journal article·2026-03Open access

Effect of specific pressure on the microstructure, tensile and tribological properties of semi-solid squeeze casting CuSn20P1 alloy

Yongkun Li, Zhijie Wang, Hao Zhang, Rongfeng Zhou, Yingjie Sun

Abstract

CuSn20P1 alloy was fabricated via semi-solid squeeze casting under various specific pressures (0–150 MPa). As the specific pressure increased gradually from 0 MPa to 150 MPa, the α-Cu dendrites disappeared and the grain size decreased. Meanwhile, higher specific pressure effectively alleviated the segregation of Sn, leading to a reduction in the amount of the δ-Cu 41 Sn 11 phase and an increase in the content of β′-Cu 5.6 Sn, which contributed to the improvement of mechanical properties. Calculation results indicated that Cu 3 P, δ and β′ are all ductile stable phases with metallic characteristics and exhibit anisotropy. The order of hardness and Young's modulus values was consistently Cu 3 P >δ >β′, which agreed reasonably well with the measured values within acceptable error margins. Mechanical property evaluations revealed that both the ultimate tensile strength (UTS) and elongation (EL) of the alloy reached their maximum values at 150 MPa, measuring 366.9 MPa and 0.52 %, respectively. These values represent improvements of 64.68 % and 156.16 % compared to those of the alloy prepared at 0 MPa. The alloy processed at 150 MPa also demonstrated the best wear resistance. As the specific pressure increased from 0 MPa to 150 MPa, the coefficient of friction (COF) and wear rate decreased from 0.483 to 2.01 × 10 −4 mm 3 /N·m to 0.341 and 0.601 × 10 −4 mm 3 /N·m, corresponding to reductions by factors of 1.42 and 3.34, respectively. Therefore, this study provides both an experimental basis and theoretical support for the design and application of high-Sn (Sn > 10 wt%) cast copper alloys with excellent mechanical properties.
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Research context

OpenAlex topics: Aluminum Alloys Composites Properties · Aluminum Alloy Microstructure Properties · Metallurgy and Material Science

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References (33)

Show source-provided references
1. Implication of peritectic composition in historical high-tin bronze metallurgy, mater10.1016/j.matchar.2009.05.009 ↗
2. A review of developments in the electrodeposition of tin-copper alloys10.1016/j.surfcoat.2016.06.065 ↗
3. Corrosion evaluation of traditional and new bronzes for artistic castings10.1016/j.matchemphys.2005.06.034 ↗
4. Additive manufacturing of Cu–10Sn bronze10.1016/j.matlet.2015.05.076 ↗
5. The Cu-Sn phase diagram, part I: new experimental results10.1016/j.intermet.2012.10.004 ↗
6. Characteristics of rapidly solidified Cu–10% Sn alloy powders produced by water jet cooled rotating disc atomization, Powder
7. Control of peritectic phase content and its effect on properties of CuSn20P1 alloy by semi-solid rheological forming10.1016/j.jmrt.2024.12.077 ↗
8. Effects of Sn content and hot deformation on microstructure and mechanical properties of binary high Sn content Cu–Sn alloys
9. Processing optimisation, mechanical properties and microstructural evolution during selective laser melting of Cu-15Sn high-tin bronze10.1016/j.msea.2018.02.051 ↗
10. An insight into the underlying mechanisms of low-rate directional solidification and resulting high plasticity of as-cast CuSn alloy10.1016/j.msea.2025.148014 ↗
11. Squeeze casting: a review and update10.1007/BF02834341 ↗
12. Synergistic enhancement of strength and ductility in leaded nickel-tin bronze by constructing a core-rim dual-phase microstructure via semi-solid squeeze casting10.1016/j.msea.2025.148902 ↗
13. Microstructure characteristics and strengthening mechanism of semisolid CuSn10P1 alloys10.1016/j.matchar.2021.110898 ↗
14. Effects of forming specific pressure and filling speed on microstructure and mechanical properties of thin-walled CuSn10P1 alloy parts by rheological squeeze forming10.1007/s40962-023-01109-3 ↗
15. Effects of squeeze casting parameters on density, macrostructure and hardness of LM13 alloy10.1016/j.msea.2006.04.099 ↗
16. Thermodynamic analysis of the Cu-Sn-P ternary system, high10.1515/htmp.2011.061 ↗
17. Study of the microstructure and mechanical properties of Cu–Sn alloys formed by selective laser melting with different Sn contents10.1016/j.jmrt.2023.04.198 ↗
18. High-strain-rate solute drag creep in a Cu-22% Sn alloy (Cu17Sn3) with near peritectic composition10.1016/j.matchar.2020.110325 ↗
19. First-principles simulation: ideas, illustrations and the CASTEP code10.1088/0953-8984/14/11/301 ↗
20. Microstructure and mechanical properties of Al-6Zn-2.5Mg-1.8Cu alloy prepared by squeeze casting and solid hot extrusion10.1016/S1003-6326(15)63824-9 ↗
21. Principles and applications of squeeze castings
22. Thermodynamic optimization of the Cu–Sn and Cu–Nb–Sn systems10.1016/j.jallcom.2008.09.141 ↗
23. Preparation and characterization of monosized Cu–Sn spherical alloy particles by pulsated orifice ejection method10.1557/jmr.2018.183 ↗
24. Effects of processing parameters and ca content on microstructure and mechanical properties of squeeze casting AZ91–Ca alloys10.1016/j.msea.2013.12.014 ↗
25. The Cu–Sn phase diagram part II: new thermodynamic assessment10.1016/j.intermet.2012.10.010 ↗
26. Martensitic transformations in β1 Cu–Sn alloys10.2320/matertrans1960.13.322 ↗
27. Preparation of ultrafine acicular α'phase titanium alloys via laser melting deposition: achieving synergistic enhancement of strength and corrosion resistance
28. Experimental investigation on the ternary phase diagram cu–sn–p
29. Enhanced mechanical properties of as-cast Al-7.0 Si-1.5 Cu-xMg alloys through synergistic main strengthening phases by controlling Mg element10.1016/j.jallcom.2024.173856 ↗
30. In-Depth DFT-Based analysis of the structural, mechanical, thermodynamic, and electronic characteristics of CuP2 and Cu3P: insights into material stability and performance10.3390/met15040369 ↗
31. Electrochemical corrosion behaviors of in situ NbC-reinforced AISI H13 composites: experimentation and first-principles study10.1016/j.apsusc.2024.161858 ↗
32. First-principles calculations of elastic and thermodynamic properties of the four main intermetallic phases in Al–Zn–Mg–Cu alloys10.1016/j.commatsci.2014.06.031 ↗
33. Effects of rheo-squeeze casting parameters on microstructure and mechanical properties of AlCuMnTi alloy10.1016/j.msea.2012.01.051 ↗