journal article·2023-09Open access

Synergistic effect of Mn2+ with unzipped carbon nanotubes on enhancement of mechanical properties of polyamide 66

Haihang Wang, Lixiu Zhang, Gaohan Liu, Jie Hu, Dong Zhao, Heng Wei, Xuezhong Gong, Sui Mao, Linjun Huang, Yao Wang, Zengkun Li, Peter Strizhak, Michail Danilov, Ihor Rusetskyi, Jianguo Tang

Abstract

Multi-walled carbon nanotubes (MWCNTs) are widely recognized for their exceptional mechanical properties and potential to reinforce composite materials. However, the requirement for high MWCNT concentration remains a challenge in achieving effective reinforcement. In this study, using unzipped multi-walled carbon nanotubes (uMWCNTs) and transition metal filler as a means to significantly enhance the mechanical properties of polyamide 66 (PA66) and incorporating 0.2% w/w of uMWCNTs-Mn as filler allowed us to increase PA66's tensile strength by over 74% and its Young's modulus by over 100%. The structural and functional integrity of uMWCNTs-Mn and PA66 matrix were investigated in detail. This work reveals that the enhancement of mechanical properties is mainly due to the interfacial interaction between uMWCNTs-Mn sheets and the PA66 matrix, the coupling effect of manganese ions, and increases the crystallinity and reduces the size of microcrystals. This work's findings provide a novel approach to the preparation of high-performance composites with low concentrations of carbon nanostructures, which holds significant implications for the development of advanced materials.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Carbon Nanotubes in Composites · Polymer Nanocomposites and Properties · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (46)

