Critical overview of polyanionic frameworks as positive electrodes for Na-ion batteries
Source abstract
Abstract
Na-ion batteries (NIBs) are an important technological alternative to Li-ion batteries (LIBs) for developing energy storage systems that are cost-effective and less constrained by geographical supply chains, with similar energy densities. Analogous to LIBs, cathodes play a critical role in determining the energy density of NIBs, and layered transition metal oxide compounds are widely used as NIB cathodes. However, the instability-driven irreversible phase transitions in layered frameworks, especially at large degrees of Na removal, has necessitated the exploration of rigid structural frameworks that are resistant to structural changes with Na exchange. Thus, polyanionic frameworks, which primarily consist of transition metal polyhedra interconnected by PO4, SiO4, and/or SO4units, with or without the presence of fluorine, have been investigated as NIB cathodes. This review provides a critical overview of recent studies using polyanion cathodes, which will be useful in guiding the scientific community towards the development of better NIB cathodes.Graphical abstract
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication
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References (100+)
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1. T. Chen, Y. Jin, H. Lv, A. Yang, M. Liu, B. Chen, Y. Xie, Q. Chen, Applications of lithium-ion batteries in grid scale energy storage systems. Trans. Tianjin Univ. 26, 208 (2020)10.1007/s12209-020-00236-w ↗
2. Y. Ding, Z.P. Cano, A. Yu, J. Lu, Z. Chen, Automotive Li-ion batteries: Current status and future perspectives. Electrochem. Energy Rev. 2(1), 1 (2019)10.1007/s41918-018-0022-z ↗
3. G. Zubi, R. Dufo-López, M. Carvalho, G. Pasaoglu, The lithium-ion battery: State of the art and future perspectives. Renew. Sustain. Energy Rev. 89, 292 (2018)10.1016/j.rser.2018.03.002 ↗
4. H. Epstein, S.M. O’Flarity, Considerations for reducing aviation’s CO2 with aircraft electric propulsion. J. Propul. Power 35(3), 572 (2019)10.2514/1.B37015 ↗
5. S. Sripad, V. Viswanathan, Evaluation of current, future, and beyond Li-ion batteries for the electrification of light commercial vehicles: Challenges and opportunities. J. Electrochem. Soc. 164(11), E3635 (2017)10.1149/2.0671711jes ↗
6. J.B. Quinn, T. Waldmann, K. Richter, M. Kasper, M. Wohlfahrt-Mehrens, Energy density of cylindrical Li-ion cells: A comparison of commercial 18650 to the 21700 cells. J. Electrochem. Soc. 165(14), A3284 (2018)10.1149/2.0281814jes ↗
7. M.S. Whittingham, History, evolution, and future status of energy storage. Proc. IEEE 100, 1518 (2012)10.1109/JPROC.2012.2190170 ↗
8. M.S. Whittingham, Ultimate limits to intercalation reactions for lithium batteries. Chem. Rev. 114(23), 11414 (2014)10.1021/cr5003003 ↗
