journal article·2025-11Open access

Synergistic effect of work hardening and gadolinium on the microstructure, texture, and mechanical properties of the ZM40 Mg alloy

Shabnam Moradi, Ahmad Bahmani, Mehdi Malekan, Woo Jin Kim

Abstract

In the present study, a high strength magnesium (Mg) alloy has been developed through gadolinium (Gd) addition and hot rolling. Five different Gd contents including 0.0, 0.4, 1.0, 1.58 and 4.0 wt.% were added to the ZM41 alloy. Microstructure, texture and mechanical properties of the designed alloys were studied using X-ray diffraction pattern, field emission scanning electron microscopy, tensile test and pole figures from X-ray diffraction and Electron Backscatter Diffraction. I, W, Mg 5 Gd, and Mg-Zn phases were detected in Gd containing alloys. Synergistic effects of these phases and hot rolling process led to grain refinement and second phase redistribution resulting in a high average yield strength of 252.5 ± 22.5 MPa in 1.58% hot rolled Gd-containing alloy and ultimate tensile strength of 360.0 ± 0.0 MPa in 1.0 % Gd-containing alloy. Moreover, the addition of Gd to the rolled alloys weakened the basal texture, leading to an increase in elongation to an average of 8.3% in the hot-rolled alloy containing 1.58% Gd.
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Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Aluminum Alloys Composites Properties · Advanced Welding Techniques Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (84)

