Superhydrophobic coatings based on thermally and chemically stable fluorinated poly(aryl ether)/SiO2/carbon nanotube
Source abstract
Abstract
The thermal and chemical stabilities are two key factors limiting the commercial application of superhydrophobic coatings. Herein, a thermally and chemically stable fluorinated poly(aryl ether) (FPAE) was used for the first time to construct superhydrophobic coatings by a facile solution spraying process. Distinct nanosheet structures were formed for the FPAE, which after the incorporation of SiO2 and carbon nanotube (CNT) turned into a hydrangea-like structure with high roughness and low surface energy. As a result, superhydrophobic coatings were obtained with the water contact angle (WCA) reaching about 170° and the rolling off angle (RA) reaching less than 1°. The superhydrophobicity was maintained after a variety of rigorous tests, including high-temperature baking, acidic and alkaline solution immersions, ultrasonic treatments, friction evaluations, etc. The self-cleaning, anti-corrosion, and oil–water separation capabilities of the FPAE/SiO2/CNT coating were successfully demonstrated. Therefore, the FPAE is a promising resin for the preparation of low-cost and high-performance superhydrophobic coatings.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Surface Modification and Superhydrophobicity · Advanced Sensor and Energy Harvesting Materials · High voltage insulation and dielectric phenomena
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (54)
Show source-provided references
1. S.P. Dalawai, M.A.S. Aly, S.S. Latthe, Recent advances in durability of superhydrophobic self-cleaning technology: a critical review. Prog. Org. Coat. 138, 105381 (2020)10.1016/j.porgcoat.2019.105381 ↗
2. E. Jeong, G. Zhao, T. Song, S.M. Yu, J. Rha, J. Shin, Y.R. Cho, J. Yun, Simultaneous improvements in self-cleaning and light-trapping abilities of polymer substrates for flexible organic solar cells. J. Mater. Chem. A 6, 2379–2387 (2018)10.1039/C7TA09351A ↗
3. R. Yuan, H. Liu, Y. Chen, Z. Liu, Z. Li, J. Wang, G. Jing, Y. Zhu, P. Yu, H. Wang, Design ambient-curable superhydrophobic/electroactive coating toward durable pitting corrosion resistance. Chem. Eng. J. 374, 840–851 (2019)10.1016/j.cej.2019.05.209 ↗
4. Y. Zhu, F. Sun, H. Qian, H. Wang, L. Mu, J. Zhu, A biomimetic spherical cactus superhydrophobic coating with durable and multiple anti-corrosion effects. Chem. Eng. J. 338, 670–679 (2018)10.1016/j.cej.2018.01.082 ↗
5. Y. Liua, K. Fu, J. Liu, Y. Tian, H. Zhang, R. Wang, B. Zhang, H. Zhang, F. Zhou, Q. Zhang, Design and preparation of a multi-fluorination organic superhydrophobic coating with high mechanical robustness and icing delay ability. Appl. Surf. Sci. 497, 143663 (2019)10.1016/j.apsusc.2019.143663 ↗
6. K.Q. Zhang, J.Z. Cai, X.H. Li, H. Li, Y.H. Zhao, X.Y. Yuan, Balance of polyacrylate-fluorosilicone block copolymers as icephobic coatings. Chin. J. Polym. Sci. 33, 153–162 (2015)10.1007/s10118-015-1563-9 ↗
7. H. Liu, S.S. Su, J.W. Xie, Y. Ma, C.H. Tao, Preparation of superhydrophobic magnetic stearic acid polyurethane sponge for oil–water separation. J. Mater. Res. 35, 2925–2935 (2020)10.1557/jmr.2020.260 ↗
8. G.H. Jiang, R.B. Hu, X.G. Xi, X.H. Wang, R.J. Wang, Facile preparation of superhydrophobic and superoleophilic sponge for fast removal of oils from water surface. J. Mater. Res. 28, 651–656 (2013)10.1557/jmr.2012.410 ↗
9. T. Darmanin, F. Guittard, Recent advances in the potential applications of bioinspired superhydrophobic materials. J. Mater. Chem. A 2, 16319–16359 (2014)10.1039/C4TA02071E ↗
