journal article·2023-08-14

Photocatalytic enhancement of bulk gC3N4 by one-step polymerization of melamine in the presence of solvent: Synthesis and characterization

Aimé Victoire Abega, Clément Marchal, Marie-Antoinette Dziurla, Nguela Christian Brice Dantio, Didier Robert

Journal of Materials Research· Volume 38· Issue 15
Publisher page

Abstract

Switching the properties of bulk graphitic carbon nitride (gC3N4) targetedly and exerting these advantages fully in organic pollutants photodegradation are crucial for the efficient utilization of solar energy but still exhibits a significant challenge for a real transposition on an industrial scale. The present study displays an easy and green strategy to switch the features of gC3N4using water or ethanol as solvents. The obitained gC3N4efficiently improve the separation and transfer of the photogenerated carriers. Interestingly, all the gC3N4synthesized in presence of solvents exhited a superior photcatalytic activity than the one obtained without solvent, especially the one obtained in presence of distilled water (gC3N4–H2O). The later results in the mass production of gC3N4sheets, giving a yield, i.e., up to 32% after annealing at 550 °C. Moreover, gC3N4–H2O achieve a superior photocatalytic activity for sodium diclofenac degradation (48%) under simulated sunlight after 120 min of irradiation.Graphical abstract
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · MXene and MAX Phase Materials · Gas Sensing Nanomaterials and Sensors

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References (46)