9. G. Assat, J.M. Tarascon, Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries. Nat. Energy 3(5), 373 (2018)10.1038/s41560-018-0097-0 ↗
10. M. Naor, N. Adler, G.D. Pinto, A. Dumanis, Psychological safety in aviation new product development teams: Case study of 737 max airplane. Sustainability 12(21), 8994 (2020)10.3390/su12218994 ↗
11. Q. Zhao, Y. Lu, J. Chen, Advanced organic electrode materials for rechargeable sodium-ion batteries. Adv. Energy Mater. 7(8), 1601792 (2017)10.1002/aenm.201601792 ↗
12. C. Vaalma, D. Buchholz, M. Weil, S. Passerini, A cost and resource analysis of sodium-ion batteries. Nat. Rev. Mater. 3(4), 18013 (2018)10.1038/natrevmats.2018.13 ↗
13. K. Chayambuka, G. Mulder, D.L. Danilov, P.H.L. Notten, From Li-Ion batteries toward Na-ion chemistries: Challenges and opportunities. Adv. Energy Mater. 10(38), 2001310 (2020)10.1002/aenm.202001310 ↗
14. C. Delmas, Sodium and sodium-ion batteries: 50 years of research. Adv. Energy Mater. 8(17), 1703137 (2018)10.1002/aenm.201703137 ↗
15. A. Rudola, A.J.R. Rennie, R. Heap, S.S. Meysami, A. Lowbridge, F. Mazzali, R. Sayers, C.J. Wright, J. Barker, Commercialisation of high energy density sodium-ion batteries: Faradion’s journey and outlook. J. Mater. Chem. A 9(13), 8279 (2021)10.1039/D1TA00376C ↗
16. T. Liu, X. Yang, J. Nai, Y. Wang, Y. Liu, C. Liu, X. Tao, Recent development of Na metal anodes: Interphase engineering chemistries determine the electrochemical performance. Chem. Eng. J. 409, 127943 (2021)10.1016/j.cej.2020.127943 ↗
17. C. Delmas, D. Carlier, M. Guignard, The layered oxides in lithium and sodium-ion batteries: A solid-state chemistry approach. Adv. Energy Mater. 11(2), 2001201 (2021)10.1002/aenm.202001201 ↗
18. B. Wang, Y. Han, X. Wang, N. Bahlawane, H. Pan, M. Yan, Y. Jiang, Prussian blue analogs for rechargeable batteries. ISci. 3, 110 (2018)10.1016/j.isci.2018.04.008 ↗
19. X. Wu, C. Wu, C. Wei, L. Hu, J. Qian, Y. Cao, X. Ai, J. Wang, H. Yang, Highly crystallized Na2CoFe(CN)6 with suppressed lattice defects as superior cathode material for sodium-ion batteries. ACS Appl. Mater. Interfaces 8(8), 5393 (2016)10.1021/acsami.5b12620 ↗
20. T. Jin, H. Li, K. Zhu, P.F. Wang, P. Liu, L. Jiao, Polyanion-type cathode materials for sodium-ion batteries. Chem. Soc. Rev. 49, 2342 (2020)10.1039/C9CS00846B ↗
21. S.-W. Kim, D.-H. Seo, X. Ma, G. Ceder, K. Kang, Electrode materials for rechargeable sodium-ion batteries: Potential alternatives to current lithium-ion batteries. Adv. Energy Mater. 2(7), 710 (2012)10.1002/aenm.201200026 ↗
22. P.F. Wang, Y. You, Y.X. Yin, Y.G. Guo, Layered oxide cathodes for sodium-ion batteries: Phase transition, air stability, and performance. Adv. Energy Mater. 8(8), 1701912 (2018)10.1002/aenm.201701912 ↗
23. B. Senthilkumar, C. Murugesan, L. Sharma, S. Lochab, P. Barpanda, An overview of mixed polyanionic cathode materials for sodium-ion batteries. Small Methods 3(4), 1800253 (2019)10.1002/smtd.201800253 ↗
