journal article·2020-07Open access

Corrosion inhibition study of beta-dimethylaminoethyl alcohol on low carbon steel in 0.5 M HCl electrolyte

Loto Roland Tolulope

Abstract

Beta-dimethylaminoethyl alcohol was investigated for its inhibition performance on low carbon steel corrosion in 0.5 M HCl solution. Results show the organic compound effectively suppressed the redox electrochemical mechanism responsible for corrosion with highest inhibition value of 89.07% and 97.05% from weight loss measurement and potentiodynamic polarization technique. Polarization plots exhibited significant passivation characteristics at higher concentrations of the alcohol in the acid solution. Open circuit corrosion potential measurements depict values within passivity potentials. Thermodynamic calculations show the molecules of the alcohol adhered onto the steel surface through physiochemical to chemisorption reaction processes with respect to Langmuir and Freundlich isotherms models. The compound exhibited cathodic type inhibition properties. Scanning electron microscopy confirmed the significant surface deterioration with visible corrosion pits, grooves and cracks on the control steel. This significantly contrasts the improved morphology of the inhibited steel. X-ray diffractometry confirmed both the absence of corrosion products and phases after exposure in the amino alcohol.
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Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Concrete Corrosion and Durability · Hydrogen embrittlement and corrosion behaviors in metals

