journal article·2003-04

Conversion of uniform colloidal Cu2O spheres to copper in polyols

Zorica Crnjak Orel, Egon Matijević, Dan V. Goia

Journal of Materials Research· Volume 18· Issue 4
Publisher page

Abstract

Colloidal copper particles with a high degree of crystallinity were obtained by heating solutions of copper(II) acetate in ethylene glycol (EG) and tetraethylene glycol (TEG). The formation mechanism of copper particles involved first the formation of sparingly soluble nano-sized copper(I) oxide, which aggregated into uniform spheres. On prolonged heating the Cu2O particles were reduced to nano-sized copper crystallites followed by their sintering to colloidal metal. The conversion of the copper(I) oxide to metallic copper proceeds uniformly within the body of each particle.
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Research context

OpenAlex topics: Laser-Ablation Synthesis of Nanoparticles · Gold and Silver Nanoparticles Synthesis and Applications · Pickering emulsions and particle stabilization

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (28)

Show source-provided references
1. 10.1021/jp992950g10.1021/jp992950g ↗
2. 10.1006/jcis.1999.610610.1006/jcis.1999.6106 ↗
3. 10.1016/S0927-7757(98)00790-010.1016/S0927-7757(98)00790-0 ↗
4. 10.1016/S0001-8686(02)00056-810.1016/S0001-8686(02)00056-8 ↗
5. 10.1557/JMR.1990.108310.1557/JMR.1990.1083 ↗
6. 10.1021/la00079a00510.1021/la00079a005 ↗
7. Rao · J. Electroanal. Chem. · 1969 · 334 · 116
8. 10.1039/jm993030062710.1039/jm9930300627 ↗
9. Figlarz · U.S. Patent No. 4 · 1985 · 539 · 041
10. 10.1016/0022-4596(92)90101-Z10.1016/0022-4596(92)90101-Z ↗
11. 10.1557/S088376940006093010.1557/S0883769400060930 ↗
12. 10.1016/S0169-4332(00)00345-710.1016/S0169-4332(00)00345-7 ↗
13. 10.1016/S0167-577X(96)00224-810.1016/S0167-577X(96)00224-8 ↗
14. 10.1016/0032-5910(90)80052-Z10.1016/0032-5910(90)80052-Z ↗
15. 10.1021/la00024a05510.1021/la00024a055 ↗
16. Masussek · 1970
17. Larry · 1980 · 168
18. Mills · 1979 · 16
19. 10.1007/978-1-4684-7882-210.1007/978-1-4684-7882-2 ↗
20. Ernst · J. Electroanal. Chem. · 1979 · 173 · 100
21. 10.1016/0167-2738(89)90222-110.1016/0167-2738(89)90222-1 ↗
22. Weiser · 1933 · 1 · 131
23. Hamer · 1972
24. 10.1006/jcis.1996.464710.1006/jcis.1996.4647 ↗
25. 10.1021/ja00842a04410.1021/ja00842a044 ↗
26. Fie´vet · 2000 · 460
27. Vosson · 1970
28. 10.1021/cr60295a00210.1021/cr60295a002 ↗