The role of Ti addition in AA6061 fabricated by LPBF and its influence on mechanical and thermal properties
Source abstract
Abstract
Grain refinement is one of the most efficient strategies to mitigate hot cracking in additively manufactured aluminum alloys (AAs), achieved through the addition of potent nucleates or solutes. While prior studies have demonstrated success in suppressing hot cracks in 6xxx series AAs fabricated by laser powder bed fusion (LPBF), the combined effects of grain refiners and heat treatment on microstructure, mechanical, and thermal properties remain insufficiently explored. In this work, Ti was deliberately selected as a peritectic-forming solute due to its strong segregation tendency in Al and the low lattice misfit of Al 3 Ti with the Al matrix. Primary L1 2 -Al 3 Ti particles formed predominantly in the fine equiaxed grain regions near melt-pool boundaries, serving as heterogeneous nucleation sites and effectively refining grains in AA6061. Grain size decreased with increasing Ti content and growth restriction factor ( Q ), though the relationship between grain size and 1/Q was non-linear. Post-T6 heat treatment induced partial recrystallization, enhanced thermal conductivity, and eliminated Lüders and Portevin–Le Chatelier (PLC) bands in stress–strain curves of Ti-modified AA6061. Finally, Kou's criterion and freezing-range-based criteria were found inadequate for evaluating hot cracking susceptibility in Ti-modified AA6061 under LPBF, indicating that grain-refinement effects should be explicitly considered in future RDG-based or other crack-susceptibility models.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Aluminum Alloys Composites Properties · Aluminum Alloy Microstructure Properties · Powder Metallurgy Techniques and Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (88)
Show source-provided references
1. 3D printing of Aluminium alloys: additive manufacturing of Aluminium alloys using selective laser melting10.1016/j.pmatsci.2019.100578 ↗
2. Additive manufacturing of metallic components – process, structure and properties10.1016/j.pmatsci.2017.10.001 ↗
3. Microstructural analysis and defect characterization of additively manufactured AA6061 aluminum alloy via laser powder bed fusion10.1016/j.jmst.2024.08.056 ↗
4. Material-structure-performance integrated laser-metal additive manufacturing10.1126/science.abg1487 ↗
5. Stefanescu · 2004 · 71
6. A Quest for a new hot tearing criterion10.1007/s11661-007-9169-7 ↗
7. A high strength Al–Li alloy produced by laser powder bed fusion: densification, microstructure, and mechanical properties
8. Solidification crack propagation and morphology dependence on processing parameters in AA6061 from ultra-high-speed x-ray visualization
9. Böllinghaus · 2008 · 1
10. Lippold · 2014
11. Cracking mechanism and its sensitivity to processing conditions during laser powder bed fusion of a structural aluminum alloy10.1016/j.mtla.2020.100976 ↗
12. Effect of substrate thickness and preheating on the distortion of laser deposited Ti–6Al–4V10.1115/1.4038890 ↗
13. Investigation on reducing distortion by preheating during manufacture of aluminum components using selective laser melting10.2351/1.4828755 ↗
14. The effect of selective laser melting process parameters on the microstructure and mechanical properties of Al6061 and AlSi10Mg alloys10.3390/ma12010012 ↗
15. Processing and characterization of crack-free aluminum 6061 using high-temperature heating in laser powder bed fusion additive manufacturing
16. On the thermal coarsening and transformation of nanoscale oxide inclusions in 316L stainless steel manufactured by laser powder bed fusion and its influence on impact toughness
17. Effect of high-temperature preheating on pure copper thick-walled samples processed by laser powder bed fusion10.1016/j.jmapro.2021.11.035 ↗
18. Explosion characteristics and suppression analysis of AlSi12 powder used in additive manufacturing10.1016/j.jlp.2024.105439 ↗
19. Design approaches for printability-performance synergy in Al alloys for laser-powder bed additive manufacturing
20. Exploiting the rapid solidification potential of laser powder bed fusion in high strength and crack-free al-cu-mg-mn-zr alloys
