Effect of cation insertion on the stability of gliding arc plasma-precipitated mesoporous MnO2 dye bleaching catalysts
Source abstract
Abstract
α-MnO2and γ-MnO2polymorphs were, respectively, obtained from the plasma precipitation of KMnO4and Mn(CH3COO)3⋅2H2O precursors. The obtained powders were calcined at 150 °C, 210 °C and 400 °C, and characterized by X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), Thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), nitrogen physisorption and Scanning electron microscopy (SEM). As a result, the calcination does not significantly affect textural properties and crystalline structure of the α-MnO2, while γ-MnO2is transformed into β-MnO2for temperatures above 400 °C. The thermal stability α-MnO2is due to the K+ions insertion in its 4.6 Å × 4.6 Å tunnels and corroborated the catalytic performance of 100, 98, 98 and 97% compared to 71, 54, 52 and 48% for γ-MnO2after four successive reuse cycles on Tartrazine Yellow dye. The insertion of cationic species (K+, Na+, Mg2+) into the structure of MnO2reinforces its crystalline structure and promotes the formation of powerful oxidizing species through oxygen vacant sites.Graphical Abstract
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Catalytic Processes in Materials Science · Supercapacitor Materials and Fabrication · Nanomaterials for catalytic reactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (61)
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