Rapid equiaxed Cu3Sn formation and high-temperature reliability of transient liquid phase bonding with an Sn/2 μm Cu/Sn preform
Source abstract
Abstract
Cu–Sn-based transient liquid phase (TLP) bonding has attracted significant attention for packaging inverter power modules, key components of electric vehicles. The Cu–Sn intermetallic compound (IMC) joints formed by TLP bonding offer excellent high-temperature stability but typically require long bonding times and high pressures. Moreover, the final Cu 3 Sn phase often develops columnar grains that degrade joint reliability. This study addresses these challenges by employing a Sn/2 μm Cu/Sn laminated solder preform, fabricated by inserting a 2 μm Cu foil between Sn foils, to bond a Cu chip to a direct bonded Cu substrate. The laminated preform enabled complete transformation of Sn into equiaxed Cu 3 Sn grains within 20 min, producing a stable, homogeneous TLP-bonded joint. After thermal aging at 150 °C for 1008 h, the joints retained shear strengths above 30 MPa. The suppression of columnar Cu 3 Sn growth was attributed to rapid consumption of the ultrathin Cu interlayer, which terminated Cu flux and promoted equiaxed nucleation at the joint center. These results demonstrate that the Sn/2 μm Cu/Sn laminated solder preform enabled rapid IMC formation while facilitating morphological control of Cu 3 Sn, ensuring improved long-term reliability. This approach offers a practical pathway for high-temperature, high-reliability interconnections in next-generation power electronic packaging.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Electronic Packaging and Soldering Technologies · 3D IC and TSV technologies · Copper Interconnects and Reliability
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (47)
Show source-provided references
1. Metallurgical and mechanical properties of transient liquid phase bonded joints formed using Sn/Ni-foam hybrid preforms10.1016/j.matchemphys.2024.130340 ↗
2. Review of silicon carbide power devices and their applications10.1109/TIE.2017.2652401 ↗
3. A review of SiC power module packaging technologies: challenges, advances, and emerging issues10.1109/JESTPE.2019.2951801 ↗
4. Silver-sintered joint properties between silicon carbide device and ceramic substrate for electric vehicle power modules10.1007/s11664-018-6769-5 ↗
5. Advanced materials for high-temperature, high-performance, wide-bandgap power modules10.1007/s11664-015-4187-5 ↗
6. Wide band gap semiconductor devices for power electronic converters
7. Physical and electrical properties of silicon nitride thin films with different nitrogen–oxygen ratios10.3390/nano15130958 ↗
8. High-field breakdown and thermal characterization of indium tin oxide transistors10.1021/acsnano.5c01572 ↗
9. Wide bandgap extrinsic photoconductive switches10.1109/TPS.2008.2002147 ↗
10. A survey of wide bandgap power semiconductor devices10.1109/TPEL.2013.2268900 ↗
11. A multiple-phase-shift control for a SiC-Based EV charger to optimize light-load efficiency, current stress, and power quality10.1109/JESTPE.2018.2820064 ↗
12. Development of high-power SiC devices for rail traction power systems10.1016/j.jcrysgro.2018.10.037 ↗
13. Extreme high efficiency enabled by silicon carbide power devices10.1016/j.mssp.2023.108052 ↗
14. Evaluation of high-temperature long-term reliability of transient liquid phase bonded joints using etched Cu Foam/Sn–3.0Ag–0.5Cu composite solder preform10.1007/s10854-024-13132-z ↗
15. Effects of creep failure mechanisms on thermomechanical reliability of solder joints in power semiconductors10.1109/TPEL.2020.2973312 ↗
16. Overview study of solder joint reliability due to creep deformation10.1017/jmech.2018.20 ↗
