The abundant oxygen vacancy on CuInS2/BiOBr composite catalyst cooperated with the double Fenton system to perform efficient heterogeneous Fenton degradation of levofloxacin
Source abstract
Abstract
In this study, we prepared a series of heterogeneous Fenton catalytic materials x-CuInS2/BiOBr(x= 10–60 wt%, x-CIS/BiOBr) for the degradation of levofloxacin (LVF) by in- situ hydrothermal synthesis. X-ray photoelectron spectroscopy (XPS) and electron paramagnetic resonance (EPR) show that the x-CIS/BiOBr heterogeneous Fenton catalyst has abundant oxygen vacancy (OVs). The experimental results showed that the degradation rate of LVF by 40%-CIS/BiOBr reached 94.1% within 60 min, and the apparent rate constant was 0.0439 min−1, 8.92 times that of CuInS2and 10.4 times that of BiOBr, respectively. The BET-specific surface area and pore volume were approximately 10 times and 7 times that of pure CuInS2and BiOBr. Based on the characterization and quenching experiments results, the catalytic mechanism of synergistic interaction between the dual Fenton system (In3+/In+and Cu+/Cu2+) and OVswas proposed, the possible degradation pathways of LVF were analyzed, and the toxicity of its intermediates was evaluated.Graphical abstract
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced Photocatalysis Techniques · Advanced oxidation water treatment · Copper-based nanomaterials and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (77)
Show source-provided references
1. T. Li, Z. Wang, J. Guo, C. de la Fuente-Nunez, J. Wang, B. Han, H. Tao, J. Liu, X. Wang, Sci. Total. Environ. 860, 160461 (2023)10.1016/j.scitotenv.2022.160461 ↗
2. S. Hussain, M. Naeem, M.N. Chaudhry, M.A. Iqbal, Exp. Health. 8, 107–115 (2016)10.1007/s12403-015-0186-2 ↗
3. H. Gu, W. Xie, A. Du, D. Pan, Z. Guo, Catal. Rev. Sci. Eng. 65, 569–619 (2023)10.1080/01614940.2021.1960009 ↗
4. Y. Fu, Z. Yang, Y. Xia, Y. Xing, X. Gui, Energy Sources Part A 43, 225–234 (2021)10.1080/15567036.2019.1624877 ↗
5. O. Falyouna, I. Maamoun, K. Bensaida, A. Tahara, Y. Sugihara, O. Eljamal, J. Colloid Interface Sci. 605, 813–827 (2022)10.1016/j.jcis.2021.07.154 ↗
6. Y.J. Ben, C.X. Fu, M. Hu, L. Liu, M.H. Wong, C.M. Zheng, Environ. Res. 169, 483–493 (2019)10.1016/j.envres.2018.11.040 ↗
7. Z.B. Lin, T. Yuan, L. Zhou, S. Cheng, X. Qu, P. Lu, Q.Y. Feng, Environ. Geochem. Health 43, 1741–1758 (2021)10.1007/s10653-020-00759-0 ↗
8. D. Ding, B. Wang, X.A. Zhang, J.X. Zhang, H.H. Zhang, X.X. Liu, Z. Gao, Z.L. Yu, Ecotox. Environ. Safe. 254, 48 (2023)10.1016/j.ecoenv.2023.114734 ↗
9. X. Zhu, Y. Wang, D. Zhou, J. Soils Sediments 14, 1350–1358 (2014)10.1007/s11368-014-0883-7 ↗
10. M.R. Abukhadra, A.S. Mohamed, A.M. El-Sherbeeny, A.T.A. Soliman, ACS Omega 5, 26195–26205 (2020)10.1021/acsomega.0c03785 ↗
11. Z. Geng, M. Yang, X. Qi, Z.Y. Li, X. Yang, M.X. Huo, J.C. Crittenden, J. Chem. Technol. Biotechnol. 94, 1660–1669 (2019)10.1002/jctb.5937 ↗