24. S.K. Sapra, J. Pati, P.K. Dwivedi, S. Basu, J.K. Chang, R.S. Dhaka, A comprehensive review on recent advances of polyanionic cathode materials in Na-ion batteries for cost effective energy storage applications. Wiley Interdiscip. Rev.: Energy Environ. 10(5), 400 (2021)
25. P. Barpanda, L. Lander, S.I. Nishimura, A. Yamada, Polyanionic insertion materials for sodium-ion batteries. Adv. Energy Mater. 8(17), 1703055 (2018)10.1002/aenm.201703055 ↗
26. Q. Zhang, Z. Yu, P. Du, C. Su, Carbon nanomaterials used as conductive additives in lithium ion batteries. Recent Pat. Nanotechnol. 4(2), 100 (2010)10.2174/187221010791208803 ↗
27. T.L. Shao, C. Liu, W. Deng, C. Li, X. Wang, M. Xue, R. Li, Metal oxide-based supercapacitors: Progress and prospectives. Batteries Supercaps 1(12), 4644 (2019)
28. P. Hohenberg, W. Kohn, Inhomogeneous electron gas. Phys. Rev. 136(3B), B864 (1964)10.1103/PhysRev.136.B864 ↗
29. W. Kohn, L.J. Sham, Self-consistent equations including exchange and correlation effects. Phys. Rev. 140(4A), 1133 (1965)10.1103/PhysRev.140.A1133 ↗
30. X. He, Y. Zhu, A. Epstein, Y. Mo, Statistical variances of diffusional properties from ab initio molecular dynamics simulations. NPJ Comput. Mater. 4, 18 (2018)10.1038/s41524-018-0074-y ↗
31. G. Henkelman, G. Jóhannesson, H. Jónsson, Progress on Theoretical Chemistry and Physics (Kluwer Academic, Switzerland, 2006), pp. 269–302
32. S. Adams, R.P. Rao, Understanding ionic conduction and energy storage materials with bond-valence-based methods. Struct. Bond. 158, 129 (2014)10.1007/430_2013_137 ↗
33. P. Canepa, G. Sai Gautam, D.C. Hannah, R. Malik, M. Liu, K.G. Gallagher, K.A. Persson, G. Ceder, Odyssey of multivalent cathode materials: Open questions and future challenges. Chem. Rev. 117(5), 4287 (2017)10.1021/acs.chemrev.6b00614 ↗
34. Y. Gao, T.P. Mishra, S.-H. Bo, G. Sai Gautam, P. Canepa, Design and characterization of host-frameworks for facile magnesium transport. Ann. Rev. Mater. Res. 52, 129 (2022)10.1146/annurev-matsci-081420-041617 ↗
35. J.L. Kaufman, J. Vinckevičiūtė, S. Krishna Kolli, J. Gabriel Goiri, A. van der Ven, Understanding intercalation compounds for sodium-ion batteries and beyond. Philos. Trans. R. Soc. Lond. Ser. A 377(2152), 20190020 (2019)
36. C. Delmas, C. Fouassier, P. Hagenmuller, Structural classification and properties of the layered oxides. Physica B+C 99(1–4), 81 (1980)10.1016/0378-4363(80)90214-4 ↗
37. J. Manzi, A. Paolone, O. Palumbo, D. Corona, A. Massaro, R. Cavaliere, A.B. Muñoz-García, F. Trequattrini, M. Pavone, S. Brutti, Monoclinic and orthorhombic NaMnO2 for secondary batteries: A comparative study. Energies 14(5), 1230 (2021)10.3390/en14051230 ↗
