journal article·2025-05Open access

Bainitic press hardening of a silicon-boron steel – Tailoring strength and ductility by process-induced multiphase microstructures

Christoph Ostwald, Ansgar Hatscher, Alexander Liehr, Uwe Diekmann, Thomas Niendorf

Abstract

Hot sheet metal forming is an integral part of the body construction in the automotive industry and enables the production of safety-relevant structural components with strength levels of around 1150 MPa to 2000 MPa. However, due to its intrinsic stress states and high dislocation density, the martensitic microstructures of press-hardened steels exhibit only low ductility. Here, ductility is of highest importance for the energy absorption and crash performance of the body. A new bainitic press hardening process, which is realized by an austenitization step, an isothermal holding phase in the bainite range, and a final quenching step in the forming die, makes it possible to realize a multiphase press-hardened steel composed of bainite, martensite and retained austenite with increased strength and improved ductility. In addition, the new bainitic press hardening process requires only a single alloy to achieve customized strength classes. Conditions obtained are characterized by improved ductility at the same time, which can otherwise only be achieved by different alloy compositions. In the present work, a specifically developed silicon-boron steel 37SiB6 was used, and the influence on strength and ductility for different time-temperature treatments was investigated. In particular, the time of the isothermal bainitic holding step shows a major influence on the phase composition and mechanical properties. Accompanying X-ray diffraction analysis revealed an increased fraction of retained austenite for longer holding times.
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Research context

OpenAlex topics: Microstructure and Mechanical Properties of Steels · Metal Alloys Wear and Properties · Metallurgy and Material Forming

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (68)

