journal article·2025-11Open access

High-performance single-crystal copper growth technology for volume manufacturing

Mengfan Wang, Shuaijie Liang, Yaoxing Ji, Qingyan Xu, Xuefeng Zhang, Mingxiang Liu, Hailong Wang, Jilin He

Abstract

Single-crystal copper (SCC) has become a critical material for high-performance electronic, thermal, and mechanical applications due to its excellent physical properties. However, scalable production of high-performance SCC remains a significant challenge. In this work, we report a novel, high-efficiency approach for the rapid growth of large-size SCC using an optimized Czochralski (CZ) method. By introducing a high-flow-rate cold argon gas system and precise thermal gradient control, we achieved a record crystal size of φ108×270 mm and a growth rate of 67.5 mm/h, surpassing previously reported CZ-based growth rates by more than twentyfold. Comprehensive structural characterization confirms the [220]-oriented single-crystal nature with exceptional orientation uniformity and atomic-scale integrity. The resulting SCC exhibits ultra-high purity (99.99995%), high electrical conductivity (106.68% IACS), and excellent mechanical ductility (elongation ∼104.4%). This work provides a scalable and cost-effective route for the industrial-grade production of SCC and offers a foundational strategy for its integration into advanced electronics, communication, and functional device manufacturing.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Microstructure and mechanical properties · Solidification and crystal growth phenomena · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Colossal grain growth yields single-crystal metal foils by contact-free annealing10.1126/science.aao3373 ↗
2. Production of single-crystal Cu plates by electrodeposition on high-index Cu foils10.1016/j.scib.2023.06.023 ↗
3. Single-crystallization of electrolytic copper foils10.1016/j.jmst.2023.07.039 ↗
4. Microstructure and properties of single crystal copper prepared by hot type horizontal continuous casting process10.1016/j.msea.2025.147924 ↗
5. Single-crystal Cu(111) foil preparation by direct bonding technology10.1016/j.apsusc.2024.159375 ↗
6. Fabrication of bulk single crystals via texture-engineered grain growth
7. The development of columnar grain and single crystal high temperature materials through directional solidification10.1016/0025-5416(70)90050-9 ↗
8. A horizontal bridgman method for growing batches of oriented copper single crystals10.1016/0022-0248(72)90137-6 ↗
9. Pilot-scale casting of single-crystal copper wires by the Ohno continuous casting process10.1007/BF00351555 ↗
10. Seeded growth of large single-crystal copper foils with high-index facets10.1038/s41586-020-2298-5 ↗
11. Preparation, properties, and applications of near stoichiometric lithium tantalate crystals10.3390/cryst13071031 ↗
12. Preparation and defect structure analysis of near-stoichiometric lithium tantalate wafers10.1039/D2RA02775E ↗
13. Micro-defects in Ge doped Czochralski grown Si crystals10.1016/j.jcrysgro.2006.04.010 ↗
14. Subramanian · 2025 · vol. 25 · 1075
15. Growth of nickel single crystals with a diameter of 8 in. using the Czochralski method10.1016/j.jcrysgro.2021.126271 ↗
16. Single crystal growth of FeGa3 and FeGa3-xGex from high-temperature solution using the czochralski method10.1002/crat.201900067 ↗
17. Copper better than silver: electrical resistivity of the grain-free single-crystal copper wire10.1021/cg1003808 ↗
18. Growth of copper single crystal using cone die Czochralski method10.1016/j.jcrysgro.2024.127957 ↗
19. Evaluating cooling tube effects on defect formation and distribution in Czochralski crystal growth10.1007/s10854-024-13093-3 ↗
20. Optimizing cooling strategies in the Czochralski process for large-diameter silicon ingots
21. High-quality graphene directly grown on Cu nanoparticles for Cu-graphene nanocomposites10.1016/j.matdes.2017.11.010 ↗
22. Epitaxial growth of a 100-square-centimetre single-crystal hexagonal boron nitride monolayer on copper10.1038/s41586-019-1226-z ↗
23. Microstructure and texture evolution of cold drawing <110> single crystal copper10.1007/s11431-011-4349-5 ↗
24. Facet effect on the reconstructed Cu-catalyzed electrochemical hydrogenation of 5-hydroxymethylfurfural (HMF) towards 2,5-bis (hydroxymethy)furan (BHMF)10.1016/j.jechem.2023.05.003 ↗
25. Li · 2021 · vol. 8
26. Ultrafast epitaxial growth of metre-sized single-crystal graphene on industrial Cu foil10.1016/j.scib.2017.07.005 ↗
27. Designed growth of large bilayer graphene with arbitrary twist angles10.1038/s41563-022-01361-8 ↗
28. Horizontal lithium growth driven by surface dynamics on single crystal Cu(111) foil
29. Fabrication of high-quality single-crystal Cu thin films using radio-frequency sputtering10.1038/srep06230 ↗
30. Wafer-scale single-crystal monolayer graphene grown on sapphire substrate10.1038/s41563-021-01174-1 ↗
31. Texture evolution and its influence mechanism on properties of single crystal copper and polycrystalline copper during cumulative deformation10.1016/j.jmrt.2023.04.264 ↗
32. On the experimental characterization of crystal plasticity in polycrystals10.1016/S0921-5093(02)00278-2 ↗
33. Stress and grain growth in thin films10.1016/0022-5096(96)00022-1 ↗
34. Grain refinement and its effect of polycrystalline metals during high strain rate deformation: crystal plasticity modeling10.1016/j.jmst.2024.12.030 ↗
35. Corrosion resistance and mechanism of (100), (110) and (111) preferred orientation of single crystal copper in NaCl solution10.1016/j.ijoes.2023.100378 ↗
36. Enhanced plastic deformability of copper single crystals under low-frequency vibrational loading10.1016/j.msea.2022.143458 ↗
37. Electrical conduction behavior in multiscale microstructure of Y micro-alloyed single-crystal copper processing wires
38. Interaction of Y and impurity P on the synergistic enhancement of elongation and electrical conductivity of single crystal copper rod10.1016/j.matdes.2023.112586 ↗