journal article·2023-09Open access

An in situ elemental migration on a nanosize Cu–Sn interface in a microscope

Ang Li, Yu Tao, Hui Lu, Shihang Qiao, Shanshan Liu, Yilin Jiao, Lilin Xie, Yanhui Chen

Abstract

Elemental migration between different elements is intrinsic process for diffusion. Most of the study focused on the presentative shape or size on Kirkendall pores not on the intermediate migration process. A dynamic elemental transition trajectory recording provides real diffusion process on a Cu-Sn nanoscale interface is thus necessary to disclose intermediated reaction on diffusion process. In this work, elemental dynamic diffusion processes were recorded and analysed on a microsize Cu-Sn couple lamella by in situ transmission electron microscopy up to Sn melting point. Factors of atomic quantity, contact condition and temperatures were studied on its diffusion behaviours. The work shed new light on conventional metallographically interfaces diffusion and provide intrinsic clues for solder design.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Electronic Packaging and Soldering Technologies · Surface and Thin Film Phenomena · Copper Interconnects and Reliability

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (31)

Show source-provided references
1. Investigation of FeCoNiCu properties: thermal stability, corrosion behavior, wettability with Sn-3.0Ag-0.5Cu and interlayer formation of multi-element intermetallic compound10.1016/j.apsusc.2021.148931 ↗
2. Design and performance of Ag nanoparticle-modified graphene/SnAgCu lead-free solders10.1016/j.msea.2016.04.084 ↗
3. Interface and marker movements in diffusion in solid solutions of metals
4. Interfacial reactions between lead-free solders and common base materials10.1016/j.mser.2005.03.001 ↗
5. Six cases of reliability study of Pb-free solder joints in electronic packaging technology10.1016/S0927-796X(02)00007-4 ↗
6. Formation of compounds and Kirkendall vacancy in the Cu–Sn system10.1016/j.mee.2013.09.009 ↗
7. Unidirectional growth of microbumps on (111)-oriented and nanotwinned copper10.1126/science.1216511 ↗
8. Interdiffusion analysis of the soldering reactions in Sn-3.5Ag/Cu couples10.1007/s11664-001-0201-1 ↗
9. Effects of Sn grain size on intermetallic compounds formation in 5 μm diameter Cu/Sn pillar bumps10.1007/s10854-018-0078-x ↗
10. Interfacial reactions in Ag-Sn/Cu couples10.1007/s11664-999-0158-z ↗
11. Kinetics of copper and high Pb/high Sn bilayered Pb-Sn solder interactions10.1007/s11664-999-0161-4 ↗
12. Scallop formation and dissolution of Cu–Sn intermetallic compound during solder reflow10.1063/1.1445283 ↗
13. Role of Cu in dissolution kinetics of Cu metallization in molten Sn-based solders10.1063/1.1925317 ↗
14. In situ investigation of the interfacial reaction in Sn/Cu system by synchrotron radiation10.1557/JMR.2010.0130 ↗
15. Morphological stability of solder reaction products in flip chip technology10.1007/s11664-001-0139-3 ↗
16. Kinetic analysis of the soldering reaction between eutectic SnPb alloy and Cu accompanied by ripening10.1103/PhysRevB.53.16027 ↗
17. Modeling of intermediate phase growth10.1063/1.2424530 ↗
18. Substrate mediated long-range oscillatory interaction between adatoms: Cu/Cu(111)10.1103/PhysRevLett.85.2981 ↗
19. Stress enhanced diffusion in Cu-Sb diffusion couples10.1007/BF02811790 ↗
20. Effect of high pressure on interdiffusion in an Al-Mg alloy10.1007/BF00547584 ↗
21. Thickening kinetics of interfacial Cu6Sn5 and Cu3Sn layers during reaction of liquid tin with solid copper10.1007/s11664-003-0113-3 ↗
22. Evolution of CuSn intermetallics between molten SnAgCu solder and Cu substrate10.1016/j.actamat.2008.04.063 ↗
23. The atomic-scale studies of the behavior of the crystal dissolution in a molten metal10.1016/j.cplett.2005.11.017 ↗
24. Early stages of soldering reactions10.1063/1.2058186 ↗
25. On the mechanism of the binary Cu/Sn solder reaction10.1063/1.1852724 ↗
26. Investigation of diffusion behavior in Cu-Sn solid state diffusion couples10.1016/j.jallcom.2015.11.214 ↗
27. Interface dynamics in one-dimensional nanoscale Cu/Sn couples10.1016/j.actamat.2016.11.051 ↗
28. Studies of Cu-Sn interdiffusion coefficients in Cu3Sn and Cu6Sn5 based on the growth kinetics10.1016/j.scriptamat.2021.114138 ↗
29. In situ visualization of metallurgical reactions in nanoscale Cu/Sn diffusion couples10.1039/C4NR06757F ↗
30. Intrinsic and interdiffusion in Cu-Sn system10.1007/s11669-011-9907-9 ↗
31. Kinetic theory of flux-driven ripening