Show source-provided references
1. Experimental trends in polymer nanocomposites—a review10.1016/j.msea.2004.09.044 ↗
2. Carbon nanotube reinforced strong carbon matrix composites10.1021/acsnano.0c03268 ↗
3. Scalable fabrication of high-performance graphene/polyamide 66 nanocomposites with controllable surface chemistry by melt compounding10.1002/app.49972 ↗
4. Dispersion of graphene-based nanocarbon fillers in polyamide 66 by dry processing and its effect on mechanical properties10.1016/j.compositesb.2017.01.054 ↗
5. Polyamide 66 and amino-functionalized multi-walled carbon nanotube composites and their melt-spun fibers10.1007/s10853-019-03619-0 ↗
6. Effect of thermo-hygro glycol aging on the damage mechanisms of short glass-fiber reinforced polyamide 6610.1016/j.compositesa.2022.107358 ↗
7. The addition of clay on the mechanical properties of surface-treated CF-filled PA66 composites10.1002/sia.6230 ↗
8. Multi elements-based hybrid flame retardants for the superior fire performance of polyamide 66 textiles10.1016/j.jtice.2021.01.008 ↗
9. Competition between heterogeneous nucleation and flow-induced crystallization of polyamide 66 and its carbon nanotube composites10.1002/marc.202270074 ↗
10. Polyamide 66 fibers synergistically reinforced with functionalized graphene and multi-walled carbon nanotubes10.1016/j.matchemphys.2021.124898 ↗
11. Role of carbon nanotubes on growth of a nanostructured double-deck tribofilm yielding excellent self-lubrication performance10.1016/j.carbon.2020.01.091 ↗
12. Toolbox for dispersing carbon nanotubes into polymers to get conductive nanocomposites10.1021/cm051881h ↗
13. Melt-spinning of carboxylated MWNTs-reinforced polyamide 6 fibers with solid mixing nanocomposites10.1002/pc.24510 ↗
14. Single-walled carbon nanotube-in-binary-polymer nanofiber structures and their use as carbon precursors for electrochemical applications10.1021/acs.jpcc.7b12145 ↗
15. Enhanced mechanical properties and flame retardant of epoxy resin by using of GOPOS decorated MWCNTs10.1007/s00289-021-03736-4 ↗
16. Small but strong: a review of the mechanical properties of carbon nanotube–polymer composites10.1016/j.carbon.2006.02.038 ↗
17. Fatigue failure mechanisms of single-walled carbon nanotube ropes embedded in epoxy10.1063/1.1703837 ↗
18. Fabrication and properties of polyamide-6,6-functionalized carboxylic multi-walled carbon nanotube composite fibers10.1177/0954008309341919 ↗
19. Poly(adipic acid-hexamethylene diamine)-functionalized multi-walled carbon nanotube nanocomposites10.1007/s10853-010-4836-2 ↗
20. Extension-induced mechanical reinforcement in melt-spun fibers of polyamide 66/multiwalled carbon nanotube composites10.1002/pi.3144 ↗
21. Polyamide-6-based composites reinforced with pristine or functionalized multi-walled carbon nanotubes produced using melt extrusion technique10.1177/0021998313484779 ↗
22. Liquid phase production of graphene by exfoliation of graphite in surfactant/water solutions10.1021/ja807449u ↗
23. A novel ferrocene-containing polymer based dispersant for noncovalent dispersion of multi-walled carbon nanotubes in chloroform10.1016/j.jorganchem.2015.06.012 ↗
24. On the effect of electric field application during the curing process on the electrical conductivity of single-walled carbon nanotubes–epoxy composites10.1016/j.carbon.2019.04.087 ↗
25. U1 snRNP regulates cancer cell migration and invasion in vitro10.1038/s41467-019-13993-7 ↗
26. Interface modulating CNTs@PANi hybrids by controlled unzipping of the walls of CNTs to achieve tunable high-performance microwave absorption10.1021/acsami.9b01122 ↗
27. Synthesis of 3D reduced graphene oxide/unzipped carbon nanotubes/polyaniline composite for high-performance supercapacitors10.1016/j.electacta.2018.03.071 ↗
28. Partially unzipping carbon nanotubes: a route to synchronously improve fracture strength and toughness of nanocomposites inspired by pinning effect of screw
29. Structural impact of graphene nanoribbon on mechanical properties and anti-corrosion performance of polyurethane nanocomposites10.1016/j.cej.2020.126858 ↗
30. Die magische Kraft der Übergangsmetalle: vergangenheit, Gegenwart und Zukunft (Nobel-Aufsatz)10.1002/ange.201101380 ↗
31. Decarboxylative coupling reactions: a modern strategy for C-C-bond formation10.1039/c1cs15093f ↗
32. Carboxylates as sources of carbon nucleophiles and electrophiles: comparison of decarboxylative and decarbonylative pathways10.1039/c2sc20312j ↗
33. Breaking amides using nickel catalysis10.1021/acscatal.6b03277 ↗
34. Wall by wall controllable unzipping of MWCNTs via intercalation with oxalic acid to produce multilayers graphene oxide ribbon10.1016/j.cej.2015.06.081 ↗
35. Highly dispersible surface-unzipped multi-walled carbon nanotubes as binder-free electrodes for supercapacitor applications10.1016/j.cap.2015.01.031 ↗
36. Broadband nonlinear optical and optical limiting effects of partially unzipped carbon nanotubes10.1039/C5TC02155C ↗
37. Interpretation of Raman spectra of disordered and amorphous carbon10.1103/PhysRevB.61.14095 ↗
38. A green approach to the synthesis of graphene nanosheets10.1021/nn900227d ↗
39. Structural and optical properties of functionalized multi-walled carbon nanotubes10.1016/j.mssp.2015.10.022 ↗
40. Surface oxides on carbon and their analysis: a critical assessment10.1016/S0008-6223(01)00165-8 ↗
41. Waterborne epoxy resin/polydopamine modified zirconium phosphate nanocomposite for anticorrosive coating10.1021/acs.iecr.9b02557 ↗
42. Characterization of polydopamine thin films deposited at short times by autoxidation of dopamine10.1021/la400587j ↗
43. Graphene and carbon nanotubes for the synergistic reinforcement of polyamide 6 fibers10.1007/s10853-015-8837-z ↗
44. Green fabrication of functionalized graphene via one-step method and its reinforcement for polyamide 66 fibers10.1016/j.matchemphys.2019.122288 ↗
45. Preparation of high-performance carbon nanotube/polyamide composite materials by elastic high-shear kneading and improvement of properties by induction heating treatment10.1002/app.50512 ↗
46. Enhancing interfacial bonding in friction stir lap welding of light metal and carbon fiber reinforced polymer composite10.1016/j.jmapro.2022.09.038 ↗