Effect of Co2+ and Mn3+/Mn4+ ratio on high-performance supercapattery
Source abstract
Abstract
The growing demand for advanced energy storage highlights supercapacitors for their high power density and long cycle life. Supercapatteries are hybrid supercapacitors (HSCs) that combine carbon materials as anode and metal oxides as cathode with a battery-type behavior. Here, electrode materials of Co-doped MnOxnanorods were prepared via incipient wet impregnation. The synthesis induced morphological modifications in the material and the creation of oxygen vacancies was suggested by their Mn3+/Mn4+ratio. The 4.79 wt.% Co/MnOxelectrode delivered a high specific capacitance of 1478.52 F g−1at 1 A g−1and enhanced stability after 1000 cycles for a symmetric device. Then, the supercapattery reached 452.19 F g−1at 1 A g−1, energy density of 579 Wh kg−1, power density of 2881 W kg−1, and good stability up to 1500 cycles. This study sheds light on the easy and low-cost production of a Co-doped MnOxelectrode material for enhanced energy storage.Graphical abstract
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: ZnO doping and properties · Inorganic Fluorides and Related Compounds · Aerogels and thermal insulation
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (63)
Show source-provided references
1. P.E. Lokhande, C. Jagtap, V. Kadam, R. Udayabhaskar, S.F. Shaikh, Microwave-assisted synthesis of gadolinium/cerium oxide nanocomposite for high-performance supercapacitor. J. Mater. Sci. Mater. Electron. 35, 615 (2024)10.1007/s10854-024-12354-5 ↗
2. H.J.T. Rabecca, M.D. Meenakshi, S. Manivannan, A.J.C. Lourduraj, Electrochemical evaluation of rGO and MnCo2S4 nanoparticle for pseudocapacitor electrodes. J. Appl. Electrochem. (2024). https://doi.org/10.1007/s10800-024-02139-310.1007/s10800-024-02139-3 ↗
3. M. Szkoda, M. Skorupska, J.P. Łukaszewicz, A. Ilnicka, Enhanced supercapacitor materials from pyrolyzed algae and graphene composites. Sci. Rep. 13, 21238 (2023)10.1038/s41598-023-48166-6 ↗
4. F.J.S. Barros, K.L.P. Cardozo, G.H. Cruvinel, E. Longo, M.A.S. Garcia, A.A. Tanaka et al., Microwave-assisted hydrothermal synthesis of CeVO4 nanostructures: Exploring their applicability in supercapacitor technologies. J. Mater. Sci. 59, 4236–4251 (2024)10.1007/s10853-024-09487-7 ↗
5. F.J.S. Barros, K.L.P. Cardoso, E. Longo, A.A. Tanaka, M.A.S. Garcia, I.M. Pinatti, Facile microwave-assisted hydrothermal synthesis of GdVO4 nanospheres: Unlocking their potential as electrodes for supercapacitors. J. Mater. Sci. 58, 15459–15470 (2023)10.1007/s10853-023-08984-5 ↗
6. S.P. Lishavi, T.A. Mohamed Ali, Synthesis and characterization of graphite enriched Fe–Co–Ni nanocomposite for supercapacitor applications. J. Appl. Electrochem. 54, 1309–1319 (2024)10.1007/s10800-023-02043-2 ↗
7. J.M. Gonçalves, P.R. Martins, K. Araki, L. Angnes, Recent progress in water splitting and hybrid supercapacitors based on nickel-vanadium layered double hydroxides. J. Energy Chem. 57, 496–515 (2021)10.1016/j.jechem.2020.08.047 ↗
8. P. Thondaiman, C. Justin, R. Velayutham, A. Dennyson, R. Manikandan, V. Cristobal et al., Engineering redox active sites enriched 3D-on-2D bimetallic double layered hydroxide electrode for supercapatteries. Mater Today Energy (2022). https://doi.org/10.1016/j.mtener.2022.10118210.1016/j.mtener.2022.101182 ↗
