journal article·2017-02-28

Rheological properties of HDPE/chitosan composites modified with PE-g-MA

Poliana S. Lima, Rebecca S.F. Brito, Bárbara F.F. Santos, Albaniza A. Tavares, Pankaj Agrawal, Daniela L.A.C.S. Andrade, Renate M.R. Wellen, Eduardo L. Canedo, Suédina M.L. Silva

Journal of Materials Research· Volume 32· Issue 4
Publisher page

Abstract

The rheological behavior of composites made with high-density polyethylene (HDPE) and chitosan was studied. Composites were prepared by melt processing in a laboratory internal mixer. Maleic anhydride grafted HDPE (PE-g-MA) was used as compatibilizer to enhance the dispersion of chitosan in the HDPE matrix. Different percentages of chitosan and compatibilizer (up to a maximum of 25 phr) were added into HDPE to prepare composites. Characterization of the composites with parallel plate rheometer and laboratory internal mixer revealed that the presence of chitosan increases the complex viscosity, loss modulus, storage modulus and the torque (i.e., melt viscosity), and the combination chitosan/compatibilizer has a similar, if slighter, effect. At higher filler levels it is clear that the PE-g-MA affected the microstructure of the compounds, possibly increasing matrix–filler interactions and acting as an effective compatibilizer.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nanocomposite Films for Food Packaging · biodegradable polymer synthesis and properties · Polymer Nanocomposites and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (76)