38. M.H. Han, E. Gonzalo, M. Casas-Cabanas, T. Rojo, Structural evolution and electrochemistry of monoclinic NaNiO2 upon the first cycling process. J. Power Sources 258, 266 (2014)10.1016/j.jpowsour.2014.02.048 ↗
39. X. Li, Y. Wang, D. Wu, L. Liu, S.-H. Bo, G. Ceder, Jahn-Teller assisted Na diffusion for high performance Na ion batteries. Chem. Mater. 28(18), 6575 (2016)10.1021/acs.chemmater.6b02440 ↗
40. L. Vitoux, M. Guignard, N. Penin, D. Carlier, J. Darriet, C. Delmas, NaMoO2: A layered oxide with molybdenum clusters. Inorg. Chem. 59(6), 4015 (2020)10.1021/acs.inorgchem.9b03688 ↗
41. J. Vinckevičiu̅tė, M. D. Radin, A. Ben, Stacking-sequence changes and Na ordering in layered intercalation materials. Chem. Mater. 28(23), 8640 (2016)10.1021/acs.chemmater.6b03609 ↗
42. T. Ma, G.-L. Xu, X. Zeng, Y. Li, Y. Ren, C. Sun, S.M. Heald, J. Jorne, K. Amine, Z. Chen, Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy. J. Power Sources 341, 114 (2017)10.1016/j.jpowsour.2016.11.022 ↗
43. K. Kubota, I. Ikeuchi, T. Nakayama, C. Takei, N. Yabuuchi, H. Shiiba, M. Nakayama, S. Komaba, New insight into structural evolution in layered NaCrO2 during electrochemical sodium extraction. J. Phys. Chem. C 119(1), 166 (2015)10.1021/jp5105888 ↗
44. Y. Lei, X. Li, L. Liu, G. Ceder, Synthesis and stoichiometry of different layered sodium cobalt oxides. Chem. Mater. 26(18), 5288 (2014)10.1021/cm5021788 ↗
45. A.J. Toumar, S.P. Ong, W.D. Richards, S. Dacek, G. Ceder, Vacancy ordering in O3-type layered metal oxide sodium-ion battery cathodes. Phys. Rev. Appl. 4(6), 64002 (2015)10.1103/PhysRevApplied.4.064002 ↗
46. J.L. Kaufman, A. van der Ven, NaxCoO2 phase stability and hierarchical orderings in the O3/P3 structure family. Phys. Rev. Mater. 3(1), 15402 (2019)10.1103/PhysRevMaterials.3.015402 ↗
47. M.D. Radin, J. Alvarado, Y.S. Meng, A. van der Ven, Role of crystal symmetry in the reversibility of stacking-sequence changes in layered intercalation electrodes. Nano Lett. 17(12), 7789 (2017)10.1021/acs.nanolett.7b03989 ↗
48. D. Hamani, M. Ati, J.M. Tarascon, P. Rozier, NaxVO2 as possible electrode for Na-ion batteries. Electrochem. Commun. 13(9), 938 (2011)10.1016/j.elecom.2011.06.005 ↗
49. A. Caballero, L. Hernán, J. Morales, L. Sánchez, J. Santos Peña, M.A.G. Aranda, Synthesis and characterization of high-temperature hexagonal P2-Na0.6MnO2 and its electrochemical behaviour as cathode in sodium cells. J. Mater. Chem. 12(4), 1142 (2002)10.1039/b108830k ↗
50. B.V.R. Reddy, R. Ravikumar, C. Nithya, S. Gopukumar, High performance NaxCoO2 as a cathode material for rechargeable sodium batteries. J. Mater. Chem. A 3(35), 18059 (2015)10.1039/C5TA03173G ↗
51. C.A. Marianetti, G. Kotliar, Na-induced correlations in NaxCoO2. Phys. Rev. Lett. 98(17), 176405 (2007)10.1103/PhysRevLett.98.176405 ↗
52. C. Delmas, J.-J. Braconnier, C. Fouassier, P. Hagenmuller, Electrochemical intercalation of sodium in NaxCoO2 bronzes. Solid State Ionics 3–4, 165 (1981)10.1016/0167-2738(81)90076-X ↗