12. V. Homem, L. Santos, J. Environ. Manage. 92, 2304–2347 (2011)10.1016/j.jenvman.2011.05.023 ↗
13. G. Lofrano, R. Pedrazzani, G. Libralato, M. Carotenuto, Curr. Org. Chem. 21, 1054–1067 (2017)10.2174/1385272821666170103162813 ↗
14. R. Anjali, S. Shanthakumar, J. Environ. Manage. 246, 51–62 (2019)10.1016/j.jenvman.2019.05.090 ↗
15. K. Ikehata, N.J. Naghashkar, M.G. Ei-Din, Ozone-Sci. Eng. 28, 353–414 (2006)10.1080/01919510600985937 ↗
16. J.-H. Wu, Y. Li, X. Liu, F. Liu, S.-J. Ma, J.-J. You, X.-Q. Zhu, X.-X. Zhong, Z.-X. Lin, Environ. Technol. 43, 1561–1572 (2022)10.1080/09593330.2020.1841831 ↗
17. M. Cheng, C. Lai, Y. Liu, G. Zeng, D. Huang, C. Zhang, L. Qin, L. Hu, C. Zhou, W. Xiong, Coord. Chem. Rev. 368, 80–92 (2018)10.1016/j.ccr.2018.04.012 ↗
18. D.A. Nichela, A.M. Berkovic, M.R. Costante, M.P. Juliarena, F.S.G. Einschlag, Chem. Eng. J. 228, 1148–1157 (2013)10.1016/j.cej.2013.05.002 ↗
19. L.L. Zhang, L. Lyu, Y.L. Nie, C. Hu, Sep. Purif. Technol. 157, 203–208 (2016)10.1016/j.seppur.2015.11.021 ↗
20. H. Li, J. Shang, Z.P. Yang, W.J. Shen, Z.H. Ai, L.Z. Zhang, Environ. Sci. Technol. 51, 5685–5694 (2017)10.1021/acs.est.7b00040 ↗
21. X. An, Q. Tang, H. Lan, H. Liu, J. Qu, Appl. Catal. B 244, 407–413 (2019)10.1016/j.apcatb.2018.11.063 ↗
22. M.A. Gaikwad, U.V. Ghorpade, U.P. Suryawanshi, P.V. Kumar, S. Jang, J.S. Jang, L. Tran, J.-S. Lee, H. Bae, S.W. Shin, M.P. Suryawanshi, J.H. Kim, A.C.S. Appl, Mater. Interfaces 15, 21123–21133 (2023)10.1021/acsami.3c01877 ↗
23. R.-R. Ding, W.-Q. Li, C.-S. He, Y.-R. Wang, X.-C. Liu, G.-N. Zhou, Y. Mu, Appl. Catal. B 291, 120069 (2021)10.1016/j.apcatb.2021.120069 ↗
24. K. Pan, C. Yang, J. Hu, W. Yang, B. Liu, J. Yang, S. Liang, K. Xiao, H. Hou, J. Hazard. Mater. 389, 122072 (2020)10.1016/j.jhazmat.2020.122072 ↗
25. X.Y. Li, S.Q. Huang, H.H. Xu, Y.P. Deng, Z. Wang, Z.Q. Liu, Chin. Chem. Lett. 33, 1321–1324 (2022)10.1016/j.cclet.2021.07.058 ↗
26. E. Dutkova, N. Daneu, Z.L. Bujnakova, M. Balaz, J. Kovac, J. Kovac, P. Balaz, Molecules 24, 69 (2019)10.3390/molecules24061031 ↗
27. X. Lu, F. Deng, M. Liu, X. Luo, A. Wang, Mater. Chem. Phys. 212, 372–377 (2018)10.1016/j.matchemphys.2018.03.036 ↗
28. H. Li, J. Shang, Z. Ai, L. Zhang, J. Am. Chem. Soc. 137, 6393–6399 (2015)10.1021/jacs.5b03105 ↗
29. S. Fu, W. Yuan, X. Liu, Y. Yan, H. Liu, L. Li, F. Zhao, J. Zhou, J. Colloid Interface Sci. 569, 150–163 (2020)10.1016/j.jcis.2020.02.077 ↗
30. F. Duo, C. Fan, Y. Wang, Y. Cao, X. Zhang, Mater. Sci. Semicond. Process. 38, 157–164 (2015)10.1016/j.mssp.2015.04.002 ↗
31. J.-C. Sin, C.-A. Lim, S.-M. Lam, A.R. Mohamed, H. Zeng, Mater. Lett. 248, 20–23 (2019)10.1016/j.matlet.2019.03.129 ↗
32. J. Guo, L. Wang, X. Wei, Z.A. Alothman, M.D. Albaqami, V. Malgras, Y. Yamauchi, Y. Kang, M. Wang, W. Guan, X. Xu, J. Hazard. Mater. 415, 125591 (2021)10.1016/j.jhazmat.2021.125591 ↗
