Multi-criteria and CNN analysis of Al2O3/TiO2/egg shell/ATH ceramic fillers in glass fiber-epoxy composites
Source abstract
Abstract
The increasing global demand for sustainable and high-performance composite materials has driven research into novel filler combinations that enhance thermal and mechanical properties while minimizing environmental impact. This study explores the synergistic effect of egg shell waste—a calcium-rich biofiller—combined with inorganic ceramic fillers (alumina, titania, and aluminum trihydrate) in glass fiber-reinforced epoxy hybrid composites. Unlike prior studies focusing on individual fillers, this unique blend offers multifunctional enhancements. The composites' physical, mechanical, and thermal properties were systematically analyzed across various filler proportions, revealing substantial performance improvements. The optimal composite (L7GEATAER) exhibited a density increase to 3015.84 kg/m 3 and a 25.4 % reduction in water absorption. Mechanical tests demonstrated significant enhancements, with flexural and tensile strengths increasing by 2.14 and 1.57 times, respectively, while the glass transition temperature improved by 8.92 %. These enhancements are attributed to superior interfacial bonding , reduced polymer chain mobility, and uniform stress distribution. Advanced analytical techniques, including deep learning-based convolutional neural network (CNN) analysis of SEM microstructures, confirmed refined filler dispersion and improved structural integrity. This research highlights the potential of integrating biowaste with inorganic fillers to develop high-performance, sustainable composites suitable for demanding aerospace, automotive, and construction applications. The findings provide a comprehensive framework for optimizing filler combinations to meet specific industrial requirements while promoting circular economy principles.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Additive Manufacturing and 3D Printing Technologies · Epoxy Resin Curing Processes · Fiber-reinforced polymer composites
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Statistical analysis of the substitution of inorganic fibers and fillers with vegetable fibers and fillers in polystyrene composites10.1002/app.55497 ↗
2. Micro/nano fillers for value‐added polymer composites: a comprehensive review10.1002/vnl.22106 ↗
3. Greening the composite industry: evaluating Lantana camara Verbenaceae fiber as a promising substitute for lightweight polymer matrix composites10.1016/j.indcrop.2024.119265 ↗
4. A review on natural fiber reinforced polymer composite and its applications10.1155/2015/243947 ↗
5. Natural fibers and their composites
6. Effect of nano SiO2 on properties of natural fiber reinforced epoxy hybrid composite: a review10.1016/j.matpr.2020.02.657 ↗
7. Manufacture of polymer composites from plant fibers
8. Plant fiber-reinforced polymer composites: a review on modification, fabrication, properties, and applications10.1007/s00289-023-04733-5 ↗
9. Influence of various chemical treatments on mechanical, thermal and morphological characteristics of Cordia dichotoma fiber10.1016/j.cscee.2024.100972 ↗
10. Optimization of nano cellulose extraction from timoho fiber using response surface methodology (RSM)10.1007/s13399-023-04551-9 ↗
11. Isolation and characterization of Muntingia calabura cellulose nanofibers10.1080/15440478.2022.2156018 ↗
12. Isolation of microcellulose from timoho fiber using the process of delinigfication and maceration: evaluation of physical, chemical, structural, and thermal properties10.1016/j.ijbiomac.2022.10.225 ↗
13. Models of kinematics dependent anisotropic and heterogeneous friction10.1016/j.ijsolstr.2005.07.001 ↗
14. Thermal and morphological characterization of graphene/Al 2 O 3 ‐reinforced epoxy hybrid nanocomposites10.1002/mame.202400180 ↗
15. Deciphering the role of 2D graphene oxide nanofillers in polymer membranes for vanadium redox flow batteries10.1039/D4TA00001C ↗
