journal article·2026-05Open access

Effect of Mn alloying on the microstructure and compression performances of in-situ bonding Al–4Cu–1Ca foam-filled tubes

Jicheng Fan, Xixian Ge, Zhanhao Feng, Yutian Li, Mingxi Sun, Hanzhe Wen, Guoyin Zu

Abstract

For melt foaming prepared Al–Cu foam, in which Calcium (Ca) was used as a thickening agent, the formation of strengthening phases (θ-Al 2 Cu) was prevented, and T phases (Al–Cu–Ca intermetallics) were formed. In this work, the microstructural evolution and compression performance of the in-situ bonding Al–4Cu–1Ca foam-filled tubes (FFT) with various Manganese (Mn) contents were studied. Through microstructure characterization and compression performance test, the refinement of grains, the evolution of the grid-like eutectic and precipitated phases, and the compression properties of Al–4Cu–1Ca FFTs due to Mn alloying were discussed. The strengthening and plasticity-improving mechanism of Mn alloying was revealed. The results show that Al 6 Mn phases were formed in the as-foamed Al–4Cu–1Ca alloys with the Mn addition. The Al 6 Mn phases serve as the precipitation sites for the T phases, resulting in the refinement of the T phases. For the Al–4Cu–1Ca–1.0Mn FFT, the energy absorption and specific energy absorption reached 15.59 MJ/m 3 and 23.05 kJ/kg, respectively. This study aims to develop an efficient strategy for achieving in-situ bonding of Al–4Cu–1Ca FFTs with superior energy absorption performance, while simultaneously overcoming the strength–plasticity trade-off.
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Research context

OpenAlex topics: Cellular and Composite Structures · Aluminum Alloys Composites Properties · Aluminum Alloy Microstructure Properties

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References (36)

Show source-provided references
1. Microstructural damage behaviour of Al foams10.1016/j.actamat.2021.116739 ↗
2. Mechanical behavior of heat-treated Al-Cu-Mg open-cell foams10.1016/j.matlet.2020.129021 ↗
3. Microstructural and mechanical characterization of quasicrystalline Al-Cu-Fe foams
4. Numerical simulation of aluminum foam and its composite structures under impact loads: from geometric models to engineering applications10.1016/j.matdes.2025.114921 ↗
5. A predictive model for strain hardening and inertia effect of aluminum tubes filled with aluminum foam10.1016/j.compstruct.2022.116177 ↗
6. The temperature effect on the axial quasi-static compressive behavior of ex-situ aluminum foam-filled tubes10.1016/j.compstruct.2017.08.034 ↗
7. Effects of calcium on mechanical properties of cellular Al–Cu foams10.1016/j.msea.2014.09.051 ↗
8. Effect of Si content on precipitation and age-hardening response of Al-Cu-Mg alloy10.1016/j.jallcom.2025.183542 ↗
9. Micro-alloying-driven transformation mechanisms of T1p to T1 in Al-Cu-Li-Mg-Ag alloys10.1016/j.actamat.2025.121371 ↗
10. Er-microalloying mediated hot-crack healing and grain boundary segregation engineering in Al-Cu-Mg-Zr alloy via laser powder bed fusion10.1016/j.msea.2025.148966 ↗
11. Synergistic enhancement of mechanical and thermo-physical properties in Al-2Mn-xNi alloys via Ni content variation10.1016/j.jallcom.2025.179589 ↗
12. Strength and stability through variable micro segregation behaviour of Ta and Zr solutes at intermetallic interfaces in Al-Cu alloys10.1016/j.actamat.2023.119254 ↗
13. Coupled segregation mechanisms of Sc, Zr and Mn at θ′ interfaces enhances the strength and thermal stability of Al-Cu alloys10.1016/j.actamat.2021.116634 ↗
14. Precipitation behavior of stress-aged Al-Cu-Mg-Ag alloy bicrystals10.1016/j.jallcom.2025.179135 ↗
15. Aging behavior, microstructure and mechanical properties of Al-Cu-Mg alloy matrix composites reinforced with carbon nanotubes10.1016/j.msea.2024.147174 ↗
16. Trace Ca alloying enhance simultaneously strength and ductility of squeeze-cast Al-5Cu-0.5Mn-based alloys10.1016/j.jmst.2023.11.075 ↗
17. Fabrication of bilayer tube consisting of outer aluminum foam tube and inner dense aluminum tube by friction stir back extrusion10.1016/j.mtcomm.2018.02.017 ↗
18. The effect of outer tube on quasi-static compression behavior of aluminum foam-filled tubes10.1016/j.compstruct.2020.112357 ↗
19. Processing of in-situ aluminium foam-filled stainless steel tube with foam-tube bonding for enhanced crashworthiness10.1016/j.jmapro.2022.08.020 ↗
20. A novel approach for fabricating in situ aluminum foam-filled carbon steel tubes via hot-dip aluminizing10.1002/adem.202402446 ↗
21. Aluminum alloy foam-filled aluminum tube fabricated by friction stir back extrusion and its compression properties10.1016/j.compstruct.2017.04.048 ↗
22. Stabilisation of aluminium foams and films by the joint action of dispersed particles and oxide films10.1016/j.actamat.2015.07.064 ↗
23. Nucleation and growth of gas bubbles in AlSi8Mg4 foam investigated by X-ray tomoscopy10.1016/j.actamat.2020.116583 ↗
24. Compressive properties and energy absorption behavior of Mg17Al12/Al ordered structure composites10.1016/j.compositesb.2021.108688 ↗
25. Stability mechanism of AlSi12 aluminum foam under the action of Al–Si–Ca second phase10.1016/j.jmrt.2021.02.038 ↗
26. Enhancing thermal stability and strengthening mechanism of Al-Cu alloy via synergistic segregation of Cr, Mn, and Zr at Al/θ′ interface10.1016/j.matdes.2025.114454 ↗
27. Effect of in situ bonding on microstructure and compression performance of aluminum foam-filled tubes10.1002/adem.202502041 ↗
28. Manufacturing and compressive properties of sandwich foam tubes containing metal syntactic foam10.1016/j.compstruct.2023.117012 ↗
29. Compressive behavior and energy absorption analysis of casting skin-wrapped aluminum foams
30. Manufacturing and compressive properties of tube-filled metal syntactic foams10.1016/j.jallcom.2019.153465 ↗
31. Transverse and longitudinal crushing of aluminum-foam filled tubes10.1016/S1359-6462(02)00024-6 ↗
32. Evolution of micropores and second phases during hot deformation of 2050 Al-Li alloy10.1016/j.jallcom.2023.173166 ↗
33. Effects of Mg addition on the Al6(Fe,Mn) intermetallic compounds and the grain refinement of α-Al in Al-Fe-Mn alloys10.1016/j.matchar.2020.110758 ↗
34. Impact of homogenization on particles in the Al–Mg–Mn alloy AA 5454 – experiment and simulation10.1016/j.jallcom.2013.01.163 ↗
35. Orientation relationship between Al6Mn precipitates and the Al matrix during continuous recrystallization in Al-1.3%Mn10.1107/S0021889899010870 ↗
36. A yield strength model for the Al-Mg-Si-Cu alloy AA611110.1016/S1359-6454(03)00028-4 ↗