21. Grain refinement of aluminum and aluminum alloys by Sc and Zr10.3390/met13040751 ↗
22. Grain refinement mechanisms in additively manufactured nano-functionalized aluminum10.1016/j.actamat.2020.09.043 ↗
23. Dilatant shear bands in solidifying metals10.1038/nature05426 ↗
24. Mechanical properties in the semi-solid state and hot tearing of aluminium alloys10.1016/S0079-6425(03)00037-9 ↗
25. Recent advances in inoculation treatment for powder-based additive manufacturing of aluminium alloys10.1016/j.mser.2024.100773 ↗
26. Grain refinement of aluminum alloys part II confirmation of, and a mechanism for, the solute paradigm10.1007/s11661-999-0099-4 ↗
27. Grain refinement of aluminum alloys part I the nucleant and solute paradigms A review of the literature10.1007/s11661-999-0098-5 ↗
28. The Interdependence Theory: the relationship between grain formation and nucleant selection10.1016/j.actamat.2011.04.035 ↗
29. Demonstrating the roles of solute and nucleant in grain refinement of additively manufactured aluminium alloys
30. A quantitative model to determine the Ti content for crack-free AlCuMg alloy in laser powder-bed fusion10.1016/j.jmapro.2024.12.059 ↗
31. Inoculation treatment of an additively manufactured 2024 aluminium alloy with titanium nanoparticles10.1016/j.actamat.2020.06.026 ↗
32. Unveiling the heat-resistant mechanism of an additively manufactured Ag– and Ti-modified al–cu–mg alloy10.1007/s12598-025-03263-5 ↗
33. Grain refinement and crack inhibition of selective laser melted AA2024 aluminum alloy via inoculation with TiC–TiH2
34. Enhanced strength and ductility in al-zn-mg-cu alloys fabricated by laser powder bed fusion using a synergistic grain-refining strategy10.1016/j.jmst.2021.12.078 ↗
35. The role of TiH2 on microstructure and mechanical properties of al–zn–mg–cu alloy fabricated by laser powder bed fusion
36. Superior mechanical properties of a selective-laser-melted AlZnMgCuScZr alloy enabled by a tunable hierarchical microstructure and dual-nanoprecipitation10.1016/j.mattod.2021.11.019 ↗
37. Process-dependent composition, microstructure, and printability of al-zn-mg and al-zn-mg-sc-zr alloys manufactured by laser powder bed fusion10.1007/s11661-020-05768-3 ↗
38. Understanding the effect of tailored heat treatment on Zr-modified Al7075 fabricated by laser powder bed fusion10.1016/j.matdes.2025.114553 ↗
39. The crack healing effect of scandium in aluminum alloys during laser additive manufacturing10.1016/j.jmapro.2019.12.050 ↗
40. A solution to the hot cracking problem for aluminium alloys manufactured by laser beam melting10.1016/j.actamat.2020.07.015 ↗
41. Additive manufacturing and mechanical properties of the dense and crack free Zr-modified aluminum alloy 6061 fabricated by the laser-powder bed fusion
42. Design and characterization of al–mg–si–zr alloys with improved laser powder bed fusion processability10.1007/s11661-021-06531-y ↗
43. Processing of aluminum alloy 6182 with high scanning speed in LPBF by In-Situ alloying with Zr and Ti powder10.3390/alloys1030018 ↗
44. Grain refinement of laser remelted Al-7Si and 6061 aluminium alloys with tibor® and scandium additions10.1016/j.jmapro.2018.08.030 ↗
45. Synergistic enhancement of mechanical strength and thermal conductivity in a novel al-mg-si-zr-ce alloy fabricated by powder bed fusion-laser beam
46. CALPHAD aided design of a crack-free al-mg-si-ti alloy with high strength: heterogeneous nucleation and eutectic filling during additive manufacturing10.1080/17452759.2024.2378930 ↗
47. Effect of the precipitation of secondary phases on the thermal diffusivity and thermal conductivity of Al-4.5Cu alloy10.1016/j.jallcom.2016.07.137 ↗
48. Thermal conductivity of aluminum Alloys-A review10.3390/ma16082972 ↗
49. Research progress on the aluminum alloy with high thermal conductivity10.4028/www.scientific.net/AMM.574.396 ↗
50. Grain refinement of 316L stainless steel through in-situ alloying with Ti in additive manufacturing10.1016/j.msea.2022.142912 ↗
51. Revisiting the role of peritectics in grain refinement of Al alloys10.1016/j.actamat.2012.09.075 ↗
52. Synthesis and characterization of in situ formed titanium diboride particulate reinforced AA7075 aluminum alloy cast composites10.1016/j.matdes.2012.08.008 ↗
53. 2018