10. J.J. Li, Y.N. Zhou, Z.H. Luo, Polymeric materials with switchable superwettability for controllable oil/water separation: a comprehensive review. Prog. Polym. Sci. 87, 1–33 (2018)10.1016/j.progpolymsci.2018.06.009 ↗
11. M.N. Qu, L.G. Hou, J.M. He, X.R. Ma, M.J. Yuan, X.R. Liu, Research and development of functional superhydrophobic materials. Prog. Chem. 28, 1774–1787 (2016)
12. T. Tkachenko, T. Kononevich, O. Kobzar, I. Purikova, Y. Yakovlev, T. Khalakhan, T. Muzafarov, K. Shevchenko, Low dielectric constant silica-containing cross-linked organic-inorganic materials based on fluorinated poly(arylene ether)s. Polymer 157, 131–138 (2018)10.1016/j.polymer.2018.10.035 ↗
13. C.J. Yang, M. Wang, Z. Yang, D.W. Zhang, Y.L. Tian, X.B. Jing, X.P. Liu, Investigation of effects of acid, alkali, and RAlt solutions on fluorinated superhydrophobic surfaces. Langmuir 35, 17027–17036 (2019)10.1021/acs.langmuir.9b03469 ↗
14. Y.B. Liu, K. Fu, J. Liu, Y. Tian, H. Zhang, R.M. Wang, B.L. Zhang, H.P. Zhang, F.T. Zhou, Q.Y. Zhang, Design and preparation of a multi-fluorination organic superhydrophobic coating with high mechanical robustness and icing delay ability. Appl. Surf. Sci. 497, 143663–143670 (2019)10.1016/j.apsusc.2019.143663 ↗
15. C.H. Kung, P.K. Sow, B. Zahiri, W. Merida, Assessment and interpretation of surface wettability based on sessile droplet contact angle measurement: challenges and opportunities. Adv. Mater. Interfaces 6, 18–37 (2019)10.1002/admi.201900839 ↗
16. W.W. Zheng, J.Y. Huang, S.H. Li, M.Z. Ge, L. Teng, Z. Chen, Y.K. Lai, Advanced materials with special wettability toward intelligent oily wastewater remediation. ACS Appl. Mater. Interfaces 13, 67–87 (2021)10.1021/acsami.0c18794 ↗
17. V. Rengarajan, J. Geng, Y. Huang, Fabrication of tapered 3D microstructure arrays using dual-exposure lithography (DEL). Micromachines 11, 1110–1117 (2020)10.3390/mi11100903 ↗
18. Y.S. Yang, H.J. Shen, J. Qiu, Fabrication of biomimetic robust self-cleaning superhydrophobic wood with canna-leaf-like micro/nanostructure through morphgenetic method improved water-, UV-, and corrosion resistance properties. J. Mol. Struct. 1219, 128616 (2020)10.1016/j.molstruc.2020.128616 ↗
19. C.H. Zhang, C. Li, X.Q. Si, Z.J. He, J.L. Qi, J.C. Feng, J. Cao, Mechanical durable ceria superhydrophobic coating fabricated by simple hot-press sintering. App. Surf. Sci. 529, 147113 (2020)10.1016/j.apsusc.2020.147113 ↗
20. X.K. Liu, T.C. Wang, W. Tong, Q.Q. Xu, J. Kong, Fabrication of unmodified bionic copper surfaces with highly stable hydrophobicity and anti-icing properties via a transfer with Zr-based metallic glasses. Adv. Mater. Interfaces 12, 2001743 (2020)
21. B. Khanzadeh, R. Rafee, M.S. Valipour, Experimental investigation of water droplet impact on the electrospun superhydrophobic cylindrical glass: contact time, maximum spreading factor, and splash threshold. Langmuir 36, 13498–13508 (2020)10.1021/acs.langmuir.0c02228 ↗
22. S.N. Malakhov, P.V. Dmitryakov, E.B. Pichkur, S.N. Chvalun, Nonwoven materials produced by melt electrospinning of polypropylene filled with calcium carbonate. Polymers 12, 12–18 (2020)10.3390/polym12122981 ↗
23. X.Y. He, F. Tian, X.Q. Bai, C.Q. Yuan, C. Wang, A. Neville, Biomimetic lubricant-infused titania nanoparticle surfaces via layer-by-layer deposition to control biofouling. Appl. Surf. Sci. 515, 146064 (2020)10.1016/j.apsusc.2020.146064 ↗
