Hybrid nanostructured PAN@NiCu(CO3)(OH)2 composite for flexible high-performance supercapacitors
Source abstract
Abstract
Abstract A binder-free porous NiCu(CO3)(OH)2 composite was grown on a polyacrylonitrile (PAN) nanofiber substrate using a hydrothermal method. PAN nanofibers were fabricated by the electrospinning method, thus producing a substrate with a nano-sized diameter and high specific surface area. The composite NiCu(CO3)(OH)2 nanowires on PAN nanofibers provided the large specific surface area required for the redox reaction. Transition metal-based nanowires and nano-sized PAN substrates indicate a synergistic effect in electrochemical performance. The NiCu(CO3)(OH)2 on PAN composite showed a remarkable maximum specific capacity of 870 mAh g−1 at a current density of 3 A g−1, which indicates that it can be a suitable electrode material. In addition, an asymmetric supercapacitor with NiCu(CO3)(OH)2 on PAN composite as the cathode and graphene as the anode showed an ultra-high energy density of 89.2 W h kg−1 at a power density of 835 W kg−1 and a capacitance retention of 90.1% after 5000 cycles. Graphic abstract
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Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced battery technologies research · Advancements in Battery Materials
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References (68)
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1. P. Kumar, K.-H. Kim, V. Bansal, P. Kumar, Nanostructured materials: A progressive assessment and future direction for energy device applications. Coordin. Chem. Rev 353, 113 (2017)10.1016/j.ccr.2017.10.005 ↗
2. L.B. Huang, W. Xu, J. Hao, Energy device applications of synthesized 1D polymer nanomaterials. Small 13, 1701820 (2017)10.1002/smll.201701820 ↗
3. P. Dong, M.-T.F. Rodrigues, J. Zhang, R.S. Borges, K. Kalaga, A.L. Reddy, G.G. Silva, P.M. Ajayan, J. Lou, A flexible solar cell/supercapacitor integrated energy device. Nano Energy 42, 181 (2017)10.1016/j.nanoen.2017.10.035 ↗
4. H. Li, Z. Tang, Z. Liu, C. Zhi, Evaluating flexibility and wearability of flexible energy storage devices. Joule 3, 613 (2019)10.1016/j.joule.2019.01.013 ↗
5. J. Wang, X. Zhang, Z. Li, Y. Ma, L. Ma, Recent progress of biomass-derived carbon materials for supercapacitors. J. Power Sources 451, 227794 (2020)10.1016/j.jpowsour.2020.227794 ↗
6. R. Liu, A. Zhou, X. Zhang, J. Mu, H. Che, Y. Wang, T. Wang, Z. Zhang, Z. Kou, Fundamentals, advances and challenges of transition metal compounds-based supercapacitors. Chem. Eng. J. 412, 128611 (2021)10.1016/j.cej.2021.128611 ↗
7. T.-F. Yi, H. Chang, T.-T. Wei, S.-Y. Qi, Y. Li, Y.-R. Zhu, Approaching high-performance electrode materials of ZnCo2S4 nanoparticle wrapped carbon nanotubes for supercapacitors. J. Materiomics 7, 563 (2021)10.1016/j.jmat.2020.11.015 ↗
8. S. Biswas, V. Sharma, T. Singh, A. Chandra, External vibrations can destroy the specific capacitance of supercapacitors–from experimental proof to theoretical explanations. J. Mater. Chem. A 9, 6460 (2021)10.1039/D0TA11794C ↗