Show source-provided references
1. A review on hot stamping10.1016/j.jmatprotec.2010.07.019 ↗
2. Konsequenter Leichtbau10.1365/s35778-012-0756-x ↗
3. The history of hardening of boron steel in northern Sweden
4. Critical review of automotive hot-stamped sheet steel from an industrial perspective10.1080/02670836.2018.1425239 ↗
5. Design and processing of next generation press-hardening steels for car body applications
6. Transformation-induced plasticity (TRIP) in advanced steels: a review10.1016/j.msea.2020.140023 ↗
7. Pre-quenching induced lath structures and enhanced TRIP effect to optimize the strength-ductility of ultrahigh-strength hot-galvanized steel10.1016/j.jmrt.2023.09.133 ↗
8. Matlock · 2009 · 185
9. Herausforderungen und Potentiale einer neuartigen bainitischen Warmblechumformung
10. Warmumformen von Stahl – Betrachtung der Nachhaltigkeit in Herstellung und Anwendung
11. Hot forming – a green technology? An evaluation of sustainability with regard to manufacturing and application of hot-formed components
12. Carbon partitioning into austenite after martensite transformation10.1016/S1359-6454(03)00059-4 ↗
13. Application of the quenching and partitioning (Q&P) process to a medium-carbon, high-Si microalloyed bar steel
14. The quenching and partitioning process: background and recent progress10.1590/S1516-14392005000400010 ↗
15. Quenching and partitioning martensite—a novel steel heat treatment10.1016/j.msea.2006.02.133 ↗
16. Research on one-step quenching and partitioning treatment and its application in hot stamping process10.1177/0954405415616062 ↗
17. Microstructural features of ‘quenching and partitioning’: a new martensitic steel heat treatment
18. Quenching and partitioning steel heat treatment10.1007/s13632-013-0082-8 ↗
19. Influence of carbon partitioning kinetics on final austenite fraction during quenching and partitioning10.1016/j.scriptamat.2009.03.021 ↗
20. Influence of silicon on cementite precipitation in steels10.1179/174328408X275973 ↗
21. The role of silicon in carbon partitioning processes in martensite/austenite microstructures10.1016/j.matdes.2017.04.080 ↗
22. Influence if Si on the microstructure and C redistribution in martensitic steels10.1016/j.matdes.2023.111875 ↗
23. Hot forming of ultra-fine-grained multiphase steel products using press hardening combined with quenching and partitioning process10.3390/met9030357 ↗
24. Bainitic transformation during the two-step quenching and partitioning process in a medium carbon steel containing silicon10.1016/j.msea.2010.06.045 ↗
25. Enhanced mechanical properties of a hot stamped advanced high-strength steel treated by quenching and partitioning process10.1016/j.scriptamat.2010.12.037 ↗
26. Experimental analysis of the stability of retained austenite in a low-alloy 42CrSi steel after different quenching and partitioning heat treatments10.1002/adem.202300380 ↗
27. Combined hot stamping and Q&P processing with a hot air partitioning device10.1016/j.jmatprotec.2018.07.011 ↗
28. Application of quenching and partitioning (Q&P) processing to press hardening steel10.1007/s11661-014-2316-z ↗
29. A carbide-free bainite/martensite/austenite triplex steel with enhanced mechanical properties treated by a novel quenching–partitioning–tempering process10.1016/j.msea.2012.08.064 ↗
30. Design and potential analysis of a new ultra high strength steel (1900 MPa) with Q&P processes for car body applications
31. Retained austenite characteristics and tensile properties in a TRIP type bainitic sheet steel10.2355/isijinternational.40.902 ↗
32. Ductility of 0.1–0.6C–1.5Si–1.5Mn ultra high-strength TRIP-aided sheet steels with bainitic ferrite matrix10.2355/isijinternational.44.1608 ↗
33. Control of retained austenite morphology through double bainitic transformation10.1016/j.msea.2016.07.083 ↗
34. Effect of austempering treatment on the microstructure and mechanical properties of 0.4C–1.5Si-1.5Mn TRIP-aided bainitic ferrite steel10.1016/j.msea.2021.141479 ↗
35. Critical assessment 29: TRIP-aided bainitic ferrite steels10.1080/02670836.2017.1356014 ↗
36. Experimental and numerical process design for press partitioning of the new Q&P steel 37SiB610.3390/met13081346 ↗
37. Development and characterization of new low alloyed ultra-high strength steel for structural body components
38. The bainite transformation in a silicon steel10.1007/BF02658309 ↗
39. Structure-properties relationship in TRIP steels containing carbide-free bainite10.1016/j.cossms.2004.10.002 ↗
40. Machenrauch · 1972 · vol. 27 · 230
41. Faninger · 1972 · vol. 27 · 233
42. The mechanism of bainite formation in steels10.1016/0001-6160(80)90082-6 ↗
43. On the nanoindentation behaviour of complex ferritic phases10.1080/09500839.2014.921348 ↗
44. Influence of carbide morphology on the deformation and fracture mechanisms of spheroidized 14CrMoR steel10.3390/met9111221 ↗
45. Spheroidizing in steels: processes, mechanisms, kinetic and microstructure -A review
46. Microstructure-based behavior law for globular pearlitic steels10.1016/j.jmrt.2019.03.014 ↗
47. Effect of prior microstructures on cementite dissolution behavior during subcritical annealing of high carbon steels10.1007/s12540-021-00983-y ↗
48. Evolution of mechanical properties of ferrite and pearlite phases during spheroidization process and their relationship to the overall properties of low alloy steel10.1016/j.jmrt.2024.02.210 ↗
49. Mechanisms of pearlite spheroidization10.1007/BF02646654 ↗
50. Hot deformation-enhanced globularization of pearlite10.1002/srin.198801546 ↗
51. Characterisation and quantification of complex bainitic microstructures in high and ultra-high strength linepipe steels10.4028/www.scientific.net/MSF.500-501.387 ↗
52. Influence of bainite morphology on impact toughness of continuously cooled cementite free bainitic steels10.1179/1743284710Y.0000000047 ↗
53. Structural characterization of low-carbon multiphase steels merging advanced research methods with light optical microscopy10.1016/j.acme.2015.12.001 ↗
54. XRD, TEM and magnetic resonance studies of iron carbide nanoparticle agglomerates in a carbon matrix10.1016/j.carbon.2003.12.069 ↗
55. Hauk · 1997 · 216
56. Stress induced transformation to bainite in Fe–Cr–Mo–C pressure vessel steel10.1179/mst.1991.7.8.686 ↗
57. In-situ observations of lattice parameter fluctuations in austenite and transformation to bainite10.1007/s11661-005-0002-x ↗
58. Effects of austenitization temperature and compressive stress during bainitic transformation on the stability of retained austenite10.1007/s12666-016-0941-5 ↗
59. Kα1,2 and Kβ1,3 x-ray emission lines of the 3d transition metals10.1103/PhysRevA.56.4554 ↗
60. A correction for the α1 α2 doublet in the measurement of widths of X-ray diffraction lines10.1088/0950-7671/25/7/125 ↗
61. Effect of ausforming on the stability of retained austenite in a C-Mn-Si bainitic steel10.1007/s12540-015-5156-5 ↗
62. The role of ausforming in the stability of retained austenite in a medium-C carbide-free bainitic steel10.1016/j.jmrt.2020.05.062 ↗
63. Untersuchung des oberen Bainits an Siliciumstahl10.1002/srin.197904743 ↗
64. Untersuchung der Bainitumwandlung in Siliciumstahl10.1002/srin.198205172 ↗
65. Effect of retained austenite stabilized via quench and partitioning on the strain hardening of martensitic steels10.1007/s11661-008-9609-z ↗
66. The effect of morphology on the stability of retained austenite in a quenched and partitioned steel10.1016/j.scriptamat.2012.11.003 ↗
67. Effects of retained austenite volume fraction, morphology, and carbon content on strength and ductility of nanostructured TRIP-assisted steels10.1016/j.msea.2015.04.030 ↗
68. Effect of tempering on the stability of retained austenite in carbide-free bainitic steel10.1016/j.msea.2022.143525 ↗