16. Thermal, morphological, and structural characterization of Seven-Islands-Sedge (Cyperus malaccensis) fiber with graphene oxide as a coupling agent for future polymer composite reinforcement10.1080/15440478.2024.2392284 ↗
17. Effect of graphene oxide addition on the interlaminar shear property of carbon fiber-reinforced epoxy composites10.1016/S1872-5805(17)60107-0 ↗
18. Fire retardant potential of natural fiber reinforced polymer composites: a review10.1080/25740881.2024.2303608 ↗
19. Nanocelluloses from jute fibers and their nanocomposites with natural rubber: preparation and characterization10.1016/j.ijbiomac.2015.08.053 ↗
20. Experimental trends in polymer nanocomposites—a review10.1016/j.msea.2004.09.044 ↗
21. A review on potentiality of nano filler/natural fiber filled polymer hybrid composites10.3390/polym6082247 ↗
22. Toughening by nanostructure10.1016/j.polymer.2008.07.048 ↗
23. Mechanistic insights of nanofillers tuning polymer microstructures for enhanced separation performance of nanofiltration membrane10.1016/j.seppur.2024.126847 ↗
24. The nano-clay effect on the improvement of the thermal, flammability, and mechanical behavior of epoxy/glass fiber/ATH hybrid composites10.1177/00219983241270992 ↗
25. Wear and failure of polyoxymethylene/calcium carbonate nanocomposite gears
26. Preparation and characterization of crystalline nanocellulose (CNC) from linseed straw fibers: as a potential alternative source of nanofillers in polymer composites
27. Poly (3,4‐ethylenedioxythiophene) γ ‐Fe 2 O 3 polymer composite–super paramagnetic behavior and variable range hopping 1D conduction mechanism–synthesis and characterization10.1002/pat.1003 ↗
28. A review on plant fiber reinforced thermoset polymers for structural and frictional composites10.1016/j.polymertesting.2020.106792 ↗
29. Thin biobased transparent UV-blocking coating enabled by nanoparticle self-assembly10.1021/acsami.9b05383 ↗
30. Antimicrobial activity of zinc oxide nano/microparticles and their combinations against pathogenic microorganisms for biomedical applications: from physicochemical characteristics to pharmacological aspects10.3390/nano11020263 ↗
31. The effect of ZnO on the failure of PET by environmental stress cracking10.3390/ma13122844 ↗
32. A review on physico-mechanical properties of bast fibre reinforced polymer composites10.1016/j.jobe.2016.12.003 ↗
33. A review of leaf fiber reinforced polymer composites10.1186/s44147-024-00365-2 ↗
34. A review on mechanical and wear properties of fiber-reinforced thermoset composites with ceramic and lubricating fillers10.1016/j.matpr.2021.02.214 ↗
35. The manufacturing process and corrosion properties of magnesium matrix composites: a review
36. On the effect of subjective, objective and combinative weighting in multiple criteria decision making: a case study on impact optimization of composites10.1016/j.eswa.2015.11.003 ↗
37. A hybrid multiple‐criteria decision‐making approach for selecting optimal automotive brake friction composite
38. Utilization of cement bypass dust in the development of sustainable automotive brake friction composite materials10.1016/j.arabjc.2021.103324 ↗
39. Multi-objective optimization of FDM using hybrid genetic algorithm-based multi-criteria decision-making (MCDM) techniques
40. Adaptable multi-objective optimization framework: application to metal additive manufacturing10.1007/s00170-024-13489-9 ↗
41. Materials selection for choosing the best composite blend polymeric membrane for hydrogen/oxygen proton exchange membrane fuel cell10.1016/j.jpowsour.2022.231566 ↗
42. Optimum design based on fabricated natural fiber reinforced automotive brake friction composites using hybrid CRITIC-MEW approach10.1016/j.jmrt.2021.06.051 ↗
43. Materials selection of reinforced sustainable composites by recycling waste plastics and agro-waste: an integrated multi-criteria decision making approach10.1016/j.conbuildmat.2022.128608 ↗
44. Optimization on physicomechanical and wear properties of wood waste filled poly(lactic acid) biocomposites using integrated entropy-simple additive weighting approach