33. J.-C. Sin, S.-M. Lam, H. Zeng, H. Lin, H. Li, L. Huang, K.-O. Tham, A.R. Mohamed, J.-W. Lim, Environ. Res. 212, 113394 (2022)10.1016/j.envres.2022.113394 ↗
34. F. Deng, X. Lu, Y. Luo, J. Wang, W. Che, R. Yang, X. Luo, S. Luo, D.D. Dionysiou, Chem. Eng. J. 361, 1451–1461 (2019)10.1016/j.cej.2018.10.176 ↗
35. K. Gao, L.-A. Hou, X. An, D. Huang, Y. Yang, Appl. Catal. B 323, 14171–14179 (2023)
36. F. El-Kabbany, S. Taha, M. Hafez, I.S. Yahia, J. Mol. Struct. 1111, 33–45 (2016)10.1016/j.molstruc.2016.01.061 ↗
37. M. Ghorbani, A.R.S. Nazar, M. Frahadian, S. Tangestaninejad, Appl. Surf. Sci. 612, 155819 (2023)10.1016/j.apsusc.2022.155819 ↗
38. G. Tang, F. Zhang, P. Huo, S. Zulfiqarc, J. Xu, Y. Yan, H. Tang, Ceram. Int. 45, 19197–19205 (2019)10.1016/j.ceramint.2019.06.167 ↗
39. D.-Y. Lee, J. Kim, Thin Solid Films 518, 6537–6541 (2010)10.1016/j.tsf.2010.03.062 ↗
40. S.-Y. Hu, Y.-C. Lee, B.-J. Chen, J. Alloys Compd. 690, 15–20 (2017)10.1016/j.jallcom.2016.08.098 ↗
41. I.J. Panneerdoss, S.J. Jeyakumar, S. Ramalingam, M. Jothibas, Spectroc. Acta Pt. A 147, 1–13 (2015)10.1016/j.saa.2015.02.033 ↗
42. V.M. Dzhagan, A.P. Litvinchuk, M.Y. Valakh, M. Kruszynska, J. Kolny-Olesiak, C. Himcinschi, D.R.T. Zahn, Phys. Status Solidi A 211, 195–199 (2014)10.1002/pssa.201330229 ↗
43. M. Gusain, P. Kumar, S. Uma, R. Nagarajan, Colloid Surf. A 481, 269–275 (2015)10.1016/j.colsurfa.2015.05.027 ↗
44. K. Zhao, L. Zhang, J. Wang, Q. Li, W. He, J.J. Yin, J. Am. Chem. Soc. 135, 15750–15753 (2013)10.1021/ja4092903 ↗
45. H. Cui, Y. Zhou, J. Mei, Z. Li, S. Xu, C. Yao, J. Phys. Chem. Solids 112, 80–87 (2018)10.1016/j.jpcs.2017.09.011 ↗
46. P.S.V. Mocherla, D. Prabhu, M.B. Sahana, N.Y. Hebalkar, R. Gopalan, M.S.R. Rao, C. Sudakar, J. Appl. Phys. 124, 48 (2018)10.1063/1.5038007 ↗
47. H. Wang, L. Zhang, C. Hu, X. Wang, L. Lyu, G. Sheng, Chem. Eng. J. 332, 572–581 (2018)10.1016/j.cej.2017.09.058 ↗
48. P. Hong, K. Zhang, J. He, Y. Li, Z. Wu, C. Xie, J. Liu, L. Kong, J. Hazard. Mater. 435, 128958 (2022)10.1016/j.jhazmat.2022.128958 ↗
49. Z. Liu, J. Cheng, O. Hoefft, F. Endres, Metals. 12, 4143061 (2022)
50. G. Wu, Y. Zhang, J. Sun, X. Chen, Z. Zhang, G. Wang, M. Liu, Appl. Surf. Sci. 571, 151268 (2022)10.1016/j.apsusc.2021.151268 ↗
51. S. Xin, G. Liu, X. Ma, J. Gong, B. Ma, Q. Yan, Q. Chen, D. Ma, G. Zhang, M. Gao, Y. Xin, Appl. Catal. B 280, 119386 (2021)10.1016/j.apcatb.2020.119386 ↗
52. L. Lyu, L. Zhang, G. He, H. He, C. Hu, J. Mater. Chem. A 5, 7153–7164 (2017)10.1039/C7TA01583F ↗
53. Y. Shi, J. Li, D. Huang, X. Wang, Y. Huang, C. Chen, R. Li, ACS Catal. 13, 445–458 (2023)10.1021/acscatal.2c04228 ↗
54. W. Zou, J. Dong, M. Ji, B. Wang, Y. Li, S. Yin, H. Li, J. Xia, A.C.S. Appl, Nano Mater. (2023). https://doi.org/10.1021/acsanm.2c0544810.1021/acsanm.2c05448 ↗
55. X. Chen, W. Fu, Z. Yang, Y. Yang, Y. Li, H. Huang, X. Zhang, B. Pan, Water Res. 230, 119562 (2023)10.1016/j.watres.2022.119562 ↗
