journal article·2025-11Open access

Wettability and brazing of (MoNbTaVW)C high-entropy carbide by Ni and NiTa

Naser Hosseini, Fabrizio Valenza, Zdeněk Chlup, Sofia Gambaro, Filip Šiška, Carla Malinverni, Jie Xu, Valentina Casalegno, Alexandra Kovalčíková, Monika Tatarková, Milena Salvo, Xiaobing Zhou, Ivo Dlouhý, Peter Tatarko

Abstract

This study aimed to design and validate a suitable brazing filler for the joining of (MoNbTaVW)C High-Entropy Carbides (HECs). CALPHAD calculations were used to analyse phase equilibria of ternary C-Ni-M (M: Mo, Ta, W) systems at 1480 °C and to select a suitable alloy composition for brazing. Wettability and high-temperature interactions with the HEC substrates were investigated using the sessile drop technique. While pure Ni provided a good wetting (≤ 15°) but an excessive dissolution, the Ni 83 Ta 17 alloy exhibited a comparable wetting with a significantly reduced dissolution due to the formation of interfacial TaC x -rich phases. Consequently, the NiTa alloy was employed as a filler to braze HEC ceramics using a pressure-less field-assisted sintering technique (FAST) furnace at 1480 °C, resulting in a crack-free, homogeneous joint. The interfacial TaC x -rich phase exhibited a high nano-hardness (∼ 24 GPa) and indentation elastic modulus (∼ 311 GPa). Single-lap offset shear tests confirmed a very high strength of the joints (∼ 220 MPa), demonstrating the viability of the NiTa alloy for joining HEC.
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Research context

OpenAlex topics: Advanced materials and composites · High Entropy Alloys Studies · Metal and Thin Film Mechanics

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References (62)