53. M. Bianchini, J. Wang, R. Clément, G. Ceder, A first-principles and experimental investigation of nickel solubility into the P2 NaxCoO2 sodium-ion cathode. Adv. Energy Mater. 8(26), 1801446 (2018)10.1002/aenm.201801446 ↗
54. F. Tournadre, L. Croguennec, I. Saadoune, D. Carlier, Y. Shao-Horn, P. Willmann, C. Delmas, On the mechanism of the P2-Na0.70CoO2→O2-LiCoO2 exchange reaction - Part I: Proposition of a model to describe the P2–O2 transition. J. Solid State Chem. 177(8), 2790 (2004)10.1016/j.jssc.2004.04.027 ↗
55. H. Liu, X. Gao, J. Chen, J. Gao, S. Yin, S. Zhang, L. Yang, S. Fang, Y. Mei, X. Xiao, L. Chen, W. Deng, F. Li, G. Zou, H. Hou, X. Ji, Reversible OP4 phase in P2–Na2/3Ni1/3Mn2/3O2 sodium ion cathode. J. Power Sources 508, 230324 (2021)10.1016/j.jpowsour.2021.230324 ↗
56. A. Kulka, C. Marino, K. Walczak, C. Borca, C. Bolli, P. Novák, C. Villevieille, Influence of Na/Mn arrangements and P2/P′2 phase ratio on the electrochemical performance of NaxMnO2 cathodes for sodium-ion batteries. J. Mater. Chem. A 8(12), 6022 (2020)10.1039/C9TA12176E ↗
57. Y. Mo, S.P. Ong, G. Ceder, Insights into diffusion mechanisms in P2 layered oxide materials by first-principles calculations. Chem. Mater. 26(18), 5208 (2014)10.1021/cm501563f ↗
58. Y. Hinuma, Y.S. Meng, G. Ceder, Temperature-concentration phase diagram of P2-NaxCoO2 from first-principles calculations. Phys. Rev. B 77(22), 224111 (2008)10.1103/PhysRevB.77.224111 ↗
59. D.H. Lee, J. Xu, Y.S. Meng, An advanced cathode for Na-ion batteries with high rate and excellent structural stability. Phys. Chem. Chem. Phys. 15(9), 3304 (2013)10.1039/c2cp44467d ↗
60. R. Sayers, J. Barker, R. Heap, Compositions containing doped nickelate compounds. US10196280B2 (Faradion Ltd, 2019)
61. D. Wu, X. Li, B. Xu, N. Twu, L. Liu, G. Ceder, NaTiO2: A layered anode material for sodium-ion batteries. Energy Environ. Sci. 8(1), 195 (2015)10.1039/C4EE03045A ↗
62. N. Yabuuchi, H. Yoshida, S. Komaba, Crystal structures and electrode performance of alpha-NaFeO2 for rechargeable sodium batteries. Electrochemistry 80(10), 716 (2012)10.5796/electrochemistry.80.716 ↗
63. B. Singh, Z. Wang, S. Park, G.S. Gautam, J.N. Chotard, L. Croguennec, D. Carlier, A.K. Cheetham, C. Masquelier, P. Canepa, A chemical map of NaSICON electrode materials for sodium-ion batteries. J. Mater. Chem. A 9(1), 281 (2021)10.1039/D0TA10688G ↗
64. J.N. Chotard, G. Rousse, R. David, O. Mentré, M. Courty, C. Masquelier, Discovery of a sodium-ordered form of Na3V2(PO4)3 below ambient temperature. Chem. Mater. 27(17), 5982 (2015)10.1021/acs.chemmater.5b02092 ↗
65. Z. Deng, T. P. Mishra, E. Mahayoni, Q. Ma, O. Guillon, J-N. Chotard, V. Seznec, A. K. Cheetham, C. Masquelier, G. S. Gautam, P. Canepa, Theoretical and Experimental Studies of Ion Transport in Mixed Polyanion Solid Electrolytes. Under Review, (n.d.).