17. Transient liquid phase bonding for solder: a short review10.1088/1757-899X/701/1/012050 ↗
18. Exploring intermetallic compounds: properties and applications in catalysis10.3390/catal14080538 ↗
19. Analytical modelling of transient liquid phase diffusion bonding when a temperature gradient is imposed10.1016/S1359-6454(99)00234-7 ↗
20. Reliability of Ag-Sintering and Sn–Ag TLP bonding for mounting of SiC and GaN devices
21. Reliability investigation of Cu/In transient liquid phase bonding10.1007/s11664-014-3373-1 ↗
22. Critical interlayer thickness for transient liquid phase bonding in the Cu–Sn system10.1016/j.actamat.2004.02.043 ↗
23. A review of intermetallic compound growth and void formation in electrodeposited Cu–Sn layers for microsystems packaging10.1007/s10854-021-05412-9 ↗
24. Fabrication of cu@Sn transient liquid phase sintering joints for high-temperature power electronics applications10.1039/D2RA04606G ↗
25. Advanced power semiconductor packaging for automotive systems
26. Review of packaging schemes for power modules10.1109/JESTPE.2019.2947645 ↗
27. A review on recent advances in transient liquid phase bonding for thermoelectric power modules10.1515/rams-2018-0011 ↗
28. A study of the growth rate of Cu–Sn intermetallic compounds during isothermal aging for transient liquid phase bonding
29. The next-generation of high-voltage (10 kV) silicon carbide power modules
30. Defect formation and mitigation in Cu/Cu joints formed through transient liquid phase bonding with Cu–Sn nanocomposite interlayers10.1016/j.microrel.2022.114681 ↗
31. Young's modulus of (Cu,Ag)–Sn intermetallics measured by nanoindentation10.1016/j.msea.2003.08.032 ↗
32. Shear strength and fracture mechanisms for full Cu–Sn intermetallic solder joints with different Cu3Sn proportions and joints with conventional interfacial structure in electronic packaging10.1108/SSMT-06-2018-0018 ↗
33. Cu3Sn joints based on transient liquid phase bonding of Cu@Cu6Sn5 core–shell particles10.1038/s41598-023-27870-3 ↗
34. The fast formation of Cu–Sn intermetallic compounds in Cu/Sn/Cu systems by induction heating10.1016/j.matlet.2017.12.102 ↗
35. Formation mechanism and orientation of Cu3Sn grains in Cu–Sn intermetallic compound joints10.1016/j.matlet.2013.07.116 ↗
36. Non-interfacial growth of Cu3Sn in Cu/Sn/Cu joints during ultrasonic-assisted transient liquid phase soldering process10.1016/j.matlet.2016.10.017 ↗
37. Columnar grain boundaries are the weakest link in hard coatings: insights from micro-cantilever testing10.1080/21663831.2025.2560526 ↗
38. Formation of equiaxed grains in selective laser melted pure titanium during annealing10.1016/j.jmrt.2021.01.008 ↗
39. Temperature-controlled gas hydrate nucleation in the heterogeneous environments10.1021/acs.jpclett.4c03074 ↗
40. Grain growth sequence of Cu3Sn in Cu/Sn and Cu/Sn–Zn systems10.1016/j.jallcom.2010.01.038 ↗
41. Coupled finite element–cellular automaton model for the prediction of dendritic grain structures in solidification processes10.1016/0956-7151(94)90302-6 ↗
42. Phase-field models in materials science10.1088/0965-0393/17/7/073001 ↗
43. Transient liquid phase bonding process using Sn-Coated Cu dendritic particles10.1007/s12540-020-00702-z ↗
44. Transient liquid phase bonding using Cu foam and Cu–Sn paste for high-temperature applications10.1016/j.jmrt.2023.10.184 ↗
45. Microstructure and mechanical properties of transient liquid phase bonded joints with lotus-type porous Cu interlayer10.1016/j.jmrt.2025.08.237 ↗
46. Microstructure evolution and grain orientation of IMC in Cu–Sn TLP bonding solder joints10.1016/j.jallcom.2019.01.384 ↗
47. Microstructural and mechanical characteristics of Cu–Sn intermetallic compound interconnects formed by TLPB with Cu–Sn nanocomposite