Conformational adaptation of 2H-Tetraphenylporphyrin at Fe/Si(100) interface during metalation
Source abstract
Abstract
Many recent studies have highlighted the possibility to tailor the physical and chemical properties of porphyrin at the molecular level to design novel catalysts, sensors and devices with applications in electronics, opto-electronics, etc. In the present work we study the electronic properties of 2H-Tetraphenylporphyrin (2H-TPP) on iron (Fe) and iron silicide (Fe3Si) onto Si (1 0 0) substrate using X-ray and Ultraviolet photoelectron spectroscopy (XPS & UPS). The results revealed that the iron atom is coordinated by TPP molecules at Fe/Si system. XPS results provide evidence of the iron coordination with TPP molecules. The UPS analysis show the fine structure in the electronic spectra related to HOMO states below the Fermi level.
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Research context
OpenAlex topics: Surface Chemistry and Catalysis · Molecular Junctions and Nanostructures · Surface and Thin Film Phenomena
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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