journal article·2026-05Open access

Corrosion behavior of Fe-based amorphous alloys in liquid lead-bismuth eutectic at 500°C

Yansong Yang, Jiawei Zhang, Chen Su, Siming Xiao, Chengquan Zhang, Limin Cai, Pengcheng Zhang, Shengfeng Guo

Abstract

Lead-cooled fast reactors (LFRs) represent a key direction of fourth-generation nuclear power technology, where the core challenge lies in the compatibility between structural materials and liquid lead-bismuth eutectic (LBE). At high temperatures, LBE tends to induce severe dissolution and oxidation corrosion in materials, while traditional crystalline alloys are difficult to meet long-term safe service requirements due to the presence of corrosion-sensitive sites, such as grain boundaries and dislocations. Fe-based amorphous alloys, with their unique structure without grain boundaries and dislocations, have demonstrated promising application potential in the field of structural coatings for LFRs. This study systematically investigated the corrosion behavior of two new types of amorphous alloys, Fe 44 Cr 23 W 10 C 13.5 B 7.5 Y 2 (Cr 23 ) and Fe 37 Cr 30 W 10 C 13.5 B 7.5 Y 2 (Cr 30 ), in static LBE at 500°C, and compared with the traditional amorphous alloy Fe 48 Cr 15 Mo 14 C 15 B 6 Y 2 . The results show that the Cr 30 amorphous alloy exhibits the best corrosion resistance, which is mainly attributed to the high Cr and W contents that synergistically promote the formation of a dense corrosion layer of Cr 2 O 3 , Fe(Fe x Cr 1-x ) 2 O 4 , and XWO 4 , enhancing the corrosion resistance of the amorphous alloy against liquid lead-bismuth.
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Research context

OpenAlex topics: Metallic Glasses and Amorphous Alloys · Nuclear reactor physics and engineering · Thermodynamic and Structural Properties of Metals and Alloys

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (34)

Show source-provided references
1. Examining the advantages and disadvantages of nuclear energy
2. Natural circulation studies in a lead bismuth eutectic loop10.1016/j.pnucene.2010.10.004 ↗
3. Long-term corrosion of austenitic steels in flowing LBE at 400°C and 10-7 mass% dissolved oxygen in comparison with 450 and 550°C10.1016/j.jnucmat.2015.09.027 ↗
4. Transmission electron microscopy study of complex oxide scales on DIN 1.4970 steel exposed to liquid Pb-Bi eutectic10.1016/j.corsci.2018.10.018 ↗
5. A review of steel corrosion by liquid lead and lead-bismuth10.1016/j.corsci.2009.03.013 ↗
6. Ferritic/martensitic steels for next-generation reactors10.1016/j.jnucmat.2007.05.005 ↗
7. Oxidation resistance in LBE and air and tensile properties of ODS ferritic steels containing Al/Zr elements10.1016/j.jnucmat.2014.07.028 ↗
8. Si-containing 9Cr ODS steel designed for high temperature application in lead-cooled fast reactor10.1016/j.jnucmat.2019.03.029 ↗
9. Al rich PVD protective coatings: a promising approach to prevent T91 steel corrosion in stagnant liquid lead10.1016/j.surfcoat.2019.124890 ↗
10. Investigation of mechanical properties and Lead-bismuth eutectic corrosion resistance of Al2O3 coatings doped Silicon10.1016/j.jmrt.2025.05.148 ↗
11. Revealing different corrosion behaviors of Cr-containing refractory high-entropy alloy coatings in static liquid lead–bismuth eutectic10.1016/j.matdes.2024.113192 ↗
12. Additive manufactured ODS-FeCrAl steel achieves high corrosion resistance in lead-bismuth eutectic (LBE)10.1016/j.jnucmat.2024.155516 ↗
13. Electrodeposition of Ni-Mo alloys and composite coatings: a review and future directions10.1016/j.jmapro.2024.03.099 ↗
14. High temperature oxidation behavior of MoCoB metallic glass10.1016/j.matchar.2024.113858 ↗
15. High temperature oxidation behaviors of Ir-Ni-Ta-(B) metallic glass10.1016/j.corsci.2022.110420 ↗
16. Superior corrosion resistance of high-temperature Ir-Ni-Ta-(B) amorphous alloy in sulfuric acid solution10.1016/j.corsci.2022.110227 ↗
17. Perspectives on novel refractory amorphous high-entropy alloys in extreme environments
18. Design of Fe-based bulk metallic glasses with improved wear resistance10.1021/acsami.8b11561 ↗
19. Current status and development trends of corrosion research in Fe-based amorphous alloys10.1007/s10853-025-11558-2 ↗
20. Effect of Fe content on the soft Magnetic properties of Fe-rich FeSiBC amorphous alloy10.1134/S1063783424601085 ↗
21. Magnetic properties evaluation of Fe-based amorphous alloys synthesized via spark plasma Sintering10.1016/j.jnoncrysol.2023.122373 ↗
22. Ternary Fe-W-B bulk metallic glasses with ultrahigh thermal stabilities10.1016/j.msea.2021.142034 ↗
23. Effect of W on the thermal stability, mechanical properties and corrosion resistance of Fe-based bulk metallic glass10.1016/j.intermet.2022.107485 ↗
24. Fe-based bulk metallic glass with high thermal stability and corrosion resistance10.1016/j.jnoncrysol.2024.123176 ↗
25. FeCrMoWCBY metallic glass with high corrosion resistance in molten lead-bismuth eutectic alloy10.1016/j.corsci.2021.109688 ↗
26. FeCr-based bulk metallic glasses with enhanced wear and corrosion Resistance
27. XPS analysis of oleylamine/oleic acid capped Fe3O4 nanoparticles as a function of temperature10.1016/j.apsusc.2014.02.006 ↗
28. Environmental degradation of structural materials in liquid lead- and lead-bismuth eutectic-cooled reactors10.1016/j.pmatsci.2022.100920 ↗
29. Corrosion and irradiation behavior of Fe-based amorphous coating in lead-bismuth eutectic liquids10.1007/s11431-021-1938-0 ↗
30. Corrosion behavior of T91 steel in liquid Lead-bismuth eutectic at 550°C: effects of exposure time and dissolved oxygen Concentration10.1016/j.corsci.2022.110405 ↗
31. A comparative study on the corrosion performance of four FeCrAl alloys with different Cr contents in contact with Oxygen-saturated LBE10.1016/j.jmrt.2023.02.033 ↗
32. Insights into LBE corrosion behavior of the FeCrAlTi and FeCrAlNb coatings10.1016/j.corsci.2025.113475 ↗
33. Fe-based amorphous coating prepared using high-velocity oxygen fuel and its corrosion behavior in static lead-bismuth eutectic alloy10.1007/s12613-022-2420-9 ↗
34. Co-WO3 composite coating on ferritic stainless steel interconnects10.1016/j.corcom.2023.06.001 ↗