Effect of Sn on microstructure and properties of Ti–Zr–Nb–Sn medium-entropy alloys (MEAs)
Source abstract
Abstract
Ti-rich body-centered cubic (BCC) high-entropy alloys (HEAs) and medium-entropy alloys (MEAs) are regarded as potential biomaterials due to their excellent biocompatibility, corrosion resistance, and comprehensive performance. In this study, three as-cast Ti–Zr–Nb–Sn MEAs (Ti45Zr45Nb7Sn3, Ti45Zr45Nb5Sn5, and Ti45Zr45Nb3Sn7) were prepared and characterized in detail. Results show that all three MEAs presented a dendritic morphology with single BCC structure, and their elastic modulus was less than 60 GPa. The yield strength of Ti–Zr–Nb–Sn MEAs increased from 775 to 833 MPa due to the solid solution strengthening effect caused by Sn addition, but their tensile ductility decreased from 11 ± 0.5 to 8 ± 0.8%. The addition of Sn content lowered the corrosion resistance of Ti–Zr–Nb–Sn MEAs in phosphate buffer saline solution, and pitting corrosion occurred on the surface with the excessive addition of Sn element. These Ti–Zr–Nb–Sn MEAs with above-mentioned properties can provide references for the design of biomedical materials.Graphical abstract
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: High Entropy Alloys Studies · Titanium Alloys Microstructure and Properties · Orthopaedic implants and arthroplasty
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (47)
Show source-provided references
1. X.Y. Yang, C.R. Hutchinson, Acta Biomater. 42, 429–439 (2016)10.1016/j.actbio.2016.07.008 ↗
2. S, Y, Zhang, Y, C, Yu, H. Wang, R. Ling, K, Yang, J. Mech. Behav. Biomde. 125, 104926(2022)10.1016/j.jmbbm.2021.104926 ↗
3. M. Niinomi, Metall. Mater. Trans. A 33, 477–486 (2002)10.1007/s11661-002-0109-2 ↗
4. Q.Z. Chen, G.A. Thouas, Mat. Sci. Eng. R. 87, 1–57 (2015)10.1016/j.mser.2014.10.001 ↗
5. M. Niinomi, M. Nakai, J. Hieda, Acta Biomater. 8, 3888–3903 (2012)10.1016/j.actbio.2012.06.037 ↗
6. S.S. Sidhu, H. Singh, M. Gepreel, Mat. Sci. Eng. C 121, 111661 (2021)10.1016/j.msec.2020.111661 ↗
7. M. Kaur, K. Singh, Mat. Sci. Eng. C. 102, 844–862 (2019)10.1016/j.msec.2019.04.064 ↗
8. J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, C.H. Tsau, S.Y. Chang, Adv. Eng. Mater. 6, 299–303 (2004)10.1002/adem.200300567 ↗
9. E.P. George, W.A. Curtin, C.C. Tasan, Acta Mater. 188, 435–474 (2020)10.1016/j.actamat.2019.12.015 ↗
10. Z.Z. Li, S.T. Zhao, R.O. Ritchie, A. Marc, Prog. Mater. Sci. 102, 296–345 (2019)10.1016/j.pmatsci.2018.12.003 ↗
11. H.W. Yao, J.W. Qiao, M.C. Gao, J.A. Hawk, S.G. Ma, H.F. Zhou, Y. Zhang, Mat. Sci. Eng. A 674, 203–211 (2016)10.1016/j.msea.2016.07.102 ↗
12. B. Gludovatz, A. Hohenwarter, D. Catoor, E.P. George, Science 345, 1153–1158 (2014)10.1126/science.1254581 ↗
13. J.Y. He, H. Wang, H.L. Huang, X.D. Xu, Z.P. Lu, Acta Mater. 102, 187–196 (2016)10.1016/j.actamat.2015.08.076 ↗
14. Y.L. Chou, J.W. Yeh, H.C. Shih, Corros. Sci. 52, 2571–2581 (2010)10.1016/j.corsci.2010.04.004 ↗
15. M.K. Wang, J.H. Yuan, F.Y. Yu, Q. Wang, P.K. Liaw, Metall. Mater. Trans. A 52, 1–11 (2021)
16. V.T. Nguyen, M. Qian, Z. Shi, T. Song, J. Zou, Intermetallics 101, 39–43 (2018)10.1016/j.intermet.2018.07.008 ↗
17. P.H. Couzinié, L. Lilensten, Y. Champion, G. Dirras, L. Perrière, I. Guillot, Mat. Sci. Eng. A 645, 255–263 (2015)10.1016/j.msea.2015.08.024 ↗
18. S.P. Wang, X. Jian, Mat. Sci. Eng. C 73, 80–89 (2017)10.1016/j.msec.2016.12.057 ↗