Show source-provided references
1. Mechanical and tribological performance of (TiNbTaWMo)C high-entropy ceramics in a wide temperature range10.1016/j.jmrt.2023.04.220 ↗
2. High-entropy carbide ceramics: a perspective review10.1007/s42864-021-00085-7 ↗
3. Nanoindentation and tribology of a (Hf-Ta-Zr-Nb-Ti)C high-entropy carbide10.1016/j.jeurceramsoc.2021.05.002 ↗
4. Hierarchical porous (Ta 0.2 Nb 0.2 Ti 0.2 Zr 0.2 Hf 0.2)C high-entropy ceramics prepared by a self-foaming method for thermal insulation10.26599/JAC.2024.9220909 ↗
5. High-entropy rare-earth diborodicarbide: a novel class of high-entropy (Y 0.25 Yb 0.25 Dy 0.25 Er 0.25)B 2 C 2 ceramics10.26599/JAC.2023.9220765 ↗
6. A review of high-entropy ceramics preparation methods, properties in different application fields and their regulation methods10.1016/j.jmrt.2024.07.153 ↗
7. Processing and properties of high-entropy ultra-high temperature carbides10.1038/s41598-018-26827-1 ↗
8. High entropy carbide ceramics from different starting materials10.1016/j.jeurceramsoc.2019.04.006 ↗
9. Preparation of high-entropy carbides by different sintering techniques10.1007/s10853-021-06004-y ↗
10. Wear behavior of (Mo–Nb–Ta–V–W)C high‐entropy carbide10.1111/ijac.14111 ↗
11. Phase, microstructure and related mechanical properties of a series of (NbTaZr)C-Based high entropy ceramics10.1016/j.ceramint.2021.02.013 ↗
12. Recent advances in joining of SiC-based materials (monolithic SiC and SiCf/SiC composites): joining processes, joint strength, and interfacial behavior10.1007/s40145-018-0297-x ↗
13. Fast seamless joining of SiC w/Ti 3 SiC 2 composite using electric field‐assisted sintering technique10.1111/ijac.13799 ↗
14. Joining of SiC ceramics using high-silicon aluminum alloy fillers assisted by laser cladding10.1016/j.jmrt.2023.04.215 ↗
15. Interfacial microstructure evolution and mechanical properties of Al2O3/Al2O3 joints brazed with Ti–Ni–Nb filler metal10.1016/j.jmrt.2023.04.088 ↗
16. Thickness-dependent phase evolution and bonding strength of SiC ceramics joints with active Ti interlayer10.1016/j.jeurceramsoc.2016.12.009 ↗
17. A yttrium aluminosilicate glass-ceramic to join SiC/SiC composites10.1016/j.jeurceramsoc.2023.12.095 ↗
18. Joining of β-SiC by spark plasma sintering10.1016/j.jeurceramsoc.2013.12.023 ↗
19. Brazing transparent YAG to Ti6Al4V: reactivity and characterization10.1016/j.jeurceramsoc.2016.05.022 ↗
20. Wetting and brazing of YIG ceramics using Ag–CuO–TiO2 metal filler10.1016/j.jmrt.2020.12.080 ↗
21. Recent advances in active metal brazing of ceramics and process10.1007/s12540-019-00536-4 ↗
22. Brazing of Ti-coated SiC using a CoFeCrNiCu high entropy alloy filler via electric field-assisted sintering10.1016/j.jmrt.2023.02.134 ↗
23. Active brazing of (HfTaZrNbTi)C high-entropy carbide ceramic and Nb with Ti Ni composite interlayer: novel findings on the reaction layer10.1016/j.matchar.2023.113103 ↗
24. Influence of different binder metals in high entropy carbide based hardmetals10.1080/00325899.2022.2076311 ↗
25. Facile synthesis of high entropy carbide-nickel based cermets by in-situ carbo-thermal reduction of transition metal oxides10.1016/j.actamat.2024.119924 ↗
26. Diffusion bonding of (Hf0.2Zr0.2Ti0.2Ta0.2Nb0.2)C high-entropy ceramic with metallic Ni foil10.1016/j.jeurceramsoc.2021.08.048 ↗
27. Densification and joining of a (HfTaZrNbTi)C high-entropy ceramic by hot pressing10.1016/j.jeurceramsoc.2020.12.043 ↗
28. Active brazing of high entropy ceramic and Nb metal: interfacial microstructure and brazing mechanism10.1016/j.vacuum.2022.111464 ↗
29. Wetting and interfacial behavior of Fe, Co, Ni on (Ti, Zr, Hf, Nb, Ta)C high entropy ceramics10.1016/j.oceram.2023.100393 ↗
30. Wetting of FeCoCrNiTi0.2 high entropy alloy on the (HfZrTiTaNb)C high entropy ceramic10.1016/j.jeurceramsoc.2023.07.065 ↗
31. Enhanced interfacial structure of (HfZrTiTaNb)C high-entropy ceramic joint brazed using FeCoCrNiTi0.2 alloy filler10.1016/j.jmatprotec.2023.118253 ↗
32. Varying interfacial reaction patterns in (VNbTaMoW)C ceramic joints brazed with Ti-Zr-Ni-Cu filler alloy10.1016/j.jeurceramsoc.2024.03.023 ↗
33. Joule heating enables ultra-fast SiC ceramics joining in seconds10.1016/j.scriptamat.2025.116721 ↗
34. Wetting and brazing of (HfTaZrNbTi)B2 and (HfTaZrNbTi)C high-entropy ceramics by AgCuTi filler10.1016/j.oceram.2025.100792 ↗
35. Wetting and interfacial phenomena in Ni–HfB2 systems10.1016/j.actamat.2008.09.016 ↗
36. Wetting and interfacial phenomena of Ni‐Ta alloys on CVD‐SiC10.1111/ijac.12632 ↗
37. Wetting and interactions of Ni- and Co-based superalloys with different ceramic materials10.1007/s10853-009-3801-4 ↗
38. Wetting behaviour of nickel-based brazing alloy BNi-5a on conventionally cast and laser-melted austenitic stainless steel 316L10.1016/j.jmrt.2024.10.228 ↗
39. Wetting of SiC by Al-Ti alloys and joining by in-situ formation of interfacial Ti3Si(Al)C210.1016/j.jeurceramsoc.2018.04.025 ↗
40. Ni-Ta (Nickel-Tantalum)
41. Joining and testing of alumina fibre reinforced YAG-ZrO2 matrix composites10.1016/j.jeurceramsoc.2017.11.026 ↗
42. Combined experimental and CALPHAD investigation of equimolar AlCoCrFeNiX (X=Mo,Ta,W) high-entropy alloys10.1016/j.calphad.2024.102702 ↗
43. Liquid AlCoCrFeNi and AlCoCrFeNiX (X = Mo, Ta) high-entropy alloys on graphite: wetting, reactivity and CALPHAD modelling
44. Wetting and bonding of Ni–Si alloys on silicon carbide10.1016/S1359-6454(98)00374-7 ↗
45. Control of interfacial reactivity between ZrB2 and Ni-based brazing alloys10.1007/s11665-012-0127-1 ↗
46. Combinatorial investigation of the Ni–Ta system via correlated high‐speed nanoindentation and EDX mapping
47. Thermodynamic optimization of the Ni–Ta system supported by the key experiments10.1016/j.tca.2018.06.011 ↗
48. Thermal expansion of some nickel alloys10.6028/jres.058.011 ↗
49. Estimation of densities and coefficients of thermal expansion of solid Ni-base superalloys10.1016/S0921-5093(97)00699-0 ↗
50. Evolution and mechanism of dissolutive wetting between hot metal and carbon brick10.1016/j.jeurceramsoc.2022.04.018 ↗
51. Filler metals, brazing processing and reliability for diamond tools brazing: a review10.1016/j.jmapro.2021.04.015 ↗
52. Residual stress distribution as a function of depth in graphite/copper brazing joints via X-ray diffraction10.1016/j.jmst.2019.07.023 ↗
53. Multiscale plastic deformation in additively manufactured FeCoCrNiMo high-entropy alloys to achieve strength–ductility synergy at elevated temperatures10.1016/j.ijplas.2024.104142 ↗
54. New insights into the formation mechanism of the multicomponent carbides (Nb, M)C (M = Ti, Cr and Mn)10.1016/j.jmrt.2023.11.179 ↗
55. Correlating structure and orbital occupation with the stability and mechanical properties of 3d transition metal carbides10.1016/j.jallcom.2021.161866 ↗
56. Wetting of carbide ceramics (B4C, SiC, TiC and ZrC) by molten Ni at 1753 K10.1016/j.jallcom.2015.07.138 ↗
57. Measurement of the elastic modulus and residual stress of thermal barrier coatings using a digital image correlation technique10.3390/coatings11020245 ↗
58. The bond strength of particulate‐filler composite to differently oriented fiber‐reinforced composite substrate10.1111/j.1532-849X.2006.00147.x ↗
59. Stress-transfer analysis for fibre/matrix interfaces in short-fibre-reinforced composites10.1016/S0266-3538(01)00034-3 ↗
60. Secondary phase interaction at interfaces of high-strength brazed joints made using liquid phase sintered alumina ceramics and Ag-Cu-Ti braze alloys10.1038/s41598-018-20674-w ↗
61. Microstructural evolution during the brazing of Al 2 O 3 ceramic to kovar alloy by sputtering Ti/Mo films on the ceramic surface10.1016/j.ceramint.2016.04.094 ↗
62. Fracture behavior of soldered Al2O3 ceramic to A356 aluminum alloy and resistance of the joint to low temperature exposure10.1016/j.matdes.2015.09.067 ↗