45. A selection of material using a novel type decision-making method: preference selection index method10.1016/j.matdes.2009.11.020 ↗
46. Experimental analysis and multi-criteria optimization of process parameters in microwave drilling of kenaf-reinforced polypropylene composites
47. An integrated multi-criteria decision-making framework for the selection of sustainable biodegradable polymer for food packaging applications10.1007/s10668-023-03052-z ↗
48. Materials informatics10.1016/S1369-7021(05)71123-8 ↗
49. Machine learning in materials informatics: recent applications and prospects10.1038/s41524-017-0056-5 ↗
50. Peridynamics-fueled convolutional neural network for predicting mechanical constitutive behaviors of fiber reinforced composites10.1016/j.cma.2024.117309 ↗
51. Prediction of composite microstructure stress-strain curves using convolutional neural networks10.1016/j.matdes.2020.108509 ↗
52. Prediction and validation of the transverse mechanical behavior of unidirectional composites considering interfacial debonding through convolutional neural networks10.1016/j.compositesb.2021.109314 ↗
53. Predicting compressive strength of consolidated molecular solids using computer vision and deep learning10.1016/j.matdes.2020.108541 ↗
54. Generation of random distribution of fibres in long-fibre reinforced composites10.1016/j.compscitech.2008.03.013 ↗
55. Statistically equivalent representative volume elements for unidirectional composite microstructures: Part I - without damage10.1177/0021998305055273 ↗
56. Extraction of reduced-order process-structure linkages from phase-field simulations10.1016/j.actamat.2016.10.071 ↗
57. Data-driven reduced-order models for rank-ordering the high cycle fatigue performance of polycrystalline microstructures10.1016/j.matdes.2018.05.009 ↗
58. Machine learning-based accelerated property prediction of two-phase materials using microstructural descriptors and finite element analysis10.1016/j.commatsci.2021.110328 ↗
59. Prediction of two-phase composite microstructure properties through deep learning of reduced dimensional structure-response data
60. Novel repair of bolted composite joints using 3D printed continuous fibre patches with custom fibre paths10.1016/j.compositesb.2025.112212 ↗
61. Fabrication and characterization approach to enhance the mechanical performance of zirconia‐coated Multi‐walled carbon nanotubes reinforced High density polyethylene composites10.1002/pc.29574 ↗
62. From single to multi‐material 3D printing of glass‐ceramics for micro‐optics10.1002/smtd.202401809 ↗
63. Synthesis and characterization of iron selenide-epoxy composites for enhanced optical, dielectric and EMI shielding applications10.1007/s10965-025-04302-6 ↗
64. XGBoost regression analysis of dielectric properties of epoxy resin with inorganic hybrid nanofillers10.1080/00222348.2024.2347746 ↗
65. Carbon nanotubes-intervened interface design of quartz fiber/polyurethane composite fibers towards improved mechanical properties10.1016/j.compscitech.2025.111065 ↗
66. Effect of sugarcane bagasse and alumina reinforcements on physical, mechanical, and thermal characteristics of epoxy composites using artificial neural networks and response surface methodology10.1007/s13399-023-03886-7 ↗
67. Effect of environmental aging conditions on the properties of fly ash filled epoxy composites10.1080/09243046.2019.1610930 ↗
68. Effects of triangle-shape fiber on the transverse mechanical properties of unidirectional carbon fiber reinforced plastics10.1016/j.compstruct.2016.05.065 ↗
69. Permeability and capillary effects in a channel-wise non-crimp fabric10.1016/j.compositesa.2018.02.015 ↗
70. Measurements of the permeability of fiber preforms and applications10.1016/S0266-3538(00)00037-3 ↗
71. Enhancing mechanical performance and water resistance of Careya-Banana fiber epoxy hybrid composites through PLA coating and alkali treatment10.1016/j.jmrt.2024.08.190 ↗