Show source-provided references
1. F. Dong, Y. Li, Z. Wang, W.-K. Ho, Enhanced visible light photocatalytic activity and oxidation ability of porous graphene-like g-C3N4 nanosheets via thermal exfoliation. Appl. Surf. Sci. 358, 393–403 (2015). https://doi.org/10.1016/j.apsusc.2015.04.03410.1016/j.apsusc.2015.04.034 ↗
2. J. Qu, X. Yang, C. Guo, Y. Cai, Z. Li, J. Hu, C.M. Li, Construction of BiVO4/NiCo2O4 nanosheet Z-scheme heterojunction for highly boost solar water oxidation. J. Colloid Interface Sci. 613, 265–275 (2022)10.1016/j.jcis.2022.01.049 ↗
3. H. Tong, S. Ouyang, Y. Bi, N. Umezawa, M. Oshikiri, J. Ye, Nano-photocatalytic materials: possibilities and challenges. Adv. Mater. 24, 229–251 (2012). https://doi.org/10.1002/adma.20110275210.1002/adma.201102752 ↗
4. J. Qu, S. Li, B. Zhong, Z. Deng, Y. Shu, X. Yang, Y. Cai, J. Hu, C.M. Li, Two-dimensional nanomaterials: synthesis and applications in photothermal catalysis. Nanoscale (2023). https://doi.org/10.1039/D2NR06092B10.1039/D2NR06092B ↗
5. J. Wen, J. Xie, X. Chen, X. Li, A review on g-C3N4-based photocatalysts. Appl. Surf. Sci. 391, 72–123 (2017). https://doi.org/10.1016/j.apsusc.2016.07.03010.1016/j.apsusc.2016.07.030 ↗
6. L. Cui, X. Hou, H. Du, Y. Yuan, Facile one-step “polymerization-exfoliation” route to crystalline graphitic carbon nitride nanosheets for increased photocatalytic hydrogen evolution. Appl. Surf. Sci. 501, 144259 (2020). https://doi.org/10.1016/j.apsusc.2019.14425910.1016/j.apsusc.2019.144259 ↗
7. R. Molinari, C. Lavorato, P. Argurio, K. Szymański, D. Darowna, S. Mozia, Overview of photocatalytic membrane reactors in organic synthesis, energy storage and environmental applications. Catalysts (2019). https://doi.org/10.3390/catal903023910.3390/catal9030239 ↗
8. S. O’Hanlon, C. O’Dwyer, Tailoring porous electrode structures by materials chemistry and 3D printing for electrochemical energy storage, in Tailored Funct. Oxide Nanomater. ed. by C. Maccato, D. Barreca (Wiley, Hoboken, 2022), pp.379–403. https://doi.org/10.1002/9783527826940.ch1110.1002/9783527826940.ch11 ↗
9. H. Du, X. Xie, Q. Zhu, L. Lin, Y.-F. Jiang, Z.-K. Yang, X. Zhou, A.-W. Xu, Metallic MoO2 cocatalyst significantly enhances visible-light photocatalytic hydrogen production over MoO2/Zn0.5Cd0.5S heterojunction. Nanoscale 7, 5752–5759 (2015). https://doi.org/10.1039/C4NR06949H10.1039/C4NR06949H ↗
10. T. Zhu, H.B. Wu, Y. Wang, R. Xu, X.W. David Lou, Formation of 1D hierarchical structures composed of Ni3S2 nanosheets on CNTs backbone for supercapacitors and photocatalytic H2 production. Adv. Energy Mater. 2, 1497–1502 (2012). https://doi.org/10.1002/aenm.20120026910.1002/aenm.201200269 ↗
11. M. Shalom, S. Inal, C. Fettkenhauer, D. Neher, M. Antonietti, Improving carbon nitride photocatalysis by supramolecular preorganization of monomers. J. Am. Chem. Soc. 135, 7118–7121 (2013). https://doi.org/10.1021/ja402521s10.1021/ja402521s ↗
12. X. Chen, S. Shen, L. Guo, S.S. Mao, Semiconductor-based photocatalytic hydrogen generation. Chem. Rev. 110, 6503–6570 (2010). https://doi.org/10.1021/cr100164510.1021/cr1001645 ↗
13. H. Zhang, G. Chen, D.W. Bahnemann, Photoelectrocatalytic materials for environmental applications. J. Mater. Chem. 19, 5089–5121 (2009). https://doi.org/10.1039/B821991E10.1039/B821991E ↗
14. L.-R. Zou, G.-F. Huang, D.-F. Li, J.-H. Liu, A.-L. Pan, W.-Q. Huang, A facile and rapid route for synthesis of g-C3N4 nanosheets with high adsorption capacity and photocatalytic activity. RSC Adv. 6, 86688–86694 (2016). https://doi.org/10.1039/C6RA20514C10.1039/C6RA20514C ↗
15. X. Wang, K. Maeda, A. Thomas, K. Takanabe, G. Xin, J.M. Carlsson, K. Domen, M. Antonietti, A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat. Mater. 8, 76–80 (2009). https://doi.org/10.1038/nmat231710.1038/nmat2317 ↗
16. Y. Wu, P. Xiong, J. Wu, Z. Huang, J. Sun, Q. Liu, X. Cheng, J. Yang, J. Zhu, Y. Zhou, Band engineering and morphology control of oxygen-incorporated graphitic carbon nitride porous nanosheets for highly efficient photocatalytic hydrogen evolution. Nano-Micro Lett. 13, 48 (2021). https://doi.org/10.1007/s40820-020-00571-610.1007/s40820-020-00571-6 ↗
