journal article·2025-11Open access

Inclusion degeneration and resultant coarsening in a Ce-treated 9% Cr heat-resistant steel during electroslag remelting

Shijun Wang, Gen Li, Zaoyu Li, Peng Xu, Huasong Liu, Lei Jia, Xikou He, Zhengdong Liu

Abstract

The evolution of inclusions in a 12-ton Ce-treated 9%Cr martensitic heat-resistant steel during vacuum induction melting and electroslag remelting was investigated. The addition of Ce in VIM converted Al 2 O 3 and Al 2 O 3 ·SiO 2 inclusions into finer Ce 2 O 3 and Ce 2 O 2 S, reducing the average inclusion size from 2.29 μm to 2.01 μm. However, the reaction between dissolved Ce and slag Al 2 O 3 during ESR caused a significant decrease in Ce content and degenerated the inclusions into CeAlO 3 , leading to the coarsening of inclusions. Thermodynamic calculations using the Ion-Molecule Coexistence Theory showed that reducing Al 2 O 3 content in slag while increasing Ce 2 O 3 content can partially suppress the reaction between Ce and Al 2 O 3 , thereby mitigating Ce oxidation during ESR. Based on FactSage simulations, maintaining Ce content between 0.005 and 0.02 wt% in the ESR ingot is essential to avoid the formation of harmful inclusions such as CeAlO 3 and Al 2 O 3 .
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Metallurgical Processes and Thermodynamics · Microstructure and Mechanical Properties of Steels · Iron and Steelmaking Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (41)

Show source-provided references
1. Generation-IV nuclear power: a review of the state of the science10.1016/j.enpol.2008.09.059 ↗
2. Safeguard assessment for life extension in nuclear power plants (NPPs) using a production function10.1016/j.nucengdes.2011.01.022 ↗
3. Implementing nuclear power plants (NPPs): state of the art, challenges, and opportunities10.1007/s41062-021-00611-z ↗
4. Defects as a root cause of fatigue failure of metallic components
5. Kolpishon · 2010 · 489
6. The low-cycle fatigue life assessment method for online monitoring of steam turbine rotors10.1016/j.ijfatigue.2018.02.032 ↗
7. The effect of Ce addition on purification and inclusion modification of CoCrFeNiMn high entropy alloy10.1016/j.jallcom.2022.167716 ↗
8. Effect of Ce addition on inclusions and grain structure in gear steel 20CrNiMo
9. Transformation behavior of primary carbides in M35 high-speed steel during the heating process before forging10.1007/s11837-025-07391-2 ↗
10. Cerium's role in transformation of inclusions and precipitated phases in Ferrium M54 steel ingots10.1016/j.jre.2025.02.020 ↗
11. Evolution mechanisms of MgO-Al2O3 inclusions by cerium in spring steel used in fasteners of high-speed railway10.2355/isijinternational.55.970 ↗
12. Study on transverse-longitudinal fatigue properties and their effective-inclusion-size mechanism of hot rolled bearing steel with rare earth addition10.1016/j.ijfatigue.2019.105193 ↗
13. Experimental and DFT study on cerium inclusions in clean steels10.1016/j.jre.2020.07.021 ↗
14. Abe · 2007
15. Effect of microstructural evolution on high-temperature strength of 9Cr-3W-3Co martensitic heat resistant steel under different aging conditions10.1016/j.msea.2013.09.033 ↗
16. Yield of Y, La, Ce in high temperature alloy during electroslag remelting process10.1051/metal/2016017 ↗
17. Reoxidation of liquid steel and evolution of inclusions during protective atmosphere electroslag remelting of Ce-containing heat-resistant stainless steel
18. Cooling rate-dependent microstructural evolution: segregation and precipitated phase in S30432 steel for ultra-supercritical power plants10.1016/j.jmrt.2025.04.002 ↗
19. Investigation of inclusion characteristics in Ferrosilicon killed high silicon steels10.1002/srin.202400331 ↗
20. Effect of yttrium addition timing on inclusion evolution and grain growth behavior in spring steel 55SiCr10.1016/j.jmrt.2025.01.163 ↗
21. Evolutions of micro-and macrostructure by cerium treatment in as-cast AISI M42 high-speed steel10.1007/s11663-020-01912-x ↗
22. Effect of cerium on the primary carbides and inclusions in electroslag remelted M35 high speed steel10.1016/j.jmrt.2023.05.044 ↗
23. Agglomeration of non-metallic inclusions at the Steel/Ar interface: model application10.1007/s11663-017-0998-5 ↗
24. Agglomeration characteristics of various inclusions in Al-killed molten steel containing rare Earth element10.1007/s11663-020-01938-1 ↗
25. Effect of cerium on solidification structure and eutectic precipitates in electroslag remelted Cr–W–Co martensitic heat-resistant steel10.1007/s11663-024-03293-x ↗
26. Influence of cerium on impact toughness, tensile properties and inclusion of industrial Al-killed steel Q355B10.1016/j.jmrt.2024.07.143 ↗
27. activities in CaO-SiO2-Al2O3 slags and deoxidation equilibria of Si and Al10.1007/s11663-996-0008-9 ↗
28. Influence of cerium treatment on inclusion modification and as-cast microstructure of high-strength low-alloy steel10.1007/s42243-022-00751-1 ↗
29. Mass transfer in the electroslag process: part 1. Mass transfer model
30. Changes in composition during A.C. ESR
31. Thermodynamic analysis of the oxidation behavior of cerium in high-speed steel during electroslag remelting10.1002/srin.202300824 ↗
32. 1988
33. The thermodynamics of liquid dilute iron alloys10.1179/msc.1974.8.1.298 ↗
34. Evolution and formation of non-metallic inclusions during electroslag remelting of a heat-resistant steel for ultra-supercritical power plants10.1007/s11663-022-02589-0 ↗
35. Evolution of nonmetallic inclusions during the electroslag remelting process10.1002/srin.202000629 ↗
36. Non-metallic inclusions in electroslag remelting: a review10.1007/s42243-021-00700-4 ↗
37. Effect of cerium content on inclusions in an ultra-low-carbon aluminum-killed steel10.1007/s11663-020-01779-y ↗
38. Kinetics on formation, growth, and removal of alumina inclusions in molten steel10.2355/isijinternational.ISIJINT-2021-475 ↗
39. Nucleation and growth kinetics of inclusions during liquid steel deoxidation10.1179/030192303225001766 ↗
40. Wang · 2015
41. Investigation on the control of rare earth content and surface quality of ingot during electroslag remelting process10.1177/03019233241298618 ↗