72. Experimental and numerical analysis of natural fillers loaded and E-glass reinforced epoxy sandwich composites10.1016/j.jmrt.2024.07.142 ↗
73. Sustainable cement replacement using waste eggshells: a review on mechanical properties of eggshell concrete and strength prediction using artificial neural network
74. Bhagwan · 2017 · vol. 1
75. A comparison of the role of boehmite (AlOOH) and alumina (Al2O3) in the thermal stability and flammability of poly(methyl methacrylate)10.1016/j.polymdegradstab.2009.05.014 ↗
76. Preparation and combustion performance of B/PVDF/Al composite microspheres10.1002/prep.201900232 ↗
77. Characterization of thermal reaction of aluminum/copper (II) oxide/poly(tetrafluoroethene) nanocomposite by thermogravimetric analysis, differential scanning calorimetry, mass spectrometry and X-ray diffraction10.1016/j.tca.2015.10.012 ↗
78. Thermal degradation behaviour and kinetic analysis of epoxy/montmorillonite nanocomposites10.1016/S0141-3910(03)00026-0 ↗
79. Catalytic pyrolysis kinetic behaviour of glass fibre-reinforced epoxy resin composites over ZSM-5 zeolite catalyst10.1016/j.fuel.2022.123235 ↗
80. Pyrolysis kinetic behaviour of glass fibre-reinforced epoxy resin composites using linear and nonlinear isoconversional methods10.3390/polym13101543 ↗
81. Effect of the resin/hardener ratio on curing, structure and glass transition temperature of nanofilled epoxies10.1002/pc.21120 ↗
82. Stability effects of added biomass on microalgae styrene–butadiene–styrene composites10.1007/s10973-024-13419-7 ↗
83. Compatibilizing effects of maleated poly(lactic acid) (PLA) on properties of PLA/soy protein composites10.1021/ie300118x ↗
84. A convolutional neural network -VGG16 method for corrosion inhibition of 304SS in sulfuric acid solution by timoho leaf extract10.1016/j.jmrt.2024.03.156 ↗
85. Enhanced performance of epoxy composites: a study on Walikukun-glass fiber hybrid reinforcement for automotive applications
86. Effect of stacking sequence and porosity on creep behavior of glass/epoxy and carbon/epoxy hybrid laminate composites10.1016/j.coco.2020.04.006 ↗
87. Mechanical properties and water absorption behaviour of recycled cellulose fibre reinforced epoxy composites10.1016/j.polymertesting.2012.04.002 ↗
88. Water absorption behaviour and its effect on the mechanical properties of flax fibre reinforced bioepoxy composites10.1155/2015/390275 ↗
89. Effect of aerogel incorporation on water content distribution and capillary water absorption in pore size intervals of cementitious composites10.1007/s10853-024-09879-9 ↗
90. Mechanical characterization, water absorption, and thickness swelling of lightweight pineapple leaf/ramie fabric-reinforced polypropylene hybrid composites10.3390/polym16131847 ↗
91. Water uptake of HDPE reinforced with Washingtonia fibre biocomposites: mathematical modelling using artificial neural network, response surface methodology and genetic algorithm
92. The driving force of water absorption in cementitious materials: an analysis of surface-free energies and pore structure10.1016/j.jmrt.2024.04.167 ↗
93. Preparation of lightweight porous slag-based geopolymer highly hydrophobic materials for efficient oil-water separation10.1016/j.conbuildmat.2024.137296 ↗
94. Polymer and ceramic nanocomposites for aerospace applications10.1007/s13204-017-0592-9 ↗
95. Selective plasma etching of polymers and polymer matrix composites
96. Effect of Sesbania grandiflora stem fiber reinforcement on mechanical, chemical, thermal, and physical properties of vinyl ester material
97. Effect of organoclay on contact angle, thermal and mechanical properties of filled epoxy composites10.1016/j.matpr.2020.05.248 ↗
98. Effect of visible and UV illumination on the water contact angle of TiO2 thin films with incorporated nitrogen10.1021/jp065392w ↗
99. Soluble eggshell membrane protein: preparation, characterization and biocompatibility10.1016/j.biomaterials.2003.11.052 ↗
100. Contact angle and adsorption behavior of carboxylic acids on α-Al2O3 surfaces10.1016/j.jcis.2010.09.087 ↗