9. S.I. Wong, H. Lin, J. Sunarso, B.T. Wong, B. Jia, Optimization of ionic-liquid based electrolyte concentration for high-energy density graphene supercapacitors. Appl. Mater. Today 18, 100522 (2020)10.1016/j.apmt.2019.100522 ↗
10. D. Lee, H.W. Lee, N.M. Shinde, J.M. Yun, S. Mathur, K.H. Kim, Synthesis of nickel–copper composite with controllable nanostructure through facile solvent control as positive electrode for high-performance supercapacitors. Dalton Trans 49, 13123 (2020)10.1039/D0DT02427A ↗
11. T. Wang, M. Liu, H. Ma, Facile synthesis of flower-like copper-cobalt sulfide as binder-free faradaic electrodes for supercapacitors with improved electrochemical properties. Nanomaterials 7, 140 (2017)10.3390/nano7060140 ↗
12. Y. Li, Z. Kang, X. Yan, S. Cao, M. Li, Y. Guo, Y. Huan, X. Wen, Y. Zhang, A three-dimensional reticulate CNT-aerogel for a high mechanical flexibility fiber supercapacitor. Nanoscale 10, 9360 (2018)10.1039/C8NR01991F ↗
13. X. Zhang, X. Liu, Y. Zeng, Y. Tong, X. Lu, Oxygen defects in promoting the electrochemical performance of metal oxides for supercapacitors: Recent advances and challenges. Small Methods 4, 1900823 (2020)10.1002/smtd.201900823 ↗
14. J. Chen, J. Xu, S. Zhou, N. Zhao, C.-P. Wong, Amorphous nanostructured FeOOH and Co–Ni double hydroxides for high-performance aqueous asymmetric supercapacitors. Nano Energy 21, 145 (2016)10.1016/j.nanoen.2015.12.029 ↗
15. V.S. Kumbhar, H. Lee, J. Lee, N.R. Chodankar, K. Lee, Mesoporous design of ultrathin NiO nanosheet-coated vertically aligned hexagonal CoS nanoplate core–shell array for flexible all-solid-state supercapacitors. J. Alloys Compd. 863, 158064 (2021)10.1016/j.jallcom.2020.158064 ↗
16. Y. Zhao, Y. Zhang, Y. Cheng, W. Zhao, W. Chen, C. Meng, C. Huang, Synthesis of Co2SiO4/Ni(OH)2 core–shell structure as the supercapacitor electrode material with enhanced electrochemical properties. Mater. Lett. 282, 128774 (2021)10.1016/j.matlet.2020.128774 ↗
17. K. Karuppasamy, D. Vikraman, J.-H. Jeon, S. Ramesh, H.M. Yadav, V.R. Jothi, R. Bose, H.S. Kim, A. Alfantazi, H.-S. Kim, Highly porous, hierarchical microglobules of Co3O4 embedded N-doped carbon matrix for high performance asymmetric supercapacitors. Appl. Surf. Sci. 529, 147147 (2020)10.1016/j.apsusc.2020.147147 ↗
18. Z. Song, W. Liu, Q. Zhou, L. Zhang, Z. Zhang, H. Liu, J. Du, J. Chen, G. Liu, Z. Zhao, Cobalt hexacyanoferrate/MnO2 nanocomposite for asymmetrical supercapacitors with enhanced electrochemical performance and its charge storage mechanism. J. Power Sources 465, 228266 (2020)10.1016/j.jpowsour.2020.228266 ↗
19. M. Chamakh, A.I. Ayesh, Production and investigation of flexible nanofibers of sPEEK/PVP loaded with RuO2 nanoparticles. Mater. Design 204, 109678 (2021)10.1016/j.matdes.2021.109678 ↗
20. S. Vijayakumar, S. Nagamuthu, G. Muralidharan, Supercapacitor studies on NiO nanoflakes synthesized through a microwave route. ACS appl. Mater. inter 5, 2188 (2013)10.1021/am400012h ↗
21. W. Lv, L. Li, Q. Meng, X. Zhang, Molybdenum-doped CuO nanosheets on Ni foams with extraordinary specific capacitance for advanced hybrid supercapacitors. J. Mater. Sci. 55, 2492 (2020)10.1007/s10853-019-04129-9 ↗