56. J. Zhang, S. Shao, X. Ding, Z. Li, J. Jing, W. Jiao, Y. Liu, Environ. Sci. Pollut. Res. 29, 34830–34840 (2022)10.1007/s11356-021-18093-y ↗
57. W. Deng, F. Pan, B. Batchelor, B. Jung, P. Zhang, A. Abdel-Wahab, H. Zhou, Y. Li, Environ. Sci. Wat. Res. Technol. 5, 769–781 (2019)10.1039/C8EW00922H ↗
58. W.D. Zhang, F. Dong, T. Xiong, Q. Zhang, Ceram. Int. 40, 9003–9008 (2014)10.1016/j.ceramint.2014.01.112 ↗
59. M. Wei, Y. Han, Y. Liu, B. Su, H. Yang, Z. Lei, J. Alloys Compd. 831, 154702 (2020)10.1016/j.jallcom.2020.154702 ↗
60. L. Li, M. Cheng, E. Almatrafi, L. Qin, S. Liu, H. Yi, L. Yang, Z. Chen, D. Ma, M. Zhang, X. Zhou, F. Xu, C. Zhou, L. Tang, G. Zeng, C. Lai, J. Hazard. Mater. 457, 131800–131800 (2023)10.1016/j.jhazmat.2023.131800 ↗
61. X. Wu, R. Han, Q. Liu, Y. Su, S. Lu, L. Yang, C. Song, N. Ji, D. Ma, X. Lu, Catal. Sci. Technol. 11, 5374–5387 (2021)10.1039/D1CY00478F ↗
62. F. Xia, Z. Nan, Funct. Mater. Lett. 13, 2050002 (2020)10.1142/S1793604720500022 ↗
63. L. Qin, Z. Wang, Y. Fu, C. Lai, X. Liu, B. Li, S. Liu, H. Yi, L. Li, M. Zhang, Z. Li, W. Cao, Q. Niu, J. Hazard. Mater. 414, 125448 (2021)10.1016/j.jhazmat.2021.125448 ↗
64. Y.P. Bhoi, B.G. Mishra, Chem. Eng. J. 344, 391–401 (2018)10.1016/j.cej.2018.03.094 ↗
65. L. Li, Y. Liu, S. Zhang, M. Liang, F. Li, Y. Yuan, J. Hazard. Mater. 399, 122883 (2020)10.1016/j.jhazmat.2020.122883 ↗
66. X.S. Cheng, L. Liang, J.Y. Ye, N. Li, B.B. Yan, G.Y. Chen, Sci. Total. Environ. 888, 132272 (2023)10.1016/j.scitotenv.2023.164086 ↗
67. X. Yang, P.Q. Wu, W. Chu, G.L. Wei, J. Wat. Process. Eng. 43, 103850 (2023)
68. L. Lyu, L. Zhang, C. Hu, Chem. Eng. J. 274, 298–306 (2015)10.1016/j.cej.2015.03.137 ↗
69. G. Pliego, J.A. Zazo, P. Garcia-Munoz, M. Munoz, J.A. Casas, J.J. Rodriguez, Crit. Rev. Environ. Sci. Technol. 45, 2611–2692 (2015)10.1080/10643389.2015.1025646 ↗
70. M.R.K. Kashani, R. Kiani, A. Hassani, A. Kadier, S. Madihi-Bidgoli, K.Y.A. Lin, F. Ghanbari, Sep. Purif. Technol. 292, 121026 (2022)10.1016/j.seppur.2022.121026 ↗
71. A. Eslami, M. Moradi, F. Ghanbari, F. Mehdipour, J. Environ. Health Sci. Eng. 11, 1–8 (2013)10.1186/2052-336X-11-31 ↗
72. W. Li, X. Li, C. Han, L. Gao, H. Wu, M. Li, Sci. Total. Environ. 855, 158963 (2023)10.1016/j.scitotenv.2022.158963 ↗
73. D. Wu, X. Zhang, S. Liu, Z. Ren, Y. Xing, X. Jin, G. Ni, J. Alloys Compd. 909, 164671 (2022)10.1016/j.jallcom.2022.164671 ↗
74. S. Wei, S. Fan, M. Zhang, J. Ren, B. Jia, Y. Wang, R. Wu, Z. Fang, Q. Liang, Mater. Today Sustain. 21, 329–336 (2023)
75. J. Nie, X. Yu, Y. Wei, Z. Liu, J. Zhang, Z. Yu, Y. Ma, B. Yao, Process Saf. Environ. Protect. 170, 241–258 (2023)10.1016/j.psep.2022.12.002 ↗
76. Y. Zhao, H. Guo, J. Liu, Q. Xia, J. Liu, X. Liang, E. Liu, J. Fan, J. Colloid Interface Sci. 627, 180–193 (2022)10.1016/j.jcis.2022.07.046 ↗
77. Y. Zhou, J. He, J. Lu, Y. Liu, Y. Zhou, Chin. Chem. Lett. 31, 2623–2626 (2020)10.1016/j.cclet.2020.02.008 ↗