journal article·2025-09Open access

Synthesis and properties of iron silicides

Pavel Novák, Ester Duchková, Andrea Boháčová, Alena Michalcová, Filip Průša, Kateřina Skotnicová, Ivo Szurman

Abstract

Composite materials based on aluminide matrix and hard silicide reinforcement are currently considered as potential tool materials. However, the reasonable design of the composites is limited by incomplete available information about the properties of suitable silicides. Therefore, this work focuses on the synthesis and characterization of iron silicides, which could be very promising also due to the low price of the constituents. The synthesis route for individual iron silicides (Fe 3 Si, FeSi, FeSi 2 ) was investigated using a combination of mechanical alloying, spark plasma sintering, and homogenization annealing.. In the case of Fe 5 Si 3 , which is thermodynamically stable at the temperatures above 825 °C, homogenization annealing was followed by water quenching. The synthesized iron silicides were characterized from the viewpoint of phase composition, microstructure, hardness and abrasive wear resistance. As the hardest silicide, Fe 5 Si 3 was proved; however, it was only obtained in coexistence with other phases due to its low thermodynamic stability. Among the stable iron silicides, FeSi phase offers the best combination of hardness and tribological properties.
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Research context

OpenAlex topics: Semiconductor materials and interfaces · Intermetallics and Advanced Alloy Properties · Surface and Thin Film Phenomena

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References (41)

Show source-provided references
1. A comprehensive review on the cutting and abrasive machining of cemented carbide materials10.1016/j.jmapro.2023.10.042 ↗
2. The critical raw materials in cutting tools for machining applications: a review10.3390/ma13061377 ↗
3. Research on microstructure and property of TiC-Co composite material made by laser cladding10.1016/j.phpro.2012.03.072 ↗
4. On the role of B4C on hardness and toughness of TiCN - SiC - TiN -Cr3C2 - Co cermet10.1016/j.ijrmhm.2020.105252 ↗
5. Enhanced thermal stability and wear resistance of TiCN-SiC-TiN-Cr3C2-Co cermet modified by B4C for cutting tool application10.1016/j.ijrmhm.2020.105352 ↗
6. Sliding wear performance of nickel-based cermet coatings composed of WC and Al2O3 nanosized particles10.1016/j.surfcoat.2016.07.014 ↗
7. Materials, properties, manufacturing methods and cutting performance of innovative ceramic cutting tools − a review
8. A critical review on self-lubricating ceramic-composite cutting tools10.1016/j.ceramint.2021.04.094 ↗
9. Design and development of ceramic-based composites with tailored properties for cutting tool inserts10.1016/j.ceramint.2018.09.009 ↗
10. A microstructure study of Ni/Al2O3 composite ceramics10.1016/j.jallcom.2007.12.036 ↗
11. Al2O3-Cu-Ni composites manufactured via uniaxial pressing: microstructure, magnetic, and mechanical properties10.3390/ma15051848 ↗
12. Copper-Nickel/SiC composites for applications on contact electrodes10.1016/j.heliyon.2024.e39965 ↗
13. Properties of cutting tool composite material diamond–(Fe–Ni–Cu–Sn) reinforced with nano-VN10.3390/machines10060410 ↗
14. Synthesis of iron aluminide–Al2O3 Composites by in-situ displacement reactions10.1016/S0921-5093(97)00642-4 ↗
15. SiC reinforced aluminide composites10.1557/PROC-81-419 ↗
16. In-situ production and microstructures of iron aluminide/TiC composites10.1016/S0966-9795(99)00002-3 ↗
17. Scale resistance of titanium silicide Ti5Si–Titanium-Aluminide TiAl3 powder composites10.1134/S2070205123700223 ↗
18. Preparation and Oxidation Resistance of Silicide/aluminide composite coatings on an Nb-Ti-Si based alloy10.1016/j.surfcoat.2015.04.016 ↗
19. Formation of NiAl–Al2O3 intermetallic-matrix composite powders by mechanical alloying technique10.1016/S0966-9795(00)00039-X ↗
20. Synthesis and characterization of NiAl–Al2O3 nanocomposite powder by mechanical alloying10.1016/j.jallcom.2008.10.043 ↗
21. Structure and properties of cast Ti-Al-Si alloys10.3390/ma14040813 ↗
22. Thermal expansion anisotropy of ternary titanium silicides based on Ti5Si310.1016/j.actamat.2004.04.033 ↗
23. Structure and properties of Fe–Al–Si alloy prepared by mechanical alloying10.3390/ma12152463 ↗
24. FeSi-NiAl composite as a future tool material10.1016/j.jallcom.2024.177227 ↗
25. Synthesis of FeSi–FeAl composites from separately prepared FeSi and FeAl alloys and their structure and properties10.3390/ma16247685 ↗
26. 1990 · vol. 1 · 970
27. Experimental and thermodynamic studies of the Fe–Si binary system10.2355/isijinternational.52.540 ↗
28. Understanding the formation of complex phases: the case of FeSi210.3390/app132312669 ↗
29. Phase transformation in FeSi2 nanowires10.1016/j.jcrysgro.2006.05.076 ↗
30. Mechanical properties of FeSi (ε), FeSi2 (ζα) and Mg2Si10.1016/S0966-9795(02)00046-8 ↗
31. Palmqvist toughness for hard and brittle materials
32. Characterization, wear and emission properties of MnS containing laser cladded brake disc
33. Modified scherrer equation to estimate more accurately nano-crystallite size using XRD10.4236/wjnse.2012.23020 ↗
34. The preferential formation of Ni2Al3, Fe2Al5, and Ti2Al5 phases in aluminide systems10.1016/j.matchemphys.2022.125859 ↗
35. The origin of iron silicides in ureilite meteorites10.1016/j.chemer.2019.125539 ↗
36. The sintering mechanism in spark plasma sintering – proof of the occurrence of spark discharge10.1016/j.scriptamat.2014.03.011 ↗
37. Fundamentals of spark plasma sintering (SPS): an ideal processing technique for fabrication of metal matrix nanocomposites
38. Fundamental principles of spark plasma sintering of metals: part I – Joule heating controlled by the evolution of powder resistivity and local current densities10.1080/00325899.2019.1653532 ↗
39. Numerical model for sparking and plasma formation during spark plasma sintering of ceramic compacts10.1007/s10853-015-9015-z ↗
40. Effect of particle size of titanium and nickel on the synthesis of NiTi by TE-SHS10.1007/s11663-016-0589-x ↗
41. On the formation of intermetallics in Fe–Al system – an in situ XRD study10.1016/j.intermet.2012.08.020 ↗