Cu–V bimetallic selenide with synergistic effect for high-rate and long-life sodium storage
Source abstract
Abstract
Sodium-ion batteries (SIBs) are considered as potential substitute in large-scale energy storage systems due to the abundant natural resources and low price of sodium, and environmental friendliness. However, commercial graphite anode in lithium-ion batteries cannot be directly applied to SIBs. Bimetallic selenides stand out among the many anode materials owing to their rich redox chemistry and superior conductivities. Here, a bimetallic selenide Cu3VSe4is successfully prepared via one-pot reaction in oil phase, and its energy storage performance for SIBs is investigated. It delivers an impressive capacity, excellent rate performance (298 mAh g−1at 10 A g−1), and outstanding long-term cycling life (305 mAh g−1over 1000 cycles at 2.0 A g−1). In addition, the Na+storage mechanism (including intercalation and conversion reactions) is revealed. This work provides a new way for the application of the Cu3VSe4in SIBs.Graphical abstractA bimetallic selenide Cu3VSe4is successfully prepared via one-pot reaction in oil phase. When it is evaluated as the anode for sodium-ion batteries, the Cu3VSe4displays an impressive capacity, excellent rate performance, and outstanding long-term cycling life. In addition, the Na+storage mechanism (including intercalation and conversion reactions) is revealed.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (41)
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