journal article·2024-11Open access

Effect of the chemical substitution on structural parameters and microwave properties of the Co–Ni–Zn spinels

D.A. Vinnik, D.P. Sherstyuk, V.E. Zhivulin, S.A. Gudkova, P.A. Zezyulina, D.A. Petrov, A.O. Shiryaev, Yuan Yao, S.V. Trukhanov, T.I. Zubar, A.V. Trukhanov

Abstract

Co 0.3 Ni 0.7-x Zn x Fe 2 O 4 (where x = 0.00–0.7 with step 0.1) spinels or CNZF with constant Co concentration and varying of the Ni/Zn concentration were obtained by the ceramic method from initial oxides. Based on X-ray diffraction data it was concluded that all samples are single-phase (SG: Fd-3m). Concentration dependences of the lattice constant and unit cell volume correlate well with Vegard's rule and the average value of the Zn 2+ and Ni 2+ ionic radii. The microwave permeability was measured in the frequency range of 0.1–20 GHz by a coaxial technique. Two resonances on frequency dependences were observed. Analysis of the microwave properties and magnetostatic data showed that low-frequency magnetic peak was caused by a resonance of domain boundaries; high-frequency peak was due to a natural ferrimagnetic resonance. Obtained results opens broad perspectives for practical application of such kind of materials and possibility for microwave parameters control by the external magnetic field.
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Research context

OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Electrical and Thermal Properties of Materials · Electromagnetic wave absorption materials

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