journal article·2022-08-14

Chemical vapor deposition growth of magnesium-doped hexagonal boron nitride films via in situ doping

Ranjan Singhal, Elena Echeverria, David N. McIlroy, Raj N. Singh

Journal of Materials Research· Volume 37· Issue 15
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Abstract

In this study, direct, single-step growth of bandgap-tunable magnesium-doped hexagonal boron nitride (hBN) films on silicon (100) substrates via in situ doping by low-pressure chemical vapor deposition is accomplished. Magnesium nitride is used as the magnesium source, and ammonia borane was used as a single-source precursor for boron and nitrogen for the CVD growth of Mg-doped hBN films. The grown films are analyzed by X-ray photoelectron spectroscopy, and the bandgap analysis of the Mg-doped hBN films is established for the first time by UV–vis spectroscopy. X-ray fluorescence spectroscopy is applied for the first time for qualitative and semi-quantitative analysis of the grown films. It is found that Mg is successfully incorporated into the hBN films, and Mg-doped hBN films with tunable bandgap are grown by controlling the Mg concentration in the grown films.Graphical abstractKubelka-Munk function vs. Wavelength of Mg-doped hBN films
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Research context

OpenAlex topics: Graphene research and applications · Diamond and Carbon-based Materials Research · 2D Materials and Applications

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References (29)