54. Modelling of inoculation of metallic melts application to grain refinement of aluminium by Al-Ti-B10.1016/S1359-6454(00)00094-X ↗
55. An analytical model for constitutional supercooling-driven grain formation and grain size prediction10.1016/j.actamat.2010.01.052 ↗
56. An analysis of the relationship between grain size, solute content, and the potency and number density of nucleant particles10.1007/s11661-005-0054-y ↗
57. Criteria for developing castable, creep-resistant aluminum-based alloys – a review10.1515/ijmr-2006-0042 ↗
58. Alloy design strategy for microstructural-tailored scandium-modified aluminium alloys for additive manufacturing10.1016/j.scriptamat.2021.114277 ↗
59. AlMgScZr alloys for laser powder bed fusion additive manufacturing
60. Defects in metal additive manufacturing processes10.1007/s11665-021-05919-6 ↗
61. Direct evidence of melting and decomposition of TiC particles in laser powder bed fusion processed 316L-TiC composite10.1016/j.jmst.2024.02.035 ↗
62. Melt pool dynamics and pore formation in selective laser melting: mechanisms and microstructural insights10.1016/j.matdes.2025.114043 ↗
63. Modeling radiation induced segregation in iron–chromium alloys10.1016/j.actamat.2015.09.058 ↗
64. Grain boundary segregation and precipitation in Aluminium Alloy AA606110.4028/www.scientific.net/MSF.519-521.467 ↗
65. Electron microscopy analysis of grain boundaries and intergranular corrosion in aged al-mg-si alloy doped with 0.05 wt% Cu
66. Effect of artificial aging on intergranular corrosion of extruded AlMgSi alloy with small Cu content10.1016/j.corsci.2005.05.045 ↗
67. Insights into grain refinement of al-mn-fe-si alloy via in situ reaction during laser directed energy deposition10.1016/j.jallcom.2025.178983 ↗
68. The development of grain structure during additive manufacturing10.1016/j.actamat.2021.116862 ↗
69. Towards understanding grain nucleation under Additive manufacturing solidification conditions10.1016/j.actamat.2020.05.012 ↗
70. The role of side-branching in microstructure development in laser powder-bed fusion10.1038/s41467-020-14453-3 ↗
71. Strength-ductility synergy of selective laser melted al-mg-sc-zr alloy with a heterogeneous grain structure
72. Effect of laser rescanning on the grain microstructure of a selective laser melted al-mg-zr alloy10.1016/j.matchar.2018.03.033 ↗
73. Compositional criteria to predict columnar to equiaxed transitions in metal additive manufacturing10.1038/s41467-025-60162-0 ↗
74. Achieving submicron grains in additively manufactured 304L-TiB2 metal matrix composite via in-situ reaction and Zener pinning10.1016/j.msea.2025.149497 ↗
75. Current issues in recrystallization: a review10.1016/S0921-5093(97)00424-3 ↗
76. Enhanced strengthening and hardening via self-stabilized dislocation network in additively manufactured metals10.1016/j.mattod.2021.06.002 ↗
77. Aging responses of an Al-Cu alloy fabricated by selective laser melting
78. The influence of shearable and nonshearable precipitates on the Portevin-Le chatelier behavior in precipitation hardening AlMgScZr alloys10.1016/j.ijplas.2021.103120 ↗
79. On the estimation of true hall–petch constants and their role on the superposition law exponent in Al alloys10.1002/adem.201200114 ↗
80. Quantitative prediction of solute strengthening in aluminium alloys10.1038/nmat2813 ↗
81. Ab initio study of compositional trends in solid solution strengthening in metals with low Peierls stresses10.1016/j.actamat.2015.07.054 ↗
82. Hatch · 1984
83. Developing a high-strength al-mg-si-sc-zr alloy for selective laser melting: Crack-inhibiting and multiple strengthening mechanisms10.1016/j.actamat.2020.03.060 ↗
84. Al-Cu-Ce(-Zr) alloys with an exceptional combination of additive processability and mechanical properties
85. A criterion for cracking during solidification10.1016/j.actamat.2015.01.034 ↗
86. A new hot-tearing criterion10.1007/s11661-999-0334-z ↗
87. The beneficial effect of minor iron additions on the crack susceptibility of rapidly solidified aluminum alloy 6060 toward additive manufacturing applications10.1016/j.matchar.2023.113287 ↗
88. Advances in nano-inoculant grain refinement for fusion-based additive manufacturing of Al and Ti alloys10.1016/j.matdes.2025.114581 ↗