9. M. Young Jung, H. Cho, C. Lee, Y. Ju, S. Kannan, Y. Jun, Synergetic effect of a battery-like nickel phosphide and a pseudocapacitive cobalt phosphide electrodes for enhanced energy storage. J Energy Storage. 66, 107321 (2023)10.1016/j.est.2023.107321 ↗
10. J.D. Santos, J.P. Mendonça, V.N.S. Campos, M.M. Teixeira, A.J. Schwanke, K. Bernardo-Gusmão et al., Exploring the potential of a ZIF-8@MCM-41-based heterostructured material for battery-type electrodes for supercapatteries. New J. Chem. (2024). https://doi.org/10.1039/D4NJ02596B10.1039/D4NJ02596B ↗
11. J.P. Mendonça, S.L. Lima, P.N. Romano, J.M.A.R. de Almeida, S.F. Santos, L. Liu et al., Unveiling the Mn3+/ Mn4+ and Ni2+ potential as a high-capacity material for next-generation energy storage devices. Catal. Today 445, 115046 (2025)10.1016/j.cattod.2024.115046 ↗
12. F.J.S. Barros, J. Rozendo, D.S. da Costa, M.C. Portes, E.A. de Mattos, L. Liu et al., Exploring morphological variations in Ce-doped MnO2-based nanomaterials: Rethinking the need for morphological control in achieving enhanced electrochemical storage. J. Mater. Sci. Mater. Electron. 2024, 35 (2024). https://doi.org/10.1007/s10854-024-12448-010.1007/s10854-024-12448-0 ↗
13. S. Mandal, J. Hu, S.Q. Shi, A comprehensive review of hybrid supercapacitor from transition metal and industrial crop based activated carbon for energy storage applications. Mater Today Commun. 34, 105207 (2023)10.1016/j.mtcomm.2022.105207 ↗
14. S.M. Jadhav, R.S. Kalubarme, N. Suzuki, C. Terashima, J. Mun, B.B. Kale et al., Cobalt-doped manganese dioxide hierarchical nanostructures for enhancing pseudocapacitive properties. ACS Omega 6, 5717–5729 (2021)10.1021/acsomega.0c06150 ↗
15. B.R. Wiston, M. Ashok, Microwave-assisted synthesis of cobalt-manganese oxide for supercapacitor electrodes. Mater. Sci. Semicond. Process. 103, 104607 (2019). https://doi.org/10.1016/j.mssp.2019.10460710.1016/j.mssp.2019.104607 ↗
16. Y.-M. Hong, J.-P. Chen, T.-J. Whang, Enhanced pseudocapacitive properties of cobalt-doped manganese oxide electrode utilizing magnesium sulfate electrolyte for supercapacitors. Ceram. Int. 50, 33809–33816 (2024)10.1016/j.ceramint.2024.06.199 ↗
17. M. Prajapati, C. Ravi Kant, M.V. Jacob, Binder free cobalt manganese layered double hydroxide anode conjugated with bioderived rGO cathode for sustainable, high-performance asymmetric supercapacitors. J. Electroanal. Chem. 961, 118242 (2024). https://doi.org/10.1016/j.jelechem.2024.11824210.1016/j.jelechem.2024.118242 ↗
18. N.S. Mankge, D.Y. Momodu, N.W. Hlongwa, K. Makgopa, A.T. Kuvarega, M.J. Madito, Hybrid cobalt-nickel oxalate/electrochemically exfoliated doped graphene composite for supercapacitor applications. Synth. Met. 307, 117652 (2024). https://doi.org/10.1016/j.synthmet.2024.11765210.1016/j.synthmet.2024.117652 ↗
19. T. Zhao, S. Boullosa-Eiras, Y. Yu, D. Chen, A. Holmen, M. Ronning, Synthesis of supported catalysts by impregnation and calcination of low-temperature polymerizable metal-complexes. Top. Catal. 54, 1163–1174 (2011)10.1007/s11244-011-9738-2 ↗
20. X. Li, L. Chen, Y. Osaka, Z. He, L. Deng, H. Huang, Preparation and desulfurization performance of various MnOx materials for ship exhaust emissions control. Sep. Purif. Technol. 253, 117182 (2020)10.1016/j.seppur.2020.117182 ↗
21. R. Balzer, L.F.D. Probst, V. Drago, W.H. Schreiner, H.V. Fajardo, Catalytic oxidation of volatile organic compounds (n-hexane, benzene, toluene, o-xylene) promoted by cobalt catalysts supported on γ-Al2O3-CeO2. Brazilian J. Chem. Eng. 31, 757–769 (2014)10.1590/0104-6632.20140313s00002802 ↗