24. Y.C. Wang, Y.R. Lan, X.M. Shi, Y.Z. Sheng, Y.T. Yang, S. Peng, J.Z. Xu, Highly efficient fabrication of self-extinguished flame-retardant and underwater superoleophobic coatings through layer-by-layer method. Mater. Chem. Phys. 256, 123590 (2020)10.1016/j.matchemphys.2020.123590 ↗
25. A. Zhuang, R. Liao, S.C. Dixon, Y. Lu, S. Rathasivam, I.P. Parkin, C.J. Carmalt, Transparent superhydrophobic PTFE films via one-step aerosol assisted chemical vapor deposition. RSC Adv. 7, 29275–29283 (2017)10.1039/C7RA04116K ↗
26. S. Barthwal, S.H. Lim, A durable, fluorine-free, and repairable superhydrophobic aluminum surface with hierarchical micro/nanostructures and its application for continuous oil-water separation. J. Membr. Sci. 618, 118716 (2021)10.1016/j.memsci.2020.118716 ↗
27. Z.Y. Chang, Y. Lu, Fabrication of superhydrophobic surfaces with Cassie-Baxter state. J. Disper. Sci. Technol. 11, 1–12 (2020)
28. O. Rius-Ayra, N. Lorca-Isern, Growth of a superhydrophobic coating on an aluminium substrate with strong adhesive properties and showing efficient oil/water separation. Thin Solid Films 710, 138259–138266 (2020)10.1016/j.tsf.2020.138259 ↗
29. D. Wang, A. Zhao, L. Li, Q. He, H. Guo, H. Sun, Q. Gao, Bioinspired ribbed hair arrays with robust superhydrophobicity fabricated by micro/nanosphere lithography and plasma etching. RSC Adv. 5, 96404–96411 (2015)10.1039/C5RA18439H ↗
30. N.U. Taskin, F. Ordu, Effect of etching duration on roughness and wettability of different carbon steel substrates. Mater. Chem. Phys. 257, 123746–123753 (2021)10.1016/j.matchemphys.2020.123746 ↗
31. H.X. Wang, J. Ding, Y.H. Xue, X.G. Wang, T. Lin, Superhydrophobic fabrics from hybrid silica sol–gel coatings: Structural effect of precursors on wettability and washing durability. J. Mater. Res. 25, 1336–1343 (2011)10.1557/JMR.2010.0169 ↗
32. K. Tadanaga, J. Morinaga, A. Matsuda, T. Minami, Superhydrophobic–superhydrophilic micropatterning on flowerlike alumina coating film by the sol–gel method. Chem. Mater. 2, 590–592 (2000)10.1021/cm990643h ↗
33. S. Wang, K. Liu, X. Yao, L. Jiang, Bioinspired surfaces with superwettability: new insight on theory, design, and applications. Chem. Rev. 155, 8230–8293 (2015)10.1021/cr400083y ↗
34. D. Zhi, Y. Lu, S. Rathasivam, I.P. Parkin, X. Zhang, Large-scale fabrication of translucent and repairable superhydrophobic spray coatings with remarkable mechanical, chemical durability and UV resistance. J. Mater. Chem. A 5, 10622–10631 (2017)10.1039/C7TA02488F ↗
35. X. Wang, H. Hu, Q. Ye, T. Gao, F. Zhou, Q. Xue, Superamphiphobic coatings with coralline-like structure enabled by one-step spray of polyurethane/carbon nanotube composites. J. Mater. Chem. 22, 9624–9631 (2012)10.1039/c2jm30744h ↗
36. D. Kumar, L. Li, Z. Chen, Mechanically robust polyvinylidene fluoride (PVDF) based superhydrophobic coatings for self-cleaning applications. Prog. Org. Coat. 101, 385–390 (2016)10.1016/j.porgcoat.2016.09.003 ↗
37. W. Zhang, Y. Zhu, X. Liu, D. Wang, J. Li, L. Jiang, J. Jin, RAlt-induced fabrication of superhydrophilic and underwater superoleophobic PAA-g-PVDF membranes for effective separation of oil-in-water emulsions. Angew. Chem. Int. Ed. 53, 856–860 (2014)10.1002/anie.201308183 ↗
38. B.F. Wang, Y.K. Zhang, J. Song, Investigation and prediction on regulation of hydrophobicity of polymethyl methacrylate (PMMA) surface by femtosecond laser irradiation. Coatings 10, 386 (2020)10.3390/coatings10040386 ↗
39. T. Hong, S. Jeong, Y.K. Choi, T. Lim, S. Ju, Superhydrophobic, elastic, and conducting polyurethane-carbon nanotube-silane-aerogel composite microfiber. Polymers 12, 8 (2020)10.3390/polym12081772 ↗