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Uhlig · 1985
2. Sastri · 1998
3. Synergistic combination effect of salvia officinalis and lavandula officinalis on the corrosion inhibition of low-carbon steel in the presence of SO42− and Cl− containing aqueous environment10.1007/s11668-018-0535-0 ↗
4. Corrosion inhibition properties of the combined admixture of essential oil extracts on mild steel in the presence of SO42− anions10.1016/j.sajce.2018.09.002 ↗
5. Carbon steel corrosion: a review of key surface properties and characterization methods10.1039/C6RA25094G ↗
6. Singh · 1996
7. Silver Jubilee review 25 years of progress in electrochemical methods10.1179/000705990798269577 ↗
8. Some surfactants in the series of 2-(alkyldimethylammonio) alkanol bromides as inhibitors of the corrosion of iron in acid chloride solution10.1016/0010-938X(94)00134-R ↗
9. Mernari B., Elattari H., Traisnel M., Bentiss F. and Lagrenee M. Inhibiting effects of 3,5-bis(n-pyridyl)- 4-amino-1,2,4-triazoles on the corrosion for mild steel in 1M HCl medium. Corrosion, 40(2-3):391-399.10.1016/S0010-938X(97)00142-X ↗
10. Polyamino‐benzoquinone polymers: A new class of corrosion inhibitors for mild steel10.1149/1.2048599 ↗
11. Corrosion inhibition and adsorption properties of mild steel in 1 M hydrochloric acid medium by expired ambroxol drug10.1007/s40735-018-0205-5 ↗
12. Adsorption and corrosion inhibition of mild steel in hydrochloric acid solution by S-allyl-O,O′-dialkyldithiophosphates10.1016/j.rinp.2017.09.012 ↗
13. Studies on corrosion inhibitory effect and adsorption behavior of waste materials on mild steel in acidic medium10.1080/21870764.2018.1439608 ↗
14. Corrosion inhibition of mild steel in hydrochloric acid solution by some double Schiff bases10.1016/j.corsci.2009.11.045 ↗
15. Probing molecular adsorption/interactions and anti-corrosion performance of poppy extract in acidic environments
16. Elucidating detailed experimental and fundamental understandings concerning the green organic-inorganic corrosion inhibiting molecules onto steel in chloride solution10.1016/j.molliq.2019.111212 ↗
17. Detailed macro-/micro-scale exploration of the excellent active corrosion inhibition of a novel environmentally friendly green inhibitor for carbon steel in acidic environments10.1016/j.jtice.2019.04.002 ↗
18. Green production of bioactive components from herbal origins through one-pot oxidation/polymerization reactions and application as a corrosion inhibitor for mild steel in HCl solution10.1016/j.jtice.2019.10.005 ↗
19. Utilizing Lemon Balm extract as an effective green corrosion inhibitor for mild steel in 1M HCl solution: a detailed experimental, molecular dynamics, Monte Carlo and quantum mechanics study10.1016/j.jtice.2018.07.011 ↗
20. Relation of degree of substitution and metal protecting ability of cinnamaldehyde modified chitosan10.1016/j.carbpol.2020.115945 ↗
21. A comprehensive study about anti-corrosion behaviour of pyrazine carbohydrazide: gravimetric, electrochemical, surface and theoretical study10.1016/j.molliq.2019.112160 ↗
22. An Exploration about the Interaction of Mild Steel with Hydrochloric Acid in the Presence of N-(Benzo[d]thiazole-2-yl)-1-phenylethan-1-imines10.1021/acs.jpcc.9b03994 ↗
23. Solvent-free microwave assisted synthesis and corrosion inhibition study of a series of hydrazones derived from thiophene derivatives: experimental, surface and theoretical study10.1016/j.molliq.2019.03.126 ↗
24. Pyrazole derivatives as environmental benign acid corrosion inhibitors for mild steel: experimental and computational studies10.1016/j.molliq.2019.111943 ↗
25. Inhibitory effect and adsorption characteristics of 2,3- diaminonaphthalene at aluminium/hydrochloric acid interface: experimental and theoretical study10.1142/S0218625X08012074 ↗
26. Synergistic and antagonistic effect of anions and ipomoea invulcrata as green corrosion inhibitor for aluminium dissolution in acidic medium10.1016/S1452-3981(23)15338-7 ↗
27. Adsorption characteristics and corrosion inhibitive properties of clotrimazole for aluminium corrosion in hydrochloric acid10.1016/S1452-3981(23)15190-X ↗
28. Adsorption properties and inhibition of mild steel corrosion in sulphuric acid solution by ketoconazole: experimental and theoretical investigation10.1016/j.corsci.2009.09.002 ↗
29. The inhibition effects of some cyclic nitrogen compounds on the corrosion of the steel in NaCl mediums10.1016/S0169-4332(01)00783-8 ↗
30. Rakanta E., Daflou E., Batis G. Evaluation of organic corrosion inhibitor effectiveness into the concrete. Measuring, Monitoring and Modeling Concrete Properties, Springer, Dordrecht, pp. 605-611. https://doi.org/10.1007/978-1-4020-5104-3_73.10.1007/978-1-4020-5104-3_73 ↗
31. Corrosion inhibition of carbon steel by N,N′-Dimethylaminoethanol in simulated concrete pore solution contaminated with NaCl
32. Corrosion protection of steel with DMEA-based organic inhibitor10.1016/j.conbuildmat.2013.03.030 ↗
33. Influence of N,N′‐dimethylaminoethanol as an inhibitor on the chloride threshold level for corrosion of steel reinforcement10.1002/maco.200905393 ↗
34. Batis · 2005 · 79
35. Abimbola Patricia Popoola, Kupolati W. Corrosion inhibition effect of n, n’-diphenylthiourea on the electrochemical characteristics of mild steel in dilute acidic environments
36. Role of manganese dioxide in corrosion in the presence of natural biofilms10.5006/1.3290313 ↗
37. Manganese dioxide as a potential cathodic reactant in corrosion of stainless steels10.1016/S0010-938X(99)00071-2 ↗
38. An investigation on the inhibition effects of some new dithiophosphonic acid monoesthers on the corrosion of the steel in 1 M HCl medium
39. Effect of sodium dodecylsulfate on copper corrosion in sulfuric acid media in the absence and presence of benzotriazole10.1016/S0022-0728(99)00267-3 ↗
40. Adsorption of lead and cadmium ions from aqueous solutions by tripolyphosphate-impregnated Kaolinite clay10.1016/j.colsurfa.2006.06.024 ↗
41. Atkin · 1994 · 877
42. Experimental and theoretical investigation of clotrimazole on corrosion inhibitor for aluminium in hydrochloric acid and effect of iodide ion addition