66. Z. Zou, N. Ma, A. Wang, Y. Ran, T. Song, Y. Jiao, J. Liu, H. Zhou, W. Shi, B. He, D. Wang, Y. Li, M. Avdeev, S. Shi, Relationships between Na+ distribution, concerted migration, and diffusion properties in rhombohedral NASICON. Adv. Energy Mater. 10(30), 2001486 (2020)10.1002/aenm.202001486 ↗
67. Y. Ishado, A. Inoishi, S. Okada, Exploring factors limiting three-Na+ extraction from Na3V2(PO4)3. Electrochemistry 88(5), 457 (2020)10.5796/electrochemistry.20-00080 ↗
68. Z. Zhang, Z. Zou, K. Kaup, R. Xiao, S. Shi, M. Avdeev, Y.S. Hu, D. Wang, B. He, H. Li, X. Huang, L.F. Nazar, L. Chen, Correlated migration invokes higher Na+-ion conductivity in NaSICON-type solid electrolytes. Adv. Energy Mater. 9(42), 1902373 (2019)10.1002/aenm.201902373 ↗
69. S.Y. Lim, H. Kim, R.A. Shakoor, Y. Jung, J.W. Choi, Electrochemical and thermal properties of NASICON structured Na3V2(PO4)3 as a sodium rechargeable battery cathode: A combined experimental and theoretical study. J. Electrochem. Soc. 159(9), A1393 (2012)10.1149/2.015209jes ↗
70. Z. Jian, L. Zhao, H. Pan, Y.S. Hu, H. Li, W. Chen, L. Chen, Carbon coated Na3V2(PO4)3 as novel electrode material for sodium ion batteries. Electrochem. Commun. 14(1), 86 (2012)10.1016/j.elecom.2011.11.009 ↗
71. X. Yao, Z. Zhu, Q. Li, X. Wang, X. Xu, J. Meng, W. Ren, X. Zhang, Y. Huang, L. Mai, High energy density symmetric sodium-ion battery: Na4V2(PO4)3∥Na3V2(PO4)3. ACS Appl. Mater. Interfaces 10(12), 10022 (2018)10.1021/acsami.7b16901 ↗
72. L. Bi, X. Li, X. Liu, Q. Zheng, D. Lin, Enhanced cycling stability and rate capability in a La-doped Na3V2(PO4)3/C cathode for high-performance sodium ion batteries. ACS Sustain. Chem. Eng. 7(8), 7693 (2019)10.1021/acssuschemeng.8b06385 ↗
73. S. Sun, Y. Chen, J. Cheng, Z. Tian, C. Wang, G. Wu, C. Liu, Y. Wang, L. Guo, Constructing dimensional gradient structure of Na3V2(PO4)3/C@CNTs-WC by wolfram substitution for superior sodium storage. Chem. Eng. J. 420(3), 130453 (2021)10.1016/j.cej.2021.130453 ↗
74. X. Li, Y. Huang, J. Wang, L. Miao, Y. Li, Y. Liu, Y. Qiu, C. Fang, J. Han, Y. Huang, High valence Mo-doped Na3V2(PO4)3/C as a high rate and stable cycle-life cathode for sodium battery. J. Mater. Chem. A 6(4), 1390 (2018)10.1039/C7TA08970H ↗
75. Y. Zhao, X. Cao, G. Fang, Y. Wang, H. Yang, S. Liang, A. Pan, G. Cao, Hierarchically carbon-coated Na3V2(PO4)3 nanoflakes for high-rate capability and ultralong cycle-life sodium ion batteries. Chem. Eng. J. 339, 162 (2018)10.1016/j.cej.2018.01.088 ↗
76. Q. Zhu, X. Chang, N. Sun, H. Liu, R. Chen, F. Wu, B. Xu, Microorganism-moulded pomegranate-like Na3V2(PO4)3/C nanocomposite for advanced sodium-ion batteries. J. Mater. Chem. A 5(20), 9982 (2017)10.1039/C7TA02165H ↗
77. L. Zhao, H. Zhao, X. Long, Z. Li, Z. Du, Superior high-rate and ultralong-lifespan Na3V2(PO4)3 @C cathode by enhancing the conductivity both in bulk and on surface. ACS Appl. Mater. Interfaces 10(42), 35963 (2018)10.1021/acsami.8b12055 ↗