40. Z. Yang, L. Wang, W. Sun, S. Li, T. Zhu, W. Liu, G. Liu, Superhydrophobic epoxy coating modified by fluorographene used for anti-corrosion and self-cleaning. Appl. Surf. Sci. 401, 146–155 (2017)10.1016/j.apsusc.2017.01.009 ↗
41. S. Wang, X. Yu, Y. Zhang, Large-scale fabrication of translucent, stretchable and durable superhydrophobic composite films. J. Mater. Chem. A 5, 23489–23496 (2017)10.1039/C7TA08203G ↗
42. Y.L. Qi, Z.B. Yang, W.X. Huang, J. Zhang, Robust superhydrophobic surface for anti-icing and cooling performance: application of fluorine-modified TiO2 and fumed SiO2. Appl. Surf. Sci. 538, 148131–148139 (2021)10.1016/j.apsusc.2020.148131 ↗
43. N. Hamzah, C.P. Leo, B.S. Ooi, Superhydrophobic PVDF/TiO2-SiO2 membrane with hierarchical roughness in membrane distillation for water recovery from phenolic rich solution containing surfactant. Chin. J. Polym. Sci. 37, 609–616 (2019)10.1007/s10118-019-2235-y ↗
44. C.Y. Cao, B. Yi, J.Q. Zhang, C.S. Hou, Z.Y. Wang, G. Lu, X. Huang, X. Yao, Sprayable superhydrophobic coating with high processibility and rapid damage-healing nature. Chem. Eng. J. 392, 124834 (2020)10.1016/j.cej.2020.124834 ↗
45. Y.P. Su, Z.Y. Li, H.J. Zhou, S.H. Kang, Y.X. Zhang, C.Z. Yu, G.Z. Wang, Ni/carbon aerogels derived from water induced self-assembly of Ni-MOF for adsorption and catalytic conversion of oily wastewater. Chem. Eng. J. 402, 126205 (2020)10.1016/j.cej.2020.126205 ↗
46. X.Y. Zhao, C.Y. Wang, W.J. Xu, M.F. Zhu, Photoluminescence electrospun membranes of poly(aryl ether)s with hydrophobicity. Fiber. Polym. 14, 693–697 (2013)10.1007/s12221-013-0693-3 ↗
47. X.Y. Zhao, X. Xu, Y. Liu, C.Y. Wang, Luminescence performance of poly(aryl ether)s membranes with different morphologies. Polym. Eng. Sci. 58, 1945–1954 (2018)10.1002/pen.24804 ↗
48. S. Alla, A. Dietmar, G. Zhong, S. Frank, L. Frank, S. Manfred, G. Karina, Perfluoroalkyl end-functionalized oligoesters: correlation between wettability and end-group segregation. Macromolecules 40, 297–305 (2007)10.1021/ma061139i ↗
49. L. Xu, R.G. Karunakaran, J. Guo, S. Yang, Transparent, superhydrophobic surfaces from one-step spin coating of hydrophobic nanoparticles. ACS Appl. Mater. Interfaces 4, 1118–1125 (2012)10.1021/am201750h ↗
50. C.J. Zhang, F.H. Liang, W. Zhang, H. Liu, M.Z. Ge, Y.Y. Zhang, J.M. Dai, H.L. Wang, G.C. Xing, Y.K. Lai, Y.X. Tang, Constructing mechanochemical durable and self-healing superhydrophobic surfaces. ACS Omega 5, 986–994 (2020)10.1021/acsomega.9b03912 ↗
51. M.Z. Ge, C.Y. Cao, F.H. Liang, R. Liu, Y. Zhang, W. Zhang, T.X. Zhu, B. Yi, Y.X. Tang, Y.K. Lai, A ‘“PDMS-in-water”’ emulsion enables mechanochemically robust superhydrophobic surfaces with self-healing nature. Nanoscale Horiz. 5, 65–73 (2020)10.1039/C9NH00519F ↗
52. L. Yang, Y. Wan, Z. Qin, Q. Xu, Y. Min, Fabrication and corrosion resistance of a graphene-tin oxide composite film on aluminium alloy 6061. Corros. Sci. 130, 85–94 (2018)10.1016/j.corsci.2017.10.031 ↗
53. H.C. Lee, H.S. Hong, Y.M. Kim, S.H. Choi, M.Z. Hong, H.S. Lee, K. Kim, Preparation and evaluation of sulfonated-fluorinated poly (arylene ether)s membranes for a proton exchange membrane fuel cell (PEMFC). Electrochim. Acta 49, 2315–2323 (2004)10.1016/j.electacta.2004.01.012 ↗
54. T.X. Zhu, Y. Cheng, J.Y. Huang, J.Q. Xiong, M.Z. Ge, J.J. Mao, Z.K. Liu, X.L. Dong, Z. Chen, Y.K. Lai, A transparent superhydrophobic coating with mechanochemical robustness for anti-icing, photocatalysis and self-cleaning. Chem. Eng. J. 399, 125746 (2020)10.1016/j.cej.2020.125746 ↗