19. H.W. Yao, J.W. Qiao, J.A. Hawk, H.F. Zhou, M.W. Chen, M.C. Gao, J. Alloys Compd. 696, 1139–1150 (2017)10.1016/j.jallcom.2016.11.188 ↗
20. W.J. Lai, H. Liu, X. Yu, Y.L. Yi, W. Li, S.F. Zhou, S.G. Cui, X.J. Wang, Mat. Sci. Eng. A 813, 141135 (2021)10.1016/j.msea.2021.141135 ↗
21. M. Ning, S.F. Liu, W. Liu, L.C. Xie, D.X. Wei, L.Q. Wang, L.J. Li, B.B. Zhao, Y. Wang, Front. Bioeng Biotech. 8, 1–18 (2020)10.3389/fbioe.2020.00001 ↗
22. Y.X. Guo, X.M. Li, Q.B. Liu, Mater. Design 196, 109085 (2020)10.1016/j.matdes.2020.109085 ↗
23. T. Nagasea, Y. Iijima, A. Matsugaki, K. Ameyama, T. Nakano, Mat. Sci. Eng. C 107, 110322 (2020)10.1016/j.msec.2019.110322 ↗
24. W. Yang, Y. Liu, S.J. Pang, P.K. Liaw, T. Zhang, Intermetallics 124, 106845 (2020)10.1016/j.intermet.2020.106845 ↗
25. T. Hori, T. Nagase, M. Todai, A. Matsugaki, T. Nakano, Scripta Mater. 172, 83–87 (2019)10.1016/j.scriptamat.2019.07.011 ↗
26. M. Niinomi, TMS. 51, 32–34 (1999)
27. S.W. Hu, T.J. Li, Z.Q. Su, D.X. Liu, Intermetallics 140, 107401 (2022)10.1016/j.intermet.2021.107401 ↗
28. Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, A. Dahmen, P.K. Liaw, Z.P. Lu, Prog. Mater. Sci. 61, 1–93 (2014)10.1016/j.pmatsci.2013.10.001 ↗
29. B. Ren, Z.X. Liu, D.M. Li, L. Shi, B. Cai, M.X. Wang, J. Alloys Compd. 493, 148–153 (2010)10.1016/j.jallcom.2009.12.183 ↗
30. B. Cantor, Prog. Mater. Sci. 120, 100754 (2021)10.1016/j.pmatsci.2020.100754 ↗
31. Y.L. Hao, S.J. Li, S.Y. Sun, C.Y. Zheng, R. Yang, Acta Biomater. 3, 277–286 (2007)10.1016/j.actbio.2006.11.002 ↗
32. M. Geetha, A.K. Singh, R. Asokamani, A.K. Gogia, Prog. Mater. Sci. 54, 397–425 (2009)10.1016/j.pmatsci.2008.06.004 ↗
33. M.T. Mohammed, Z.A. Khan, A.N. Siddiquee, Int. J. Min. Met. Mater. 8, 726–731 (2014)
34. B. Jiang, Q. Wang, D. Wen, F. Xu, G. Chen, C. Dong, L. Sun, P.K. Liaw, Mat. Sci. Eng. A. 687, 1–7 (2017)10.1016/j.msea.2017.01.047 ↗
35. H.C. Hsu, S.C. Wu, S.K. Hsu, J.Y. Syu, W.F. Ho, Mat. Sci. Eng. A 568, 1–7 (2013)10.1016/j.msea.2013.01.002 ↗
36. S. Guo, Y.L. Shi, G.L. Liu, R.T. Wu, R. Luo, C.T. Peng, Q.K. Meng, X.N. Cheng, X.Q. Zhao, J. Alloys Compd. 805, 517–521 (2019)10.1016/j.jallcom.2019.07.109 ↗
37. S.W. Hu, T.J. Li, Z.Q. Su, S.J. Meng, Z. Jia, D.X. Liu, Mat. Sci. Eng. B 270, 115226 (2021)10.1016/j.mseb.2021.115226 ↗
38. A. Motallebzadeh, N.S. Peighambardoust, S. Sheikh, H. Murakami, S. Guo, D. Canadinc, Intermetallics 113, 106572 (2019)10.1016/j.intermet.2019.106572 ↗
39. N.B. Hua, W.J. Wang, Q.T. Wang, Y.X. Ye, S.H. Lin, L. Zhang, Q.H. Guo, J. Brechtl, P.K. Liaw, J. Alloys Compd. 861, 157997 (2021)10.1016/j.jallcom.2020.157997 ↗
40. Q.T. Song, J. Xu, Corros. Sci. 167, 108513 (2020)10.1016/j.corsci.2020.108513 ↗
41. S. Gurel, M.B. Yagci, B. Bal, D. Canadinc, Mater. Chem. Phys. 254, 123377 (2020)10.1016/j.matchemphys.2020.123377 ↗
42. M. Pourbaix, Biomaterials 5, 122–134 (1984)10.1016/0142-9612(84)90046-2 ↗
43. D.R. Knittel, A. Bronson, Corrosion 40, 9–14 (1984)10.5006/1.3579296 ↗
44. M.R. Hurtado, P.T. Sumodjo, A.V. Benedetti, Electrochim. Acta 48, 2791–2798 (2003)10.1016/S0013-4686(03)00413-4 ↗
45. R. Chelariu, L.C. Trinca, C. Munteanu, G. Bolat, D. Sutiman, D. Mareci, R.M. Souto, Electrochim. Acta 248, 368–375 (2017)10.1016/j.electacta.2017.07.157 ↗
46. Y.H. Chen, W.S. Chuang, J.C. Huang, X. Wang, H.S. Chou, Y.J. Lai, P.H. Lin, Appl. Surf. Sci. 508, 145307 (2020)10.1016/j.apsusc.2020.145307 ↗
47. B.E. Conway, J.O. Bockris, R.E. White, Z. Phys. Chem. 29, 287–288 (1983)