Impact of NiTbxFe2−XO4 nanofiller in PVDF matrix for the characterization of magnetic, dielectric properties and effectiveness of EMI shielding
Source abstract
Abstract
This paper reports the influence of the inclusion of terbium-doped nickel ferrite [NiTbxFe2−xO4(x= 0.1, 0.2, 0.3)] nanofiller in polyvinylidene fluoride (PVDF) matrix for modification of the dielectric and magnetic properties of polymer nanocomposite. The dielectric spectroscopic analysis reveals a significant improvement in permittivity for a certain filler (x= 0.3) content in the PVDF matrix. The magnetization (M–H) and FC-ZFC studies show a decrement in blocking (Tb) temperature with high filler loading. Hard ferrimagnetic characteristics predominate over soft ferromagnetic properties at high filler concentrations. The higher saturation magnetization, high retentivity, high coercively and a wider hysteresis loop area are seen in the low-temperature regions. The lower skin depth and better shielding effectiveness give a great platform to the films for the fabrication of electromagnetic shielding (EMI) devices in the high-frequency domain. The light weight of Tb-NFO-PVDF nanocomposite film poses superior advantages against traditional EMI shielding material.Graphical abstractTOC: Represents magnetization plot, ZC & ZFC change with temperature (Inset) and skin depth with frequency plot (Inset).
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Research context
OpenAlex topics: Electromagnetic wave absorption materials · Magnetic Properties and Synthesis of Ferrites · Advancements in Battery Materials
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References (48)
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1. R.C. Pullar, Hexagonal ferrites: a review of the synthesis, properties and applications of hexaferrite ceramics. Prog. Mater. Sci. 57(7), 1191–1334 (2012). https://doi.org/10.1016/j.pmatsci.2012.04.00110.1016/j.pmatsci.2012.04.001 ↗
2. M.A. Dar, K.M. Batoo, V. Verma, W.A. Siddiqui, R.K. Kotnala, Synthesis and characterization of nano-sized pure and Al-doped lithium ferrite having high value of dielectric constant. J. Alloys Compd. 493(1–2), 553–560 (2010). https://doi.org/10.1016/j.jallcom.2009.12.15410.1016/j.jallcom.2009.12.154 ↗
3. X. Batlle, N. Perez, P. Guardia, O. Iglesias, A. Labarta, F. Bartolome, L.M. Garcia, J. Bartolome, A.G. Roca, M.P. Morales, C.J. Serna, Recent advances in magnetic nanoparticles with bulk-like properties. J Appl. Phys. 109, 07B524 (2011)10.1063/1.3559504 ↗
4. G.L. Sun, J.B. Li, J.J. Sun, X.Z. Yang, The influences of Zn2+ and some rare-earth ions on the magnetic properties of nickel-zinc ferrites. J. Magn. Magn. Mater. 281, 173–177 (2004). https://doi.org/10.1016/j.jmmm.2004.04.09910.1016/j.jmmm.2004.04.099 ↗
5. K.K. Bharathi, J.A. Chelvane, G. Markandeyulu, Magnetoelectric properties of Gd and Nd-doped nickel ferrite. J. Magn. Magn. Mater. 321, 3677–3680 (2009). https://doi.org/10.1016/j.jmmm.2009.07.01110.1016/j.jmmm.2009.07.011 ↗
6. V. Franco, J.S. Blazquez, J.J. Law, J.Y. Moreno-Ramírez, L.M. Conde, A Magnetocaloric effect: from materials research to refrigeration devices. Prog. Mater. Sci. 93, 112–232 (2018). https://doi.org/10.1016/j.pmatsci.2017.10.00510.1016/j.pmatsci.2017.10.005 ↗
7. S. Atta, M. Halder, T. Chatterjee, R. Karmakar, A.K. Meikap, Influence of neodymium doping in tuning microstructural, optical and magneto-dielectric properties of nickel ferrite nanoparticles. Mater. Chem. Phys. 285, 126094 (2022). https://doi.org/10.1016/j.matchemphys.2022.12609410.1016/j.matchemphys.2022.126094 ↗