22. A. Kiecana, I. Batashev, A.I. Dugulan, C. Kwakernaak, L. Pieter, F. Zhang et al., Effect of Co and Ni doping on the structure, magnetic and magnetocaloric properties of Fe-rich (Mn, Fe)2(P, Si) compounds. J. Magn. Magn. Mater. 561, 169710 (2022). https://doi.org/10.1016/j.jmmm.2022.16971010.1016/j.jmmm.2022.169710 ↗
23. J. Han, D. Li, L. Jiang, D. Fang, Co-MnO2 nanorods for high-performance sodium/potassium-ion batteries and highly conductive gel-type supercapacitors. Adv. Sci. (2022). https://doi.org/10.1002/advs.20210551010.1002/advs.202105510 ↗
24. M.A. Ehsan, A.S. Hakeem, A. Rehman, Hierarchical growth of CoO nanoflower thin films influencing the electrocatalytic oxygen evolution reaction. Electrocatalysis 11, 282–291 (2020)10.1007/s12678-020-00585-z ↗
25. N.H.M. Dostagir, R. Rattanawan, M. Gao, J. Ota, J. Hasegawa, K. Asakura et al., Co single atoms in ZrO2 with inherent oxygen vacancies for selective hydrogenation of CO2 to CO. ACS Catal. 11, 9450–9461 (2021)10.1021/acscatal.1c02041 ↗
26. J. Li, D. Xiong, L. Wang, M.K.S. Hirbod, X. Li, High-performance self-assembly MnCo2O4 nanosheets for asymmetric supercapacitors. J. Energy Chem. 37, 66–72 (2019)10.1016/j.jechem.2018.11.015 ↗
27. Y. Feng, W. Liu, Y. Wang, W. Gao, J. Li, K. Liu et al., Oxygen vacancies enhance supercapacitive performance of CuCo2O4 in high-energy-density asymmetric supercapacitors. J. Power. Sources 458, 228005 (2020)10.1016/j.jpowsour.2020.228005 ↗
28. K. Xu, M. Wang, Y. Zhang, W. Shan, H. He, Promotion effects of barium and cobalt on manganese oxide catalysts for soot oxidation. Ind. Eng. Chem. Res. 60, 11412–11420 (2021)10.1021/acs.iecr.1c01524 ↗
29. L. Chen, J. Ding, J. Jia, R. Ran, C. Zhang, X. Song, Cobalt-doped MnO2 nanofibers for enhanced propane oxidation. ACS Appl. Nano Mater. 2, 4417–4426 (2019)10.1021/acsanm.9b00818 ↗
30. Y. Fu, H. He, X. Li, L. Wu, R. Yan, J. Zhang et al., Enhance supercapacitive performance of Ni foam electrode and MnCo2O4.5/Ni foam electrode. J. Mater. Sci. Mater. Electron. 28, 1562–1571 (2017)10.1007/s10854-016-5696-6 ↗
31. J. Liu, J. Bao, X. Zhang, Y. Gao, Y. Zhang, L. Liu et al., MnO2-based materials for supercapacitor electrodes: Challenges, strategies and prospects. RSC Adv. 12, 35556–35578 (2022)10.1039/D2RA06664E ↗
32. F. Marken, A. Neudeck, A.M. Bond, Cyclic Voltammetry Electroanal Methods (Springer, Berlin, 2010), pp.57–106
33. R. Zhao, L. Zhang, C. Wang, L. Yin, Tetramethyl ammonium cation intercalated layered birnessite manganese dioxide for high-performance intercalation pseudocapacitor. J. Power. Sour. 353, 77–84 (2017)10.1016/j.jpowsour.2017.03.138 ↗
34. S. da Silva Eduardo, P.B.S. de Figueiredo, S.L.S. de Lima, K.E.R. Santos, G.A.C. Ribeiro, W.S. Fonseca et al., Investigating the influence of varying cobalt doping on the cross-sectional widths and surface composition of MnOx nanowires in the context of battery–supercapacitor systems. J. Appl. Electrochem. 54, 1983–1998 (2024)10.1007/s10800-024-02090-3 ↗
35. M. Alzaid, M.Z. Iqbal, S. Siddique, N.M.A. Hadia, Exploring the electrochemical performance of copper-doped cobalt–manganese phosphates for potential supercapattery applications. RSC Adv. 11, 28042–28051 (2021)10.1039/D0RA09952J ↗
36. A. Liu, H. Zhang, C. Xing, Y. Wang, J. Zhang, X. Zhang et al., Intensified energy storage in high-voltage nanohybrid supercapacitors via the efficient coupling between TiNb2O7/Holey-rGO nanoarchitectures and ionic liquid-based electrolytes. ACS Appl. Mater. Interfaces 13, 21349–21361 (2021)10.1021/acsami.1c03266 ↗