Show source-provided references
1. Effects of rare earth yttrium on microstructure and properties of MgAlZn alloy10.1016/j.jallcom.2018.01.234 ↗
2. Strengthening effects of Zn addition on an ultrahigh ductility Mg-Gd-Zr magnesium alloy10.3390/ma11101942 ↗
3. Effect of solution treatment on microstructure and corrosion properties of Mg–4Gd–1Y–1Zn–0.5 Ca–1Zr alloy10.1007/s40195-018-0709-5 ↗
4. Role of the LPSO structure in the improvement of corrosion resistance of Mg-Gd-Zn-Zr alloys10.1016/j.jallcom.2018.12.233 ↗
5. Effect of adding rare Earth elements Er and Gd on the corrosion residual strength of magnesium alloy10.1515/phys-2019-0042 ↗
6. Ultrastrong Mg alloy via nano-spaced stacking faults10.1080/21663831.2013.765927 ↗
7. Significant refinement of 18R-LPSO phase and enhancement of mechanical properties in Mg97Y2Zn1 alloy through an industrially viable processing method10.1016/j.jallcom.2025.180211 ↗
8. Developing high anti-corrosion dilute Mg-La-Ca-Ge alloy as promising anode for primary Mg-air batteries10.1016/j.jallcom.2024.173473 ↗
9. The influence of alloy element on magnesium for electronic devices applications – a review
10. Magnesium castings in aeronautics applications — special requirements
11. Development and application of magnesium alloy parts for automotive OEMs: a review10.1016/j.jma.2022.12.015 ↗
12. A review of magnesium die-castings for closure applications10.1016/j.jma.2019.02.005 ↗
13. Mg-Alloys for forging Applications-A review10.3390/ma13040985 ↗
14. Magnesium application in railway rolling stocks: a new challenge and opportunity for lightweighting
15. Nyberg · 2016 · 7
16. Biodegradable magnesium phosphates in biomedical applications10.1039/D1TB02836G ↗
17. Biodegradable Mg alloys for orthopedic implants – a review10.1016/j.jma.2021.06.024 ↗
18. Development and testing of an allterrain wheelchair built with light magnesium alloy to improve the mobility of the rural population10.17151/kepes.2023.20.28.3 ↗
19. Effect of volume fraction of LPSO phases on corrosion and mechanical properties of Mg-Zn-Y alloys10.1016/j.matdes.2017.02.078 ↗
20. Huang · 2018
21. The effect of Ce addition (up to 3%) and extrusion ratio on the microstructure and tensile properties of ZK60 Mg alloy10.1088/2053-1591/ab1fa0 ↗
22. Recent progress on coatings of biomedical magnesium alloy
23. Catalytic mechanism of spinel oxides for oxidative electrolyte decomposition in Mg rechargeable batteries10.1039/D1TA08115B ↗
24. Effects of Zr and Mn additions on formation of LPSO structure and dynamic recrystallization behavior of Mg-15Gd-1Zn alloy10.1016/j.jallcom.2016.09.068 ↗
25. Recent developments in high-strength Mg-RE-based alloys: focusing on Mg-Gd and Mg-Y systems10.1016/j.jma.2018.08.001 ↗
26. Effect of Zn addition on the microstructure and mechanical properties of cast, rolled and extruded Mg-6Sn-xZn alloys10.1016/j.msea.2016.10.075 ↗
27. Characterization of a Mg95. 5Zn1. 5Y3 alloy both containing W phase and LPSO phase with or without heat treatment10.1016/j.jma.2017.05.003 ↗
28. Mechanical and corrosion properties of Mg-Gd-Zn-Zr-Mn biodegradable alloy by hot extrusion10.1016/j.jallcom.2016.05.241 ↗
29. Substantial corrosion resistance improvement in heat-treated Mg–Gd–Zn alloys with a long period stacking ordered structure10.1016/j.matchemphys.2017.09.035 ↗
30. Recent progress on corrosion behavior and mechanism of Mg–RE based alloys with long period stacking ordered structure10.1007/s12540-019-00410-3 ↗
31. Effect of heat treatments on mechanical properties and corrosion behavior of MgY3Zn2Al magnesium alloy10.1088/2053-1591/aad9da ↗
32. Refining 18R-LPSO phase into sub-micron range by pre-kinking design and its prominent strengthening effect on Mg97Y2Zn1 alloy10.1016/j.jmst.2023.07.051 ↗
33. Tailoring strength and ductility of Mg97Y2Zn1 alloy through the architecture of heterogeneous lamellar structure by large-ratio hot extrusion10.1016/j.jallcom.2023.169212 ↗
34. Magnesium-based composites and alloys for medical applications: a review of mechanical and corrosion properties10.1016/j.jallcom.2019.04.080 ↗
35. Comparative in vitro study on binary Mg-RE (Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) alloy systems10.1016/j.actbio.2019.11.013 ↗
36. Mechanical properties, corrosion resistance and biocompatibilities of degradable Mg-RE alloys: a review10.1016/j.jmrt.2018.08.003 ↗
37. Towards developing Mg alloys with simultaneously improved strength and corrosion resistance via RE alloying10.1016/j.jma.2020.08.016 ↗
38. Correlation between dynamic recrystallization and formation of rare earth texture in a Mg-Zn-Gd magnesium alloy during extrusion10.1038/s41598-018-35170-4 ↗
39. A review on the effect of rare-earth elements on texture evolution during processing of magnesium alloys10.1007/s10853-016-0371-0 ↗
40. Microstructure, texture evolution and tensile properties of extruded Mg-4.58 Zn-2.6 Gd-0.16 Zr alloy10.1016/j.msea.2018.11.142 ↗
41. Fundamentals and advances in magnesium alloy corrosion10.1016/j.pmatsci.2017.04.011 ↗
42. Influence of Zn addition on the microstructure, tensile properties and work-hardening behavior of Mg-1Gd alloy10.1016/j.msea.2019.138779 ↗
43. Microstructure, texture, and strain-hardening behavior of extruded Mg–Gd–Zn alloys10.1016/j.msea.2019.138833 ↗