Show source-provided references
1. M. Jana, R.N. Singh, Progress in CVD synthesis of layered hexagonal boron nitride with tunable properties and their applications. Int. Mater. Rev. 63, 162–203 (2018). https://doi.org/10.1080/09506608.2017.132283310.1080/09506608.2017.1322833 ↗
2. S. Roy, X. Zhang, A.B. Puthirath, A. Meiyazhagan, S. Bhattacharyya, M.M. Rahman, G. Babu, S. Susarla, S.K. Saju, M.K. Tran, L.M. Sassi, M.A.S.R. Saadi, J. Lai, O. Sahin, S.M. Sajadi, B. Dharmarajan, D. Salpekar, N. Chakingal, A. Baburaj, X. Shuai, A. Adumbumkulath, K.A. Miller, J.M. Gayle, A. Ajnsztajn, T. Prasankumar, V.V.J. Harikrishnan, V. Ojha, H. Kannan, A.Z. Khater, Z. Zhu, S.A. Iyengar, P.A. da S. Autreto, E.F. Oliveira, G. Gao, A.G. Birdwell, M.R. Neupane, T.G. Ivanov, J. Taha-Tijerina, R.M. Yadav, S. Arepalli, R. Vajtai, P.M. Ajayan, Structure, properties and applications of two-dimensional hexagonal boron nitride. Adv. Mater. 33, 1–48 (2021).10.1002/adma.202101589 ↗
3. A.K. Geim, K.S. Novoselov, The rise of graphene. Nat. Mater. 6, 183–191 (2007). https://doi.org/10.1038/nmat184910.1038/nmat1849 ↗
4. G. Cassabois, P. Valvin, B. Gil, Hexagonal boron nitride is an indirect bandgap semiconductor. Nat. Photonics 10, 262–266 (2016). https://doi.org/10.1038/nphoton.2015.27710.1038/nphoton.2015.277 ↗
5. M.S. Bresnehan, M.J. Hollander, M. Wetherington, K. Wang, T. Miyagi, G. Pastir, D.W. Snyder, J.J. Gengler, A.A. Voevodin, W.C. Mitchel, J.A. Robinson, Prospects of direct growth boron nitride films as substrates for graphene electronics. J. Mater. Res. 29, 459–471 (2014). https://doi.org/10.1557/jmr.2013.32310.1557/jmr.2013.323 ↗
6. M. Sajjad, W.M. Jadwisienczak, P. Feng, Nanoscale structure study of boron nitride nanosheets and development of a deep-UV photo-detector. Nanoscale 6, 4577–4582 (2014). https://doi.org/10.1039/c3nr05817d10.1039/c3nr05817d ↗
7. H. Liu, J. Meng, X. Zhang, Y. Chen, Z. Yin, D. Wang, Y. Wang, J. You, M. Gao, P. Jin, High-performance deep ultraviolet photodetectors based on few-layer hexagonal boron nitride. Nanoscale 10, 5559–5565 (2018). https://doi.org/10.1039/c7nr09438h10.1039/c7nr09438h ↗
8. K. Watanabe, T. Taniguchi, T. Niiyama, K. Miya, M. Taniguchi, Far-ultraviolet plane-emission handheld device based on hexagonal boron nitride. Nat. Photonics 3, 591–594 (2009). https://doi.org/10.1038/nphoton.2009.16710.1038/nphoton.2009.167 ↗
9. J. Wu, B. Wang, Y. Wei, R. Yang, M. Dresselhaus, Mechanics and mechanically tunable band gap in single-layer hexagonal boron-nitride. Mater. Res. Lett. 1, 200–206 (2013). https://doi.org/10.1080/21663831.2013.82451610.1080/21663831.2013.824516 ↗
10. E. Almahmoud, J.A. Talla, Band gap tuning in carbon doped boron nitride mono sheet with Stone- Wales defect: a simulation study Band gap tuning in carbon doped boron nitride mono sheet with Stone-Wales defect : a simulation study. Mater. Res. Express (2019). https://doi.org/10.1088/2053-1591/ab39a310.1088/2053-1591/ab39a3 ↗
11. A. Bhattacharya, S. Bhattacharya, G.P. Das, Band gap engineering by functionalization of BN sheet. Phys. Rev. B (2012). https://doi.org/10.1103/PhysRevB.85.035415.10.1103/PhysRevB.85.035415 ↗
12. F. Meng, S. Zhang, I.H. Lee, S. Jun, C.V. Ciobanu, Strain-tunable half-metallicity in hybrid graphene-hBN monolayer superlattices. Appl. Surf. Sci. 375, 179–185 (2016). https://doi.org/10.1016/j.apsusc.2016.03.08510.1016/j.apsusc.2016.03.085 ↗
13. L. Ci, L. Song, C. Jin, D. Jariwala, D. Wu, Y. Li, A. Srivastava, Z.F. Wang, K. Storr, L. Balicas, F. Liu, P.M. Ajayan, Atomic layers of hybridized boron nitride and graphene domains. Nat. Mater. 9, 430–435 (2010). https://doi.org/10.1038/nmat271110.1038/nmat2711 ↗
14. K. Nose, H. Oba, T. Yoshida, Electric conductivity of boron nitride thin films enhanced by in situ doping of zinc. Appl. Phys. Lett. 89, 3–6 (2006). https://doi.org/10.1063/1.235400910.1063/1.2354009 ↗
15. M. Sakamoto, J.S. Speck, M.S. Dresselhaus, Cesium and bromine doping into hexagonal boron nitride. J. Mater. Res. 1, 685–692 (1986). https://doi.org/10.1557/JMR.1986.068510.1557/JMR.1986.0685 ↗
16. J. Wu, L. Yin, L. Zhang, Tuning the electronic structure, bandgap energy and photoluminescence properties of hexagonal boron nitride nanosheets via a controllable Ce 3+ ions doping. RSC Adv. 3, 7408–7418 (2013). https://doi.org/10.1039/c3ra23132a10.1039/c3ra23132a ↗
17. Y. Wang, G. Liu, S. Lu, H. Zhang, G. Du, X. Chen, D. Cai, B. Guo, G. Du, X. Chen, D. Cai, J. Kang, Enhancement of p-type conductivity of monolayer hexagonal boron nitride by driving Mg incorporation through low- energy path with N-rich condition. Appl. Phys. Lett. (2020). https://doi.org/10.1063/5.0004923.10.1063/5.0004923 ↗
18. R. Dahal, J. Li, S. Majety, B.N. Pantha, X.K. Cao, J.Y. Lin, H.X. Jiang, Epitaxially grown semiconducting hexagonal boron nitride as a deep ultraviolet photonic material. Appl. Phys. Lett. (2011). https://doi.org/10.1063/1.3593958.10.1063/1.3593958 ↗
19. H.X. Jiang, J.Y. Lin, Hexagonal boron nitride for deep ultraviolet photonic devices. Semicond. Sci. Technol. (2014). https://doi.org/10.1088/0268-1242/29/8/084003.10.1088/0268-1242/29/8/084003 ↗
20. R. Trehan, Y. Lifshitz, J.W. Rabalais, Auger and x‐ray electron spectroscopy studies of h BN, c BN, and N + 2 ion irradiation of boron and boron nitride. J. Vac. Sci. Technol. A 8, 4026–4032 (1990). https://doi.org/10.1116/1.576471.10.1116/1.576471 ↗
21. T.D. Thomas, P. Weightman, Valence electronic structure of AuZn and AuMg alloys derived from a new way of analyzing Auger-parameter shifts. Phys. Rev. B. 33, 5406–5413 (1986). https://doi.org/10.1103/PhysRevB.33.5406.10.1103/PhysRevB.33.5406 ↗
22. H. Seyama, M. Soma, X-ray photoelectron spectroscopic study of montmorillonite containing exchangeable divalent cations. J. Chem. Soc. Faraday Trans. 80, 237–248 (1984). https://doi.org/10.1039/F19848000237.10.1039/F19848000237 ↗
23. J. Deng, G. Chen, Surface properties of cubic boron nitride thin films. Appl. Surf. Sci. 252, 7766–7770 (2006). https://doi.org/10.1016/j.apsusc.2005.09.06610.1016/j.apsusc.2005.09.066 ↗
24. X.D. Peng, D.S. Edwards, M.A. Barteau, Reactions of O2 and H2O with magnesium nitride films. Surf. Sci. 195, 103–114 (1988). https://doi.org/10.1016/0039-6028(88)90783-210.1016/0039-6028(88)90783-2 ↗
25. Thermo Fisher Scientific, Safety Data Sheet - Magnesium Nitride, Revis. Number 2. (2020). https://www.alfa.com/en/msds/?language=EN&subformat=AGHS&sku=41946.
26. S. Smolek, C. Streli, N. Zoeger, P. Wobrauschek, Improved micro x-ray fluorescence spectrometer for light element analysis. Rev. Sci. Instrum. 81, 053707 (2010). https://doi.org/10.1063/1.342873910.1063/1.3428739 ↗
27. S. Landi, I.R. Segundo, E. Freitas, M. Vasilevskiy, J. Carneiro, C.J. Tavares, Use and misuse of the Kubelka-Munk function to obtain the band gap energy from diffuse reflectance measurements. Solid State Commun. 341, 1–7 (2022). https://doi.org/10.1016/j.ssc.2021.11457310.1016/j.ssc.2021.114573 ↗
28. R. Singhal, E. Echeverria, D.N. McIlroy, R.N. Singh, Synthesis of hexagonal boron nitride films on silicon and sapphire substrates by low-pressure chemical vapor deposition. Thin Solid Films 733, 138812 (2021). https://doi.org/10.1016/j.tsf.2021.13881210.1016/j.tsf.2021.138812 ↗
29. A.S. Hassanien, A.A. Akl, Effect of Se addition on optical and electrical properties of chalcogenide CdSSe thin films. Superlattices Microstruct. 89, 153–169 (2016). https://doi.org/10.1016/j.spmi.2015.10.04410.1016/j.spmi.2015.10.044 ↗