78. X. Liu, G. Feng, E. Wang, H. Chen, Z. Wu, W. Xiang, Y. Zhong, Y. Chen, X. Guo, B. Zhong, Insight into preparation of Fe-doped Na3V2(PO4)3 @C from aspects of particle morphology design, crystal structure modulation, and carbon graphitization regulation. ACS Appl. Mater. Interfaces 11(13), 12421 (2019)10.1021/acsami.8b21257 ↗
79. K. Kawai, W. Zhao, S.I. Nishimura, A. Yamada, High-voltage Cr4+/Cr3+ redox couple in polyanion compounds. ACS Appl. Energy Mater. 1(3), 928 (2018)10.1021/acsaem.7b00105 ↗
80. S. Park, J.N. Chotard, D. Carlier, I. Moog, M. Courty, M. Duttine, F. Fauth, A. Iadecola, L. Croguennec, C. Masquelier, Crystal structures and local environments of NASICON-type Na3V2(PO4)3 and Na4V2(PO4)3 positive electrode materials for Na-Ion batteries. Chem. Mater. 33(13), 5355 (2021)10.1021/acs.chemmater.1c01457 ↗
81. Y. Zhao, X. Gao, H. Gao, H. Jin, J.B. Goodenough, Three electron reversible redox reaction in sodium vanadium chromium phosphate as a high-energy-density cathode for sodium-ion batteries. Adv. Funct. Mater. 30(10), 1908680 (2020)10.1002/adfm.201908680 ↗
82. C. Delmas, F. Cherkaoui, A. Nadiri, P. Hagenmuller, A nasicon-type phase as intercalation electrode: NaTi2(PO4)3. Mater. Res. Bull. 22(5), 631 (1987)10.1016/0025-5408(87)90112-7 ↗
83. P. Senguttuvan, G. Rousse, M.E. Arroyo, Y. De Dompablo, H. Vezin, J.M. Tarascon, M.R. Palacín, Low-potential sodium insertion in a NASICON-type structure through the Ti(III)/Ti(II) redox couple. J. Am. Chem. Soc. 135(10), 3897 (2013)10.1021/ja311044t ↗
84. R. Rajagopalan, B. Chen, Z. Zhang, X.L. Wu, Y. Du, Y. Huang, B. Li, Y. Zong, J. Wang, G.H. Nam, M. Sindoro, S.X. Dou, H.K. Liu, H. Zhang, Improved reversibility of Fe3+/Fe4+ redox couple in sodium super ion conductor type Na3Fe2(PO4)3 for sodium-ion batteries. Adv. Mater. 29(12), 1605694 (2017)10.1002/adma.201605694 ↗
85. J. Gopalakrishnan, K.K. Rangan, Vanadium phosphate (V2(PO4)3): A novel NASICON-type vanadium phosphate synthesized by oxidative deintercalation of sodium from sodium vanadium phosphate (Na3V2(PO4)3). Chem. Mater. 4(4), 745 (1992)10.1021/cm00022a001 ↗
86. S. Il Park, I. Gocheva, S. Okada, J. Yamaki, Electrochemical properties of NaTi2(PO4)3 anode for rechargeable aqueous sodium-ion batteries. J. Electrochem. Soc. 158(10), A1067 (2011)10.1149/1.3611434 ↗
87. S.C. Chung, J. Ming, L. Lander, J. Lu, A. Yamada, Rhombohedral NASICON-type NaxFe2(SO4)3 for sodium ion batteries: Comparison with phosphate and alluaudite phases. J. Mater. Chem. A 6(9), 3919 (2018)10.1039/C7TA08606G ↗
88. X. Ma, X. Cao, Y. Zhou, S. Guo, X. Shi, G. Fang, A. Pan, B. Lu, J. Zhou, S. Liang, Tuning crystal structure and redox potential of NASICON-type cathodes for sodium-ion batteries. Nano Res. 13(12), 3330 (2020)10.1007/s12274-020-3011-6 ↗