44. Effects of solution treatment before extrusion on the microstructure, mechanical properties and corrosion of Mg-Zn-Gd alloy in vitro10.1016/j.corsci.2017.01.001 ↗
45. Effect of heat treatment on microstructure, mechanical, corrosion and biocompatibility of Mg-Zn-Zr-Gd-Nd alloy10.1016/j.jallcom.2019.153462 ↗
46. The corrosion performance and mechanical properties of Mg-Zn based alloys—a review10.3390/cmd1020007 ↗
47. Tailoring the mechanical properties of Mg–Zn magnesium alloy by calcium addition and hot extrusion process10.1016/j.msea.2020.138929 ↗
48. The texture and its optimization in magnesium alloy10.1016/j.jmst.2019.10.010 ↗
49. Effect of rolling passes on the microstructures and mechanical properties of Mg–Gd–Y–Zr alloy sheets10.1016/j.msea.2014.09.018 ↗
50. Effect of cross rolling on the corrosion resistance of AZ31 magnesium alloy
51. Effect of rare earth additions on microstructure and texture development of magnesium alloy sheets10.1016/j.scriptamat.2009.12.033 ↗
52. Characterizing microscale deformation mechanisms and macroscopic tensile properties of a high strength magnesium rare-earth alloy: a combined experimental and crystal plasticity approach10.1016/j.actamat.2019.12.012 ↗
53. Mechanochemical characteristics of Ca-added Mg-based alloys: a multimodality approach10.1016/j.matchar.2020.110475 ↗
54. Effects of tensile twinning on the stretch formability of Mg10.1007/s12540-017-6399-0 ↗
55. Deformation behaviors of twin roll cast Mg-Zn-X-Ca alloys for enhanced room-temperature formability10.1016/j.msea.2016.10.046 ↗
56. 2015
57. Achieving high-strain-rate and low-temperature superplasticity in an ECAP-processed Mg-Y-Er-Zn alloy via Ag addition10.1016/j.jma.2022.03.003 ↗
58. Phase formation of Mg-Zn-Gd alloys on the Mg-rich corner10.3390/ma11081351 ↗
59. Effects of Zn/Gd ratio on the microstructures and mechanical properties of Mg-Zn-Gd-Zr alloys10.1016/j.msea.2017.03.117 ↗
60. The influence of Gd on the recrystallisation, texture and mechanical properties of Mg alloy10.1016/j.msea.2022.142867 ↗
61. Effects of calcium on the activity of slip systems in AZ31 magnesium alloy10.1016/j.msea.2018.10.060 ↗
62. Improved strength and plasticity of magnesium matrix nanocomposites reinforced by carbonaceous nanoplatelets and micro-clusters10.1016/j.jmrt.2022.10.083 ↗
63. Nanoscale precipitations in deformed dilute alloying Mg-Zn-Gd alloy10.1016/j.matdes.2020.109122 ↗
64. Correlation between dynamic recrystallization and formation of rare earth texture in a Mg-Zn-Gd magnesium alloy during extrusion10.1038/s41598-018-35170-4 ↗
65. Activation Behavior of {10-12}-{10-12} Secondary Twins by Different Strain Variables and Different Loading Directions during Fatigue Deformation of AZ31 Magnesium Alloy10.3390/met12091433 ↗
66. Local microstructure and micromechanical stress evolution during deformation twinning in hexagonal polycrystals10.1557/jmr.2020.14 ↗
67. In-situ, ex-situ EBSD and (HR-) TEM analyses of primary, secondary and tertiary twin development in an Mg–4 wt% Li alloy10.1016/j.msea.2014.05.025 ↗
68. Evolution of twinning and shear bands in magnesium alloys during rolling at room and cryogenic temperature10.1016/j.matdes.2020.108793 ↗
69. Twinning behavior, microstructure evolution and mechanical property of random-orientated ZK60 Mg alloy compressed at room temperature10.3390/ma16031163 ↗
70. Correlation between dynamic recrystallization and formation of rare earth texture in a Mg-Zn-Gd magnesium alloy during extrusion10.1038/s41598-018-35170-4 ↗
71. Unveiling the effect of Gd content on the dynamic recrystallization behavior and resultant mechanical property of magnesium10.1016/j.msea.2023.145523 ↗
72. Effect of Gd content on the microstructure, texture and mechanical properties of Mg-xGd-0.5 Mn alloys10.1016/j.jmrt.2022.07.034 ↗
73. Effects of Zn content and initial grain size on double peak basal textures of Mg-Zn-Al alloys10.1007/s12540-017-6841-3 ↗
74. Effect of heat treatment on microstructures and mechanical properties of Mg–Zn–Gd–Zr alloys with different compositions10.1166/mex.2018.1435 ↗
75. Grain refinement and weak-textured structures based on the dynamic recrystallization of Mg–9.80 Gd–3.78 Y–1.12 Sm–0.48 Zr alloy10.1016/j.jma.2020.06.001 ↗
76. Multi-solute solid solution behavior and its effect on the properties of magnesium alloys10.1016/j.jma.2022.06.015 ↗
77. Study on microstructure and mechanical properties of TC4/AZ31 magnesium matrix nanocomposites10.3390/ma16031139 ↗
78. Mechanochemical study of a novel Magnesium alloy with trace addition of Gd, Nd, Ce, and La rare-earth and Sr elements
79. Hall-Petch relationship in Mg alloys: a review10.1016/j.jmst.2017.07.022 ↗
80. Improved strength-ductility synergy of directed energy deposited AZ31 magnesium alloy with cryogenic cooling mode10.1080/17452759.2023.2170252 ↗
81. Automated method for fractographic analysis of shape and size of dimples on fracture surface of high-strength titanium alloys10.3390/met8030161 ↗
82. The effects of grain boundary structures on mechanical properties in nanocrystalline al alloy
83. Rare earth texture and improved ductility in a Mg-Zn-Gd alloy after high-speed extrusion10.1016/j.msea.2016.04.093 ↗
84. Effect of LPSO and SFs on microstructure evolution and mechanical properties of Mg-Gd-Y-Zn-Zr alloy