17. J. Ran, J. Qu, H. Zhang, T. Wen, H. Wang, S. Chen, L. Song, X. Zhang, L. Jing, R. Zheng, S.-Z. Qiao, 2D Metal organic framework nanosheet: a universal platform promoting highly efficient visible-light-induced hydrogen production. Adv. Energy Mater. 9, 1803402 (2019). https://doi.org/10.1002/aenm.20180340210.1002/aenm.201803402 ↗
18. S. Cao, J. Yu, g-C3N4-based photocatalysts for hydrogen generation. J. Phys. Chem. Lett. 5, 2101–2107 (2014). https://doi.org/10.1021/jz500546b10.1021/jz500546b ↗
19. L. Sun, W. Wang, C. Zhang, M. Cheng, Y. Zhou, Y. Yang, H. Luo, D. Qin, C. Huang, Z. Ouyang, Multiple optimization strategies for improving photocatalytic performance of the h-BN/flower-ring g-C3N4 heterostructures: morphology engineering and internal electric field effect. Chem. Eng. J. 446, 137027 (2022)10.1016/j.cej.2022.137027 ↗
20. M. Zhang, Y. Yang, X. An, J. Zhao, Y. Bao, L. Hou, Exfoliation method matters: the microstructure-dependent photoactivity of g-C3N4 nanosheets for water purification. J. Hazard. Mater. 424, 127424 (2022). https://doi.org/10.1016/j.jhazmat.2021.12742410.1016/j.jhazmat.2021.127424 ↗
21. Y. Zhang, T. Mori, L. Niu, J. Ye, Non-covalent doping of graphitic carbon nitride polymer with graphene: controlled electronic structure and enhanced optoelectronic conversion. Energy Environ. Sci. 4, 4517–4521 (2011). https://doi.org/10.1039/C1EE01400E10.1039/C1EE01400E ↗
22. P. Hu, C. Chen, R. Zeng, J. Xiang, Y. Huang, D. Hou, Q. Li, Y. Huang, Facile synthesis of bimodal porous graphitic carbon nitride nanosheets as efficient photocatalysts for hydrogen evolution. Nano Energy 50, 376–382 (2018). https://doi.org/10.1016/j.nanoen.2018.05.06610.1016/j.nanoen.2018.05.066 ↗
23. G. Chen, S.-P. Gao, Structure and electronic structure of S-doped graphitic C3N4 investigated by density functional theory. Chin. Phys. B 21, 107101 (2012). https://doi.org/10.1088/1674-1056/21/10/10710110.1088/1674-1056/21/10/107101 ↗
24. S. Cao, J. Low, J. Yu, M. Jaroniec, Polymeric photocatalysts based on graphitic carbon nitride. Adv. Mater. 27, 2150–2176 (2015). https://doi.org/10.1002/adma.20150003310.1002/adma.201500033 ↗
25. J. Yu, K. Wang, W. Xiao, B. Cheng, Photocatalytic reduction of CO2 into hydrocarbon solar fuels over g-C3N4–Pt nanocomposite photocatalysts. Phys. Chem. Chem. Phys. 16, 11492–11501 (2014). https://doi.org/10.1039/C4CP00133H10.1039/C4CP00133H ↗
26. Y. Hou, F. Zuo, A.P. Dagg, J. Liu, P. Feng, Branched WO3 nanosheet array with layered C3N4 heterojunctions and CoOx nanoparticles as a flexible photoanode for efficient photoelectrochemical water oxidation. Adv. Mater. 26, 5043–5049 (2014). https://doi.org/10.1002/adma.20140103210.1002/adma.201401032 ↗
27. C. Han, L. Ge, C. Chen, Y. Li, X. Xiao, Y. Zhang, L. Guo, Novel visible light induced Co3O4-g-C3N4 heterojunction photocatalysts for efficient degradation of methyl orange. Appl. Catal. B Environ. 147, 546–553 (2014). https://doi.org/10.1016/j.apcatb.2013.09.03810.1016/j.apcatb.2013.09.038 ↗
28. D.R. Paul, R. Sharma, S.P. Nehra, A. Sharma, Effect of calcination temperature, pH and catalyst loading on photodegradation efficiency of urea derived graphitic carbon nitride towards methylene blue dye solution. RSC Adv. 9, 15381–15391 (2019). https://doi.org/10.1039/C9RA02201E10.1039/C9RA02201E ↗
29. B.V. Lotsch, M. Döblinger, J. Sehnert, L. Seyfarth, J. Senker, O. Oeckler, W. Schnick, Unmasking melon by a complementary approach employing electron diffraction, solid-state NMR spectroscopy, and theoretical calculations—structural characterization of a carbon nitride polymer. Chem. Eur. J. 13, 4969–4980 (2007). https://doi.org/10.1002/chem.20060175910.1002/chem.200601759 ↗
30. L. Florentino-Madiedo, E. Díaz-Faes, C. Barriocanal, Relationship between gCN structure and photocatalytic water splitting efficiency. Carbon 187, 462–476 (2022). https://doi.org/10.1016/j.carbon.2021.11.03010.1016/j.carbon.2021.11.030 ↗
31. P. Jiménez-Calvo, C. Marchal, T. Cottineau, V. Caps, V. Keller, Influence of the gas atmosphere during the synthesis of g-C3N4 for enhanced photocatalytic H2 production from water on Au/g-C3N4 composites. J. Mater. Chem. A. 7, 14849–14863 (2019). https://doi.org/10.1039/C9TA01734H10.1039/C9TA01734H ↗
32. Y. Li, M.-Q. Wang, S.-J. Bao, S. Lu, M. Xu, D. Long, S. Pu, Tuning and thermal exfoliation graphene-like carbon nitride nanosheets for superior photocatalytic activity. Ceram. Int. 42, 18521–18528 (2016). https://doi.org/10.1016/j.ceramint.2016.08.19010.1016/j.ceramint.2016.08.190 ↗
33. Y. Cao, Q. Li, W. Wang, Construction of a crossed-layer-structure MoS2/g-C3N4 heterojunction with enhanced photocatalytic performance. RSC Adv. 7, 6131–6139 (2017). https://doi.org/10.1039/C6RA26925G10.1039/C6RA26925G ↗
34. P. Xia, B. Zhu, J. Yu, S. Cao, M. Jaroniec, Ultra-thin nanosheet assemblies of graphitic carbon nitride for enhanced photocatalytic CO2 reduction. J. Mater. Chem. A. 5, 3230–3238 (2017). https://doi.org/10.1039/C6TA08310B10.1039/C6TA08310B ↗
35. C. Schlumberger, M. Thommes, Characterization of hierarchically ordered porous materials by physisorption and mercury porosimetry—a tutorial review. Adv. Mater. Interfaces 8, 2002181 (2021). https://doi.org/10.1002/admi.20200218110.1002/admi.202002181 ↗
36. G. Li, Z. Xie, S. Chai, X. Chen, X. Wang, A facile one-step fabrication of holey carbon nitride nanosheets for visible-light-driven hydrogen evolution. Appl. Catal. B Environ. 283, 119637 (2021). https://doi.org/10.1016/j.apcatb.2020.11963710.1016/j.apcatb.2020.119637 ↗
37. I. Fatimah, N.I. Prakoso, I. Sahroni, M.M. Musawwa, Y.-L. Sim, F. Kooli, O. Muraza, Physicochemical characteristics and photocatalytic performance of TiO2/SiO2 catalyst synthesized using biogenic silica from bamboo leaves. Heliyon 5, e02766 (2019). https://doi.org/10.1016/j.heliyon.2019.e0276610.1016/j.heliyon.2019.e02766 ↗
38. Q. Sun, X. Hu, S. Zheng, Z. Sun, S. Liu, H. Li, Influence of calcination temperature on the structural, adsorption and photocatalytic properties of TiO2 nanoparticles supported on natural zeolite. Powder Technol. 274, 88–97 (2015). https://doi.org/10.1016/j.powtec.2014.12.05210.1016/j.powtec.2014.12.052 ↗
39. P. Chen, W. Lv, Z. Chen, J. Ma, R. Li, K. Yao, G. Liu, F. Li, Phototransformation of mefenamic acid induced by nitrite ions in water: mechanism, toxicity, and degradation pathways. Environ. Sci. Pollut. Res. 22, 12585–12596 (2015). https://doi.org/10.1007/s11356-015-4537-010.1007/s11356-015-4537-0 ↗
40. B.-M. Bresolin, P. Sgarbossa, D.W. Bahnemann, Synthesis of metal-free functionalized g-C3N4 nanosheets for enhanced photocatalytic activity. J. Environ. Chem. Eng. 9, 106389 (2021). https://doi.org/10.1016/j.jece.2021.10638910.1016/j.jece.2021.106389 ↗
41. Z. Mo, X. She, Y. Li, L. Liu, L. Huang, Z. Chen, Q. Zhang, H. Xu, H. Li, Synthesis of gC3N4 at different temperatures for superior visible/UV photocatalytic performance and photoelectrochemical sensing of MB solution. RSC Adv. 5, 101552–101562 (2015)10.1039/C5RA19586A ↗
42. F. Chang, Y. Xie, J. Zhang, J. Chen, C. Li, J. Wang, J. Luo, B. Deng, X. Hu, Construction of exfoliated gC3N4 nanosheets–BiOCl hybrids with enhanced photocatalytic performance. RSC Adv. 4, 28519–28528 (2014)10.1039/c4ra02735c ↗
43. M. Zhang, C. Lai, B. Li, D. Huang, G. Zeng, P. Xu, L. Qin, S. Liu, X. Liu, H. Yi, Rational design 2D/2D BiOBr/CDs/g-C3N4 Z-scheme heterojunction photocatalyst with carbon dots as solid-state electron mediators for enhanced visible and NIR photocatalytic activity: kinetics, intermediates, and mechanism insight. J. Catal. 369, 469–481 (2019)10.1016/j.jcat.2018.11.029 ↗
44. S.P. Pattnaik, A. Behera, S. Martha, R. Acharya, K. Parida, Facile synthesis of exfoliated graphitic carbon nitride for photocatalytic degradation of ciprofloxacin under solar irradiation. J. Mater. Sci. 54, 5726–5742 (2019)10.1007/s10853-018-03266-x ↗
45. J. Xia, J. Zhao, J. Chen, J. Di, M. Ji, L. Xu, Z. Chen, H. Li, Facile fabrication of g-C3N4/BiPO4 hybrid materials via a reactable ionic liquid for the photocatalytic degradation of antibiotic ciprofloxacin. J. Photochem. Photobiol. Chem. 339, 59–66 (2017)10.1016/j.jphotochem.2017.02.010 ↗
46. M. Tian, J. Wang, R. Sun, D. Lu, N. Li, T. Liu, M. Yao, G. Zhang, L. Li, Facile synthesis of rod-like TiO2-based composite loaded with g-C3N4 for efficient removal of high-chroma organic pollutants based on adsorption-photocatalysis mechanism. Inorg. Chem. Commun. 141, 109517 (2022)10.1016/j.inoche.2022.109517 ↗