Show source-provided references
1. Correlation of dynamic and steady-flow viscosities
2. 10.1021/ma00104a01410.1021/ma00104a014 ↗
3. Effectiveness of chitosan as antimicrobial agent in LDPE/CS composite films as minced poultry meat packaging materials
4. 10.1021/bm034130m10.1021/bm034130m ↗
5. 10.1016/j.cej.2012.07.05810.1016/j.cej.2012.07.058 ↗
6. Walsh · 1995
7. Bird · 1987
8. 10.1016/j.compositesb.2013.06.00810.1016/j.compositesb.2013.06.008 ↗
9. Vasile · 2005
10. 10.1016/j.polymdegradstab.2016.05.01610.1016/j.polymdegradstab.2016.05.016 ↗
11. 10.1016/j.meatsci.2010.02.02210.1016/j.meatsci.2010.02.022 ↗
12. 56. Addivant: Polybond 3009 Technical Information [www.addivant.com] (Danbury, 2013).
13. 10.1016/j.carbpol.2010.07.06910.1016/j.carbpol.2010.07.069 ↗
14. 10.1007/s00397-008-0329-510.1007/s00397-008-0329-5 ↗
15. 10.3139/978344641281110.3139/9783446412811 ↗
16. 10.1016/0141-8130(95)01066-110.1016/0141-8130(95)01066-1 ↗
17. Wetzel · 2009 · 479
18. 10.1002/pts.214610.1002/pts.2146 ↗
19. 10.1016/j.polymertesting.2015.11.02010.1016/j.polymertesting.2015.11.020 ↗
20. 10.1016/j.carbpol.2013.10.05210.1016/j.carbpol.2013.10.052 ↗
21. 10.1016/j.polymertesting.2016.01.00210.1016/j.polymertesting.2016.01.002 ↗
22. 10.1080/1060132950801027610.1080/10601329508010276 ↗
23. 10.1002/app.3029910.1002/app.30299 ↗
24. 10.1016/j.ijbiomac.2015.06.01610.1016/j.ijbiomac.2015.06.016 ↗
25. 10.1016/0095-8522(65)90022-X10.1016/0095-8522(65)90022-X ↗
26. 10.1016/j.msea.2005.04.05510.1016/j.msea.2005.04.055 ↗
27. 10.1126/science.297.5582.80310.1126/science.297.5582.803 ↗
28. Application of chitosan-based polysaccharide biomaterials in cartilage tissue engineering: A review10.1016/S0142-9612(00)00126-5 ↗
29. 10.1002/pc.2045510.1002/pc.20455 ↗
30. Kinetic study of biodegradation of linear low density polyethylene/chitosan
31. 10.1016/j.ibiod.2007.07.01110.1016/j.ibiod.2007.07.011 ↗
32. 10.1016/j.foodchem.2008.11.04710.1016/j.foodchem.2008.11.047 ↗
33. 10.1007/s00397-011-0612-810.1007/s00397-011-0612-8 ↗
34. 10.1134/S107042720609026610.1134/S1070427206090266 ↗
35. 10.1080/03602559.2012.73436210.1080/03602559.2012.734362 ↗
36. Scott · 199910.1039/9781847551726 ↗
37. Carreau · 1997
38. 10.1016/S0141-3910(03)00129-010.1016/S0141-3910(03)00129-0 ↗
39. 10.1002/978047090046810.1002/9780470900468 ↗
40. 10.1016/j.polymertesting.2015.01.00710.1016/j.polymertesting.2015.01.007 ↗
41. 10.1016/j.progpolymsci.2009.04.00110.1016/j.progpolymsci.2009.04.001 ↗
42. Swift · 2004
43. 10.1080/03602559.2011.61815610.1080/03602559.2011.618156 ↗
44. 10.1002/vnl.2026810.1002/vnl.20268 ↗
45. Tolinski · 2015
46. 10.1016/j.polymertesting.2011.07.00310.1016/j.polymertesting.2011.07.003 ↗
47. 10.1007/978-94-015-9213-010.1007/978-94-015-9213-0 ↗
48. 10.4236/ojpchem.2014.4100210.4236/ojpchem.2014.41002 ↗
49. Santos · 2008
50. 10.1016/j.compositesa.2012.10.01410.1016/j.compositesa.2012.10.014 ↗
51. 10.1122/1.54985510.1122/1.549855 ↗
52. 10.1002/app.4104510.1002/app.41045 ↗
53. 51. Braskem: High Density Polyethylene JV-060U Technical Data Sheet, Revision 8 (São Paulo, 2015).
54. Peacock · 200010.1201/9781482295467 ↗
55. 10.1016/S0260-8774(02)00345-X10.1016/S0260-8774(02)00345-X ↗
56. Barnes · 1989
57. Biodegradation of plastic compost bags under controlled soil conditions
58. 10.1016/j.polymer.2004.11.01310.1016/j.polymer.2004.11.013 ↗
59. 10.1122/1.54884810.1122/1.548848 ↗
60. 10.1016/j.jconrel.2004.08.01010.1016/j.jconrel.2004.08.010 ↗
61. 10.1134/S0965545X0905010110.1134/S0965545X09050101 ↗
62. 10.3139/978156990521010.3139/9781569905210 ↗
63. 10.1016/S0141-3910(01)00054-410.1016/S0141-3910(01)00054-4 ↗
64. 10.1177/073168441039150710.1177/0731684410391507 ↗
65. 10.1122/1.157402010.1122/1.1574020 ↗
66. 10.1002/app.3347710.1002/app.33477 ↗
67. 10.3139/9783446433717.02810.3139/9783446433717.028 ↗
68. 10.1016/j.carbpol.2012.08.07610.1016/j.carbpol.2012.08.076 ↗
69. Lima · 2014
70. 10.1038/pj.2014.1910.1038/pj.2014.19 ↗
71. 10.1016/j.polymdegradstab.2010.12.00410.1016/j.polymdegradstab.2010.12.004 ↗
72. Functional characterization of chitin and chitosan
73. 10.1016/j.tifs.2006.10.02210.1016/j.tifs.2006.10.022 ↗
74. 10.1016/j.enzmictec.2003.12.01310.1016/j.enzmictec.2003.12.013 ↗
75. 10.1002/(SICI)1099-1581(199706)8:6<355::AID-PAT651>3.0.CO;2-T10.1002/(SICI)1099-1581(199706)8:6<355::AID-PAT651>3.0.CO;2-T ↗
76. 10.1080/00914037.2010.53181210.1080/00914037.2010.531812 ↗