22. V.T. Chebrolu, B. Balakrishnan, V. Raman, I. Cho, J.-S. Bak, K. Prabakar, H.-J. Kim, Co-electrodeposition of NiCu(OH)2@Ni-Cu-Se hierarchical nanoparticle structure for supercapacitor application with enhanced performance. Appl. Surf. Sci. 506, 145015 (2020)10.1016/j.apsusc.2019.145015 ↗
23. D. Lee, Q.X. Xia, R.S. Mane, J.M. Yun, K.H. Kim, Direct successive ionic layer adsorption and reaction (SILAR) synthesis of nickel and cobalt hydroxide composites for supercapacitor applications. J. Alloys. Compd 722, 809 (2017)10.1016/j.jallcom.2017.06.170 ↗
24. S. Liu, K. Hui, K. Hui, V.V. Jadhav, Q.X. Xia, J.M. Yun, Y. Cho, R.S. Mane, K.H. Kim, Facile synthesis of microsphere copper cobalt carbonate hydroxides electrode for asymmetric supercapacitor. Electrochim. Acta 188, 898 (2016)10.1016/j.electacta.2015.12.018 ↗
25. T.M. Masikhwa, J.K. Dangbegnon, A. Bello, M.J. Madito, D. Momodu, N. Manyala, Preparation and electrochemical investigation of the cobalt hydroxide carbonate/activated carbon nanocomposite for supercapacitor applications. J. Phys. Chem. Solids 88, 60 (2016)10.1016/j.jpcs.2015.09.015 ↗
26. D. Lee, Q.X. Xia, J.M. Yun, K.H. Kim, High-performance cobalt carbonate hydroxide nano-dot/NiCo(CO3)(OH)2 electrode for asymmetric supercapacitors. Appl. Surf. Sci. 433, 16 (2018)10.1016/j.apsusc.2017.10.066 ↗
27. M. Azad, Z. Hussain, M.M. Baig, MWCNTs/NiS2 decorated Ni foam based electrode for high-performance supercapacitors. Electrochim. Acta 345, 136196 (2020)10.1016/j.electacta.2020.136196 ↗
28. M. Huang, F. Li, J.Y. Ji, Y.X. Zhang, X.L. Zhao, X. Gao, Facile synthesis of single-crystalline NiO nanosheet arrays on Ni foam for high-performance supercapacitors. CrystEngComm 16, 2878 (2014)10.1039/C3CE42335B ↗
29. D. Lee, J.M. Yun, K.H. Kim, Preparation and electrochemical properties of nickel iron carbonate hydroxide as a cathode electrode material for asymmetric supercapacitors. Nanosci. Nanotech. Lett. 10, 741 (2018)10.1166/nnl.2018.2662 ↗
30. M. Panapoy, A. Dankeaw, B. Ksapabutr, Electrical conductivity of PAN-based carbon nanofibers prepared by electrospinning method. Thammasat Int J. Sc. Tech. 13, 11 (2008)
31. C. Hellert, J.L. Storck, T. Grothe, B. Kaltschmidt, A. Hütten, A. Ehrmann: Positioning and aligning electrospun PAN fibers by conductive and dielectric substrate patterns, in: Macromolecular Symposia, Macromol. Symposia, 395, 2000213 (2021).10.1002/masy.202000213 ↗
32. S. Temesgen, M. Rennert, T. Tesfaye, M. Nase, Review on spinning of biopolymer fibers from starch. Polymers 13, 1121 (2021)10.3390/polym13071121 ↗
33. E. Boyraz, F. Yalcinkaya, Hydrophilic surface-modified PAN nanofibrous membranes for efficient oil-water emulsion separation. Polymers 13, 197 (2021)10.3390/polym13020197 ↗
34. T. Yang, H. Yang, S.J. Zhen, C.Z. Huang, Hydrogen-bond-mediated in situ fabrication of AgNPs/Agar/PAN electrospun nanofibers as reproducible SERS substrates. ACS Appl. Mater. Inter. 7, 1586 (2015)10.1021/am507010q ↗
35. M. Gao, L. Zeng, J. Nie, G. Ma, Polymer–metal–organic framework core–shell framework nanofibers via electrospinning and their gas adsorption activities. RSC Adv 6, 7078 (2016)10.1039/C5RA23147G ↗
36. D. Potphode, M.S. Sayed, T.L. Tamang, J.-J. Shim, High-performance binder-free flower-like (Ni0. 66Co0.3Mn0.04)2(OH)2(CO3) array synthesized using ascorbic acid for supercapacitor applications. Chem. Eng. J 378, 122129 (2019)10.1016/j.cej.2019.122129 ↗
37. G. Zhang, P. Qin, R. Nasser, S. Li, P. Chen, J. Song, Synthesis of Co(CO3)0.5(OH)/Ni2 (CO3)(OH)2 nanobelts and their application in flexible all-solid-state asymmetric supercapacitor. Chem. Eng. J 387, 124029 (2020)10.1016/j.cej.2020.124029 ↗
38. G. Yilmaz, C.F. Tan, Y.F. Lim, G.W. Ho, Pseudomorphic transformation of interpenetrated prussian blue analogs into defective nickel iron selenides for enhanced electrochemical and photo-electrochemical water splitting. Adv. Energy Mater. 9, 1802983 (2019)10.1002/aenm.201802983 ↗
39. S. Ding, T. Zhu, J.S. Chen, Z. Wang, C. Yuan, X.W.D. Lou, Controlled synthesis of hierarchical NiO nanosheet hollow spheres with enhanced supercapacitive performance. J. Mater. Chem. 21, 6602 (2011)10.1039/c1jm00017a ↗
40. A. Mansour, Characterization of β-Ni(OH)2 by XPS. Surf. Sci. Spectra 3, 239 (1994)10.1116/1.1247752 ↗
41. N. Pauly, S. Tougaard, F. Yubero, Determination of the Cu 2p primary excitation spectra for Cu, Cu2O and CuO. Surf. Sci. 620, 17 (2014)10.1016/j.susc.2013.10.009 ↗
42. R. Morent, N. De Geyter, C. Leys, L. Gengembre, E. Payen, Comparison between XPS-and FTIR-analysis of plasma-treated polypropylene film surfaces, Surface and Interface Analysis: An International Journal devoted to the development and application of techniques for the analysis of surfaces. Interfaces. Thin Films 40, 597 (2008)
43. L. Fen-rong, L. Wen, G. Hui-qing, L. Bao-qing, B. Zong-qing, H. Rui-sheng, XPS study on the change of carbon-containing groups and sulfur transformation on coal surface. J. Fuel Chem. Technol. 39, 81 (2011)10.1016/S1872-5813(11)60011-X ↗
44. D. Lee, N. Shinde, J.C. Ding, J. Fu, R.K. Sahoo, H.W. Lee, J.M. Yun, H.-C. Shin, K.H. Kim, Improvement of electrical performance by surface structure of Ni-material as a high-performance asymmetric supercapacitor electrode. Ceram. Inter. 46, 11189 (2020)10.1016/j.ceramint.2020.01.140 ↗
45. Q. Zhou, J. Huang, C. Li, Z. Lv, H. Zhu, G. Hu, Wrapping CuCo2S4 arrays on nickel foam with Ni2(CO3)(OH)2 nanosheets as a high-performance faradaic electrode. New J. Chem. 43, 5904 (2019)10.1039/C9NJ00038K ↗
46. H. Yang, Effects of supercapacitor physics on its charge capacity. IEEE Trans. Power Electr. 34, 646 (2018)10.1109/TPEL.2018.2812882 ↗
47. A.M. Patil, X. Yue, A. Yoshida, S. Li, X. Hao, A. Abudula, G. Guan, Redox-ambitious route to boost energy and capacity retention of pouch type asymmetric solid-state supercapacitor fabricated with graphene oxide-based battery-type electrodes. Appl. Mater. Today 19, 100563 (2020)10.1016/j.apmt.2020.100563 ↗
48. J. Yan, Z. Fan, W. Sun, G. Ning, T. Wei, Q. Zhang, R. Zhang, L. Zhi, F. Wei, Advanced asymmetric supercapacitors based on Ni(OH) 2/graphene and porous graphene electrodes with high energy density. Adv. Funct. Mater 22, 2632 (2012)10.1002/adfm.201102839 ↗
49. Y. Wang, B. Chang, D. Guan, K. Pei, Z. Chen, M. Yang, X. Dong, Preparation of nanospherical porous NiO by a hard template route and its supercapacitor application. Mater. Lett. 135, 172 (2014)10