Hydrogen-induced amorphization and embrittlement resistance in Ti-based in situ composite with bcc-phase in an amorphous matrix

We report the hydrogenation characteristics and mechanical properties of Ti₅₀Zr₂₅Cu₂₅ in situ composite ribbons, composed of β-Ti crystalline phase dispersed in an amorphous matrix. Upon cathodic charging at room temperature, high hydrogen absorption up to ∼60 at.% (H/M = ∼1.2) is obtained. At such a high concentration, hydrogen-induced amorphization occurs. Mechanical tests conducted on the composite with varying hydrogen concentrations indicate that the Ti₅₀Zr₂₅Cu₂₅ alloy is significantly resistant to hydrogen embrittlement when compared to conventional amorphous alloys. A possible mechanism that would contribute toward hydrogen-induced amorphization and hydrogen embrittlement is discussed.