journal article·2020-05Open access

Microstructure refinement and strengthening of Al–Cu alloys manipulated by nanocrystalline phases formed by in situ crystallization of Ni–Nb–Ti metallic glasses in melt

Tao-Tao Li, Hong-Yu Yang, Tian-Jing Miao, He-Li Peng, Xu Chen, Lin Zhu, Tao-Tao Duan, Feng Qiu, Zhi-Hao Bai, Shu-Ming Chen, Ying-Ying Liu, Xue Han, Shuang Zhang, Qi-Chuan Jiang

Abstract

In this study, the thermal stability of Ni–Nb–Ti metallic glasses was investigated under isothermal and non-isothermal conditions. The effectiveness of NiTi phases, one of the nanosized crystallized phases, as grain refiners for Al–Cu alloys was also investigated from a crystallographic point of view using the edge-to-edge matching (E2EM) model. Thermal analysis showed that NiTi phases promote solidification of α-Al, and these nanocrystalline phases also promote an Al–Cu eutectic reaction and inhibit the growth of eutectic phases. A significant refining effect of α-Al grains from 402.7 μm to 69.1 μm was achieved with 0.05 wt.% nanocrystalline phases. Simultaneously, values for yield strength, ultimate tensile strength and fracture strain of inoculated Al–Cu alloys were increased by 18%, 13% and 78% to 363.2 MPa, 534.3 MPa and 11.92%, respectively, when compared with those of uninoculated Al–Cu alloys. Strengthening mechanisms of Al–Cu alloys manipulated by the nanocrystalline phases are grain boundary strengthening and precipitation strengthening.
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Research context

OpenAlex topics: Aluminum Alloys Composites Properties · Aluminum Alloy Microstructure Properties · Microstructure and mechanical properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. Atomistic calculations of interfacial energies, nucleus shape and size of θ′ precipitates in Al-Cu alloys10.1016/j.actamat.2006.06.010 ↗
2. Enhanced age-hardening behavior in Al–Cu alloys induced by in-situ synthesized TiC nanoparticles10.1016/j.jmst.2018.09.029 ↗
3. Simultaneously increasing strength and ductility of the Al-Cu alloys inoculated by Zr-based metallic glass10.1016/j.matchar.2014.12.016 ↗
4. Effect of Cu addition on microstructures and tensile properties of high-pressure die-casting Al-5.5Mg-0.7Mn alloy10.1016/j.jmst.2018.11.024 ↗
5. Micro-mechanism of texture evolution during isochronal annealing of as-annealed hot rolled Al-Cu-Mg sheet10.1016/j.matdes.2018.107575 ↗
6. Microstructure and mechanical properties at both room and high temperature of in-situ TiC reinforced Al–4.5Cu matrix nanocomposite10.1016/j.jallcom.2018.07.045 ↗
7. Effect of Nb, Y and Zr on thermal stability of nanocrystalline Al-4.5 wt.% Cu alloy prepared by mechanical alloying10.1016/j.jallcom.2017.06.089 ↗
8. Formation of novel microstructures in quenched Al–Cu alloys in steady magnetic field10.1016/j.jallcom.2018.10.006 ↗
9. Formation of equiaxed crystal structures in directionally solidified Al-Si alloys using Nb-based heterogeneous nuclei10.1038/srep39554 ↗
10. Effect of annealing treatment on the microstructure and mechanical properties of a duplex Zr-2.5 Nb alloy10.1016/j.msea.2017.08.107 ↗
11. Wetting of graphite by molten Cu-xSn-yCr ternary alloys at 1373 K10.1016/j.carbon.2019.12.097 ↗
12. Fabrication and characterization of in situ synthesized SiC/Al composites by combustion synthesis and hot press consolidation method10.1155/2017/9314740 ↗
13. Effect of Ta addition on the microstructures and mechanical properties of in situ bi-phase (TiB2-TiCxNy)/(Ni-Ta) cermets10.1016/j.ceramint.2018.11.118 ↗
14. Settling behaviour of different grain refiners in aluminium10.1016/j.msea.2005.08.202 ↗
15. Effect of instability of TiC particles on grain refinement of Al and Al-Mg alloys by addition of Al-Ti-C inoculants10.1179/026708300101507046 ↗
16. Grain refinement behavior of Al-Cu alloys inoculated by various metallic glasses10.1016/j.matchemphys.2015.11.003 ↗
17. The applicability of Johnson-Mehl-Avrami model in the thermal analysis of the crystallization kinetics of glasses10.1016/0040-6031(95)02466-2 ↗
18. Crystallographic study of nucleation in SiC particulate reinforced magnesium matrix composite10.1016/j.jallcom.2017.02.246 ↗
19. Effect of Al content on microstructure and mechanical properties of as-cast Mg-5Nd alloys10.1016/j.jallcom.2017.11.143 ↗
20. Precipitation mechanism of Mg2Ni in Mg-Ni-Y studied by STEM, 3DAP and first-principles calculations10.1016/j.jallcom.2018.03.254 ↗
21. Microstructural evolution and mechanical properties of the AA2219/TiC nanocomposite manufactured by ultrasonic solidification10.1016/j.jallcom.2019.151991 ↗
22. Simultaneously improved strength and toughness of in situ bi-phased TiB2-Ti(C,N)-Ni cermets by Mo addition10.1016/j.jallcom.2019.153068 ↗
23. Unified rationalization of the pitsch and T-H orientation relationships between Widmanstätten cementite and austenite10.1016/S1359-6454(00)00033-1 ↗
24. A two-dimensional analytical approach for phase transformations involving an invariant line strain10.1016/j.actamat.2008.10.003 ↗
25. Surface modification of titanium and titanium alloys: technologies, developments and future interests10.1002/adem.202070017 ↗
26. Some remarks on cooling curves as a principle tool for solidification characterization10.1016/j.jcrysgro.2016.10.071 ↗
27. Estimation of the shifting distance of the eutectic point in hypereutectic Al-Si alloys by the lever rule10.1016/j.scriptamat.2006.11.023 ↗
28. Tensile nanomechanics and the Hall-Petch effect in nanocrystalline aluminium10.1016/j.msea.2017.10.021 ↗
29. Effect of precipitate shape and orientation on Orowan strengthening of non-basal slip modes in hexagonal crystals, application to magnesium alloys10.1016/j.msea.2016.04.056 ↗
30. TiB2 reinforced aluminum based in situ composites fabricated by stir casting10.1016/j.msea.2014.12.033 ↗
31. Processing, multiscale microstructure refinement and mechanical property enhancement of hypoeutectic Al-Si alloys via in situ bimodal-sized TiB2 particles10.1016/j.msea.2020.139081 ↗
32. A facile electron microscopy method for measuring precipitate volume fractions in AlCuMg alloys10.1016/j.matchar.2012.04.009 ↗