8. K. Srinivasamurthy, V. Angadi, S. Kubrin, S. Matteppanavar, P.M. Kumar, B. Rudraswamy, Evidence of enhanced ferromagnetic nature and hyperfine interaction studies of Ce-Sm doped Co-Ni ferrite nanoparticles for microphone applications. Ceram. Int. 44, 18878–18885 (2018). https://doi.org/10.1016/j.ceramint.2018.07.12310.1016/j.ceramint.2018.07.123 ↗
9. N. Boda, G. Boda, K.C.B. Naidu, M. Srinivas, K.M. Batoo, D. Ravinder, A.P. Reddy, Effect of rare earth elements on low temperature magnetic properties of Ni and Co-ferrite nanoparticles. J. Magn. Magn. Mater. 473, 228–235 (2019). https://doi.org/10.1016/j.jmmm.2018.10.02310.1016/j.jmmm.2018.10.023 ↗
10. M.N. Akhtar, M.A. Khan, Effect of rare earth doping on the structural and magnetic features of nanocrystalline spinel ferrites prepared via sol-gel route. J. Magn. Magn. Mater. 460, 268–277 (2018). https://doi.org/10.1016/j.mseb.2016.03.01110.1016/j.mseb.2016.03.011 ↗
11. J. Sahariya, H.S. Mund, A. Sharma, A. Dashora, M. Itou, Y. Sakurai, B.L. Ahuja, Magnetic properties of NiFe2-XRExO4 (RE=Dy, Gd) using magnetic Compton scattering. J. Magn. Magn. Mater. 360, 113–117 (2014). https://doi.org/10.1016/j.jmmm.2014.02.04510.1016/j.jmmm.2014.02.045 ↗
12. D. Rana, K. Bag, S.N. Bhattacharyya, B.M. Mandal, Miscibility of poly (styrene-co-butyl acrylate) with poly (ethyl methacrylate): existence of both UCST and LCST. J. Polym. Sci. Part B 38(3), 369–375 (2000). https://doi.org/10.1002/(SICI)1099-0488(20000201)38:3/3C369::AID-POLB3/3E3.0.CO;2-W10.1002/(SICI)1099-0488(20000201)38:3/3C369::AID-POLB3/3E3.0.CO;2-W ↗
13. D. Rana, B.M. Mandal, S.N. Bhattacharyya, Analogue calorimetric studies of blends of poly (vinyl ester) and polyacrylates. Macromolecules 29(5), 1579–1583 (1996). https://doi.org/10.1021/ma950954n10.1021/ma950954n ↗
14. D. Rana, B.M. Mandal, S.N. Bhattacharyya, Analogue calorimetry of polymer blends: poly (styrene-co-acrylonitrile) and poly (phenyl acrylate) or poly (vinyl benzoate). Polymer 37(12), 2439–2443 (1996). https://doi.org/10.1016/0032-3861(96)85356-010.1016/0032-3861(96)85356-0 ↗
15. D. Rana, B.M. Mandal, S.N. Bhattacharyya, Miscibility and phase diagrams of poly (phenyl acrylate) and poly (styrene-co-acrylonitrile) blends. Polymer 34(7), 1454–1459 (1993). https://doi.org/10.1016/0032-3861(93)90861-410.1016/0032-3861(93)90861-4 ↗
16. S. Atta, M. Halder, A.K. Meikap, Effect of terbium doping on the optical, electrical and magnetic properties of nanocrystalline nickel ferrite. J. Mater. Sci. 32(6), 6992–7008 (2021). https://doi.org/10.1007/s10854-021-05407-610.1007/s10854-021-05407-6 ↗
17. S.S. Tzeng, Catalytic graphitization of electroless Ni–P coated PAN-based carbon fibers. Carbon 44(10), 1986–1993 (2006). https://doi.org/10.1016/j.carbon.2006.01.02410.1016/j.carbon.2006.01.024 ↗
18. K. Gao, X. Hu, C. Dai, T. Yi, Crystal structures of electrospun PVDF membranes and its separator application for rechargeable lithium metal cells. Mater. Sci. Eng. B 131, 100–105 (2006). https://doi.org/10.1016/j.mseb.2006.03.03510.1016/j.mseb.2006.03.035 ↗
19. M. Sang, S. Wang, M. Liu, L. Bai, W. Jiang, S. Xuan, X. Gong, Fabrication of a piezoelectric polyvinylidene fluoride/carbonyl iron (PVDF/CI) magnetic composite film towards the magnetic field and deformation bi-sensor. Compos. Sci. Technol. 165, 31–38 (2018). https://doi.org/10.1016/j.compscitech.2018.06.00610.1016/j.compscitech.2018.06.006 ↗
20. P.D. Prasad, J. Hemalatha, Energy harvesting performance of magnetoelectric poly (vinylidene fluoride)/NiFe2O4 nanofiber films. J. Magn. Magn. Mater. 532, 167986 (2021). https://doi.org/10.1016/j.jmmm.2021.16798610.1016/j.jmmm.2021.167986 ↗