37. H. Li, D. Chen, S. Li, C. Kang, Q. Liu, Synthesis of mesoporous cobalt-doped manganese oxides for high-performance supercapacitors. Ionics 27, 2181–2192 (2021)10.1007/s11581-021-03957-7 ↗
38. A.K. Singh, D. Sarkar, K. Karmakar, K. Mandal, G.G. Khan, High-performance supercapacitor electrode based on cobalt oxide-manganese dioxide–nickel oxide ternary 1D hybrid nanotubes. ACS Appl. Mater. Interfaces 8, 20786–20792 (2016)10.1021/acsami.6b05933 ↗
39. Z. Song, W. Liu, Q. Zhou, L. Zhang, Z. Zhang, H. Liu et al., Cobalt hexacyanoferrate/MnO2 nanocomposite for asymmetrical supercapacitors with enhanced electrochemical performance and its charge storage mechanism. J. Power. Sour. 465, 228266 (2020)10.1016/j.jpowsour.2020.228266 ↗
40. S. Wang, J. Zhang, O. Gharbi, V. Vivier, M. Gao, M.E. Orazem, Electrochemical impedance spectroscopy. Nat Rev Methods Prim. 1, 41 (2021)10.1038/s43586-021-00039-w ↗
41. S.B. Aziz, M.M. Nofal, R.T. Abdulwahid, O.H. Ghareeb, E.M.A. Dannoun, M.R. Abdullah et al., Plasticized sodium-ion conducting PVA based polymer electrolyte for electrochemical energy storage—EEC modeling, transport properties, and charge–discharge characteristics. Polymers (Basel). 13, 803 (2021)10.3390/polym13050803 ↗
42. R.U. Amate, P.J. Morankar, A.M. Teli, G.T. Chavan, S.A. Beknalkar, N.A. Ahir et al., Exploring the electrochemical performance of niobium phosphate electrode for supercapacitor application. Surf. Interfaces. 41, 103265 (2023)10.1016/j.surfin.2023.103265 ↗
43. W. Kang, Y. Tang, W. Li, Z. Li, X. Yang, J. Xu et al., Porous CuCo2O4 nanocubes wrapped by reduced graphene oxide as high-performance lithium-ion battery anodes. Nanoscale 6, 6551–6556 (2014)10.1039/C4NR00446A ↗
44. E.L. Anderson, P. Bühlmann, Electrochemical Impedance spectroscopy of ion-selective membranes: Artifacts in two-, three-, and four-electrode measurements. Anal. Chem. 88, 9738–9745 (2016)10.1021/acs.analchem.6b02641 ↗
45. S. Khaja Hussain, Yu.J. Su, Cobalt-doped zinc manganese oxide porous nanocubes with controlled morphology as positive electrode for hybrid supercapacitors. Chem. Eng. J. 361, 1030–1042 (2019)10.1016/j.cej.2018.12.152 ↗
46. M. Haripriya, A.M. Ashok, S. Hussain, R. Sivasubramanian, Nanostructured MnCo2O4 as a high-performance electrode for supercapacitor application. Ionics 27, 325–337 (2021). https://doi.org/10.1007/s11581-020-03788-y10.1007/s11581-020-03788-y ↗
47. A. Nayak, B. Bhushan, S. Kotnala, N. Kukretee, P. Chaudhary, A.R. Tripathy et al., Nanomaterials for supercapacitors as energy storage application: Focus on its characteristics and limitations. Mater. Today Proc. 73, 227–232 (2023)10.1016/j.matpr.2022.11.259 ↗
48. X. Tang, S. Xia, Q. Luo, J. Liu, X. Yang, X. Luo et al., High-performance aqueous asymmetric supercapacitors based on K+ and Na+ co-preinserted δ-MnO2 nanocrystals. J. Mater. Res. 38, 2998–3008 (2023)10.1557/s43578-023-01018-5 ↗
49. Z. Qiao, X. Yang, S. Yang, L. Zhang, B. Cao, 3D hierarchical MnO2 nanorod/welded Ag-nanowire-network composites for high-performance supercapacitor electrodes. Chem. Commun. 52, 7998–8001 (2016)10.1039/C6CC03768B ↗
50. T.W. van Deelen, J.J. Nijhuis, N.A. Krans, J. Zečević, K.P. de Jong, Preparation of cobalt nanocrystals supported on metal oxides to study particle growth in Fischer-Tropsch catalysts. ACS Catal. 8, 10581–10589 (2018)10.1021/acscatal.8b03094 ↗
