of powder states on the composition and phase stability of LZ/YSZ composite thermal barrier coatings10.1016/j.ceramint.2018.08.015 ↗
45. The deformation behavior and fracture toughness of single crystal YSZ(111) by indentation10.1016/j.jallcom.2017.12.022 ↗
46. Thermal and mechanical properties of crack-designed thick lanthanum zirconate coatings10.1016/j.jeurceramsoc.2013.10.018 ↗
47. Influence of micro–structure on erosion resistance of plasma sprayed 7YSZ thermal barrier coating under gas turbine operating conditions10.1016/j.wear.2017.11.005 ↗
48. Thermal conductivity and erosion durability of composite two-phase air plasma sprayed thermal barrier coatings10.1016/j.surfcoat.2015.08.010 ↗
49. Influence of particle shape on erosion behavior of EB-PVD thermal barrier coatings10.1016/j.ceramint.2021.12.074 ↗
50. The effect of TBC morphology on the erosion rate of EB PVD TBCs10.1016/j.wear.2004.04.011 ↗
51. Stress states and crack behavior in plasma sprayed TBCs based on a novel lamellar structure model with real interface morphology10.1016/j.ceramint.2019.05.243 ↗
52. Assessment of the solid particle erosion resistance, microstructure and failure mechanism of calcia, magnesia, and yttria-stabilized zirconia thermal barrier coatings10.1007/s41779-025-01265-1 ↗
53. Properties evolution of plasma-sprayed La2Zr2O7 coating induced by pore structure evolution during thermal exposure10.1016/j.ceramint.2016.06.201 ↗
54. Interplay between cracking and delamination in incrementally deposited plasma sprayed coatings10.1016/j.actamat.2021.117074 ↗
55. Fracture toughness of freestanding plasma sprayed yttria stabilized zirconia coatings via in situ tensile experiments10.1016/j.jeurceramsoc.2023.10.074 ↗
56. Optimization of laser process parameters and improved corrosion behaviour of LZ/YSZ thermal barrier coating10.1007/s41779-025-01149-4 ↗