89. W. Zhou, L. Xue, X. Lü, H. Gao, Y. Li, S. Xin, G. Fu, Z. Cui, Y. Zhu, J.B. Goodenough, NaxMV(PO4)3 (M = Mn, Fe, Ni) structure and properties for sodium extraction. Nano Lett. 16(12), 7836 (2016)10.1021/acs.nanolett.6b04044 ↗
90. R. Chen, D.S. Butenko, S. Li, D. Li, X. Zhang, J. Cao, I.V. Ogorodnyk, N.I. Klyui, W. Han, I.V. Zatovsky, Effects of low doping on the improvement of cathode materials Na3+xV2-xMx(PO4)3 (M = Co2+, Cu2+; x = 0.01–0.05) for SIBs. J. Mater. Chem. A 9(32), 17380 (2021)10.1039/D1TA05000A ↗
91. S. Ghosh, N. Barman, E. Gonzalez-Correa, M. Mazumder, A. Zaveri, R. Giovine, A. Manche, S.K. Pati, R.J. Clément, P. Senguttuvan, Elucidating the impact of Mg substitution on the properties of NASICON-Na3+yV2−yMgy(PO4)3 cathodes. Adv. Funct. Mater. 31(48), 2105463 (2021)10.1002/adfm.202105463 ↗
92. F. Lalère, V. Seznec, M. Courty, J.N. Chotard, C. Masquelier, Coupled X-ray diffraction and electrochemical studies of the mixed Ti/V-containing NASICON: Na2TiV(PO4)3. J. Mater. Chem. A 6(15), 6654 (2018)10.1039/C7TA10689K ↗
93. J. Zhang, Y. Liu, X. Zhao, L. He, H. Liu, Y. Song, S. Sun, Q. Li, X. Xing, J. Chen, A novel NASICON-type Na4MnCr(PO4)3 demonstrating the energy density record of phosphate cathodes for sodium-ion batteries. Adv. Mater. 32(11), 1906348 (2020)10.1002/adma.201906348 ↗
94. T. Zhu, P. Hu, X. Wang, Z. Liu, W. Luo, K.A. Owusu, W. Cao, C. Shi, J. Li, L. Zhou, L. Mai, Realizing three-electron redox reactions in NASICON-structured Na4MnTi(PO4)3 for sodium-ion batteries. Adv. Energy Mater. 9(9), 1803436 (2019)10.1002/aenm.201803436 ↗
95. J. Zhang, C. Lin, Q. Xia, C. Wang, X.S. Zhao, Improved performance of Na3TiMn(PO4)3 using a non-stoichiometric synthesis strategy. ACS Energy Lett. 6(6), 2081 (2021)10.1021/acsenergylett.1c00426 ↗
96. Z. Zhang, S. Wenzel, Y. Zhu, J. Sann, L. Shen, J. Yang, X. Yao, Y.-S. Hu, C. Wolverton, H. Li, L. Chen, J. Janek, Na3Zr2Si2PO12: A stable Na+-ion solid electrolyte for solid-state batteries. ACS Appl. Energy Mater. 3(8), 7427 (2020)10.1021/acsaem.0c00820 ↗
97. Z. Deng, G. Sai Gautam, S.K. Kolli, J.N. Chotard, A.K. Cheetham, C. Masquelier, P. Canepa, Phase behavior in rhombohedral NaSiCON electrolytes and electrodes. Chem. Mater. 32(18), 7908 (2020)10.1021/acs.chemmater.0c02695 ↗
98. L.X. Yuan, Z.H. Wang, W.X. Zhang, X.L. Hu, J.T. Chen, Y.H. Huang, J.B. Goodenough, Development and challenges of LiFePO4 cathode material for lithium-ion batteries. Energy Environ. Sci. 4(2), 269 (2011)10.1039/C0EE00029A ↗
99. C. Heubner, S. Heiden, M. Schneider, A. Michaelis, In-situ preparation and electrochemical characterization of submicron sized NaFePO4 cathode material for sodium-ion batteries. Electrochim. Acta 233, 78 (2017)10.1016/j.electacta.2017.02.107 ↗
100. T. Boyadzhieva, V. Koleva, E. Zhecheva, D. Nihtianova, L. Mihaylov, R. Stoyanova, Competitive lithium and sodium intercalation into sodium manganese phospho-olivine NaMnPO4 covered with carbon black. RSC Adv. 5(106), 87694 (2015)10.1039/C5RA17299C ↗