51. B.R. Wiston, M. Ashok, Microwave-assisted synthesis of cobalt-manganese oxide for supercapacitor electrodes. Mater. Sci. Semicond. Process. 103, 104607 (2019)10.1016/j.mssp.2019.104607 ↗
52. H.A. Ghaly, A.G. El-Deen, E.R. Souaya, N.K. Allam, Asymmetric supercapacitors based on 3D graphene-wrapped V2O5 nanospheres and Fe3O4@3D graphene electrodes with high power and energy densities. Electrochim. Acta 310, 58–69 (2019)10.1016/j.electacta.2019.04.071 ↗
53. S. Ramesh, K. Karuppasamy, H.-S. Kim, H.S. Kim, J.-H. Kim, Hierarchical flowerlike 3D nanostructure of Co3O4@MnO2/N-doped graphene oxide (NGO) hybrid composite for a high-performance supercapacitor. Sci. Rep. 8, 16543 (2018)10.1038/s41598-018-34905-7 ↗
54. K. Khan, M. Zia Ullah Shah, U. Aziz, K. Hayat, M. Sajjad, I. Ahmad et al., Development of 1.6 V hybrid supercapacitor based on ZnO nanorods/MnO2 nanowires for next-generation electrochemical energy storage. J. Electroanal. Chem. 922, 116753 (2022)10.1016/j.jelechem.2022.116753 ↗
55. G.A.C. Ribeiro, S.L.S. de Lima, K.E.R. Santos, J.P. Mendonça, P. Macena, E.C. Pessanha et al., Zn-doped MnOx nanowires displaying plentiful crystalline defects and tunable small cross-sections for an optimized volcano-type performance towards supercapacitors. Discov Nano. 18, 147 (2023)10.1186/s11671-023-03933-2 ↗
56. R. Manikandan, C.J. Raj, A.D. Savariraj, P. Thondaiman, W.-J. Cho, H.-M. Jang et al., Template assisted synthesis of porous termite nest-like manganese cobalt phosphide as binder-free electrode for supercapacitors. Electrochim. Acta 393, 139060 (2021)10.1016/j.electacta.2021.139060 ↗
57. E. Sohouli, K. Adib, B. Maddah, M. Najafi, Manganese dioxide/cobalt tungstate/ nitrogen-doped carbon nano-onions nanocomposite as new supercapacitor electrode. Ceram. Int. 48, 295–303 (2022)10.1016/j.ceramint.2021.09.104 ↗
58. Z. Liu, F. Teng, C. Yuan, Z. Ul Abideen, W. Gu, Z. Liu, Highly uniform MnCo2O4 hollow spheres-based all-solid-state asymmetric micro-supercapacitor via a simple metal-glycerate precursor approach. Energy Technol. 7, 1900314 (2019)10.1002/ente.201900314 ↗
59. B. Saravanakumar, X. Wang, W. Zhang, L. Xing, W. Li, Holey two dimensional manganese cobalt oxide nanosheets as a high-performance electrode for supercapattery. Chem. Eng. J. 373, 547–555 (2019)10.1016/j.cej.2019.05.080 ↗
60. C.-H. Yang, Y.-C. Chen, C.-F. Wu, R.-J. Chung, S. Yougbaré, L.-Y. Lin, Novel synthesis of ZIF67-derived MnCo2O4 nanotubes using electrospinning and hydrothermal techniques for supercapacitor. J. Solid State Chem. 313, 123351 (2022)10.1016/j.jssc.2022.123351 ↗
61. A. Khan, F. Shaheen, M. Roman, R. Ahmad, K. Mehboob, M. Hammad, Highly redox active mesoporous Ni/Co-organic framework as a potential battery type electrode material for high energy density supercapattery. J. Energy Storage. 58, 106317 (2023). https://doi.org/10.1016/j.est.2022.10631710.1016/j.est.2022.106317 ↗
62. S. Kasap, Nanoscale advances graphene foam and zinc oxide ( ZnO ) electrodes induced by structural defects. Nanoscale Adv. 1, 2586–2597 (2019). https://doi.org/10.1039/C9NA00199A10.1039/C9NA00199A ↗
63. J. Iqbal, A. Numan, M.O. Ansari, R. Jafer, R. Jagadish, S. Bashir, P. Hasan, A. Bilgrami, S. Mohamad, K. Ramesh, S. Ramesh, Cobalt oxide nanograins and silver nanoparticles decorated fibrous polyaniline nanocomposite as battery-type electrode for high perfomance supercapattery. Polymers 12, 1296 (2020)10.3390/polym12122816 ↗