21. K.N. Harish, H.S.B. Naik, P.N.P. Kumar, R. Viswanath, Optical and photocatalytic properties of solar light active Nd-substituted Ni ferrite catalysts: for environmental protection. ACS Sustain. Chem. Eng. 1(9), 1143–1153 (2013). https://doi.org/10.1021/sc400060z10.1021/sc400060z ↗
22. A.P. Indolia, M.S. Gaur, Optical properties of solution grown PVDF-ZnO nanocomposite thin films. J. Polym. Res. 20(1), 1–8 (2013). https://doi.org/10.1007/s10965-012-0043-y10.1007/s10965-012-0043-y ↗
23. S. Atta, M. Haldar, A.K. Das, A.K. Meikap, Study of electrical transport, dielectric and magnetic properties of NiFe2O4-PVDF nanocomposite film. Physica E Low Dimens. Syst. Nanostruct. 114, 113632 (2019). https://doi.org/10.1016/j.physe.2019.11363210.1016/j.physe.2019.113632 ↗
24. T. Nishiyama, T. Sumihara, Y. Sasaki, E. Sato, M. Yamato, H. Horibe, Crystalline structure control of poly (vinylidene fluoride) films with the antisolvent addition method. Polym. J. 48(10), 1035–1038 (2016). https://doi.org/10.1038/pj.2016.6210.1038/pj.2016.62 ↗
25. A.A. Al-Tabbakh, M.A. More, D.S. Joag, I.S. Mulla, V.K. Pillai, The Fowler-Nordheim plot behavior and mechanism of field electron emission from ZnO tetrapod structures. ACS Nano 4(10), 5585–5590 (2010). https://doi.org/10.1021/nn100840310.1021/nn1008403 ↗
26. R.H. Fowler, L. Nordheim, Electron emission in intense electric fields. Proc. R. Soc. A 119, 173–181 (1928). https://doi.org/10.1098/rspa.1928.009110.1098/rspa.1928.0091 ↗
27. S.K. Cheung, N.W. Cheung, Extraction of Schottky diode parameters from forward current-voltage characteristics. Appl. Phys. Lett. 49, 85–87 (1986). https://doi.org/10.1063/1.9735910.1063/1.97359 ↗
28. I. Jyothi, H.D. Yang, K.H. Shim, V. Janardhanam, S.M. Kang, H. Hong, C.J. Choi, Mater. Trans. 14, 1655 (2013). https://doi.org/10.2320/matertrans.M201301510.2320/matertrans.M2013015 ↗
29. Z.J. Horvath, I. Gyuro, M.N. Sallay, Near-interface concentration reduction in n-type Au/Cr GaAs Schottky contacts P. Tutto. Vacuum 40, 201–203 (1990). https://doi.org/10.1016/0042-207X(90)90156-S10.1016/0042-207X(90)90156-S ↗
30. M. Vivona, F. Giannazzo, F. Roccaforte, Materials and processes for Schottky contacts on silicon carbide. Materials 15(1), 298 (2022). https://doi.org/10.3390/ma1501029810.3390/ma15010298 ↗
31. M.K. Hudait, S.B. Krupanidhi, Doping dependence of the barrier height and ideality factor of Au/n-GaAs Schottky diodes at low temperatures. Phys. B: Condens. Matter 307(1–4), 125–137 (2001). https://doi.org/10.1016/S0921-4526(01)00631-710.1016/S0921-4526(01)00631-7 ↗
32. M. Halder, A.K. Das, A.K. Meikap, Effect of BiFeO3 nanoparticle on electrical, thermal and magnetic properties of polyvinyl alcohol (PVA) composite film. Mater. Res. Bull. 104, 179–187 (2018). https://doi.org/10.1016/j.materresbull.2018.01.03610.1016/j.materresbull.2018.01.036 ↗
33. Y. Song, Y. Shen, H.Y. Lin, Y.H. Lin, M. Li, C.W. Nan, Improving the dielectric constants and breakdown strength of polymer composites: effects of the shape of the BaTiO3 nanoinclusions, surface modification and polymer matrix. J. Mater. Chem. 22, 16491–16498 (2012). https://doi.org/10.1039/C2JM32579A10.1039/C2JM32579A ↗
34. W. Xia, Z. Xu, F. Wen, Z. Zhang, Electrical energy density and dielectric properties of poly (vinylidene fluoride-chlorotrifluoroethylene)/BaSrTiO3 nanocomposites. Ceram. Int. 38, 1071–1075 (2012). https://doi.org/10.1016/j.ceramint.2011.08.03310.1016/j.ceramint.2011.08.033 ↗
35. S. Sinha, S.K. Chatterjee, J. Ghosh, A.K. Meikap, Semiconducting selenium nanoparticles: structural, electrical characterization, and formation of a back-to-back Schottky diode device. J. Appl. Phys. 113, 123704–123711 (2013). https://doi.org/10.1063/1.479610610.1063/1.4796106 ↗
36. G. Chakraborty, K. Gupta, D. Rana, A.K. Meikap, Electrical transport properties of the composite of multiwall carbon nanotube–polypyrrole–polyvinyl alcohol below room temperature. Polym. Compos. 33(3), 343–352 (2012). https://doi.org/10.1002/pc.2215310.1002/pc.22153 ↗
37. G. Chakraborty, K. Gupta, D. Rana, A.K. Meikap, Effect of multiwalled carbon nanotubes on electrical conductivity and magneto-conductivity of polyaniline. Adv. Nat. Sci. Nanosci. Nanotechnol. 3(3), 035015 (2012). https://doi.org/10.1088/2043-6262/3/3/03501510.1088/2043-6262/3/3/035015 ↗
38. G. Chakraborty, K. Gupta, D. Rana, A.K. Meikap, Dielectric relaxation in polyvinyl alcohol–polypyrrole–multiwall carbon nanotube composites below room temperature. Adv. Nat. Sci. Nanosci. Nanotechnol. 4(2), 025005 (2013). https://doi.org/10.1088/2043-6262/4/2/02500510.1088/2043-6262/4/2/025005 ↗
39. P.S. Mukherjee, K. Gupta, D. Rana, A.K. Meikap, Magnetoconductivity and electrical transport of polyaniline coated ternary carbide Ti0.9Al0.1C. Indian J. Phys. 91, 1331–1338 (2017). https://doi.org/10.1007/s12648-017-1043-x10.1007/s12648-017-1043-x ↗
40. A.K. Das, R. Dharmana, A. Mukherjee, K. Baba, R. Hatada, A.K. Meikap, Influence of the functional group on the electrical transport properties of polyvinyl alcohol grafted multiwall carbon nanotube composite thick film. J. Appl. Phys. 123, 145105 (2018). https://doi.org/10.1063/1.502271210.1063/1.5022712 ↗
41. L. Shen, M. Liu, C. Ma, L. Lu, H. Fu, C. You, X. Lu, C.L. Jia, Enhanced bending-tuned magnetic properties in epitaxial cobalt ferrite nanopillar arrays on flexible substrates. Mater. Horiz. 5(2), 230–239 (2018). https://doi.org/10.1039/C7MH00939A10.1039/C7MH00939A ↗
42. B. Dutta, E. Kar, G. Sen, N. Bose, S. Mukherjee, Lightweight, flexible NiO@ SiO2/PVDF nanocomposite film for UV protection and EMI shielding application. Mater. Res. Bull. 124, 110746 (2020). https://doi.org/10.1016/j.materresbull.2019.11074610.1016/j.materresbull.2019.110746 ↗
43. A. Mukherjee, S. Basu, P.K. Manna, S.M. Yusuf, M. Pal, Enhancement of multiferroic properties of nanocrystalline BiFeO3 powder by Gd-doping. J. Alloys Compd. 598, 142–150 (2014). https://doi.org/10.1016/j.jallcom.2014.01.24510.1016/j.jallcom.2014.01.245 ↗
44. Z. Wang, T. Wang, C. Wang, Y. Xiao, The effect of interfacial interaction-induced soft percolation regime on dielectric properties in Ba (Fe0.55Nb0.5)O3/P(VDF-TrFE) nanocomposites. J. Mater. Sci. 52(19), 11496–11505 (2017). https://doi.org/10.1007/s10853-017-1290-410.1007/s10853-017-1290-4 ↗
45. D. Sellmyer, R. Skomski, Advanced Magnetic Nanostructures, 1st edn. (Springer, New York, 2006), p.49410.1007/b101199 ↗
46. M. Abdullah Dar, J. Shah, W.A. Siddiqui, R.K. Kotnala, Study of structure and magnetic properties of Ni–Zn ferrite nano-particles synthesized via co-precipitation and reverse micro-emulsion technique. Appl. Nanosci. 4(6), 675–682 (2014). https://doi.org/10.1007/s13204-013-0241-x10.1007/s13204-013-0241-x ↗
47. D. Peddis, C. Cannas, G. Piccaluga, E. Agostinelli, D. Fiorani, Surface spin freezing effects on enhanced saturation magnetization and magnetic anisotropy in CoFe2O4 nanoparticles. Nanotechnology 21, 125705 (2010)10.1088/0957-4484/21/12/125705 ↗
48. X. Chen, S. Bedanta, O. Petracic, W. Kleemann, S. Sahoo, S. Cardoso, P.P. Freitas, P. Freitas, Superparamagnetism versus superspin glass behavior in dilute magnetic nanoparticle systems. Phys. Rev. B 72, 214436 (2005). https://doi.org/10.1103/PhysRevB.72.21443610.1103/PhysRevB.72.214436 ↗