Sol-gel synthesis of phosphate ceramic composites II
Source abstract
Abstract
Phosphate ceramics were synthesized using sol-gel technique of direct reaction of P2O5 with tetraethoxy silane (TEOS) or titanium tetraethoxide (Ti(OEt)4). The reaction mechanism of P2O5 and TEOS was deduced using liquid and solid-state NMR. Hexacoordinated silicon in phosphosilicate gels was observed. A specially structured titanium phosphate-layered Ti(HPO4)2 · 2H2O was synthesized for the first time through the sol-gel method. The gelation process and phase transformations were investigated.
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OpenAlex topics: Chemical Synthesis and Characterization · Bone Tissue Engineering Materials · Ferroelectric and Piezoelectric Materials
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References (28)
Show source-provided references
1. Van Wazer · 1958 · 627
2. 10.1007/BF0048837410.1007/BF00488374 ↗
3. 10.1246/bcsj.56.163210.1246/bcsj.56.1632 ↗
4. 10.1002/pi.498011040210.1002/pi.4980110402 ↗
5. 10.1021/j100001a05910.1021/j100001a059 ↗
6. 10.1557/JMR.1996.007710.1557/JMR.1996.0077 ↗
7. 10.1063/1.33570810.1063/1.335708 ↗
8. 10.1007/BF0036345110.1007/BF00363451 ↗
9. 10.1557/JMR.1991.059210.1557/JMR.1991.0592 ↗
10. Liebau · Z. Anorg. Allg. Chem. · 1968 · 113 · 359
11. 10.1007/BF0071988510.1007/BF00719885 ↗
12. 10.1016/0022-3093(88)90336-510.1016/0022-3093(88)90336-5 ↗
13. Poojary · Inorg. Chim. Acta · 1993 · 23 · 208
14. 10.1016/0022-3093(93)91248-210.1016/0022-3093(93)91248-2 ↗
15. Fernandez-Lorenzo · 1992
16. Yamanaka · 1989
17. 10.1016/S0022-3093(05)80586-110.1016/S0022-3093(05)80586-1 ↗
18. 10.1016/S0022-3093(05)80548-410.1016/S0022-3093(05)80548-4 ↗
19. 10.1006/jssc.1994.127310.1006/jssc.1994.1273 ↗
20. 10.1557/JMR.1996.001710.1557/JMR.1996.0017 ↗
21. Makart · Helv. Chim. Acta · 1989 · 50 · 911
22. Mayer · Monatsh. Chem. · 1974 · 46 · 105
23. Mudrkovskii · Chem. Phys. Lett. · 1985 · 120 · 429
24. 10.1016/S0022-3093(87)80073-X10.1016/S0022-3093(87)80073-X ↗
25. 10.1038/318352a010.1038/318352a0 ↗
26. 10.1016/0022-3093(84)90391-010.1016/0022-3093(84)90391-0 ↗
27. 10.1557/JMR.1996.031410.1557/JMR.1996.0314 ↗
28. 10.1039/JM994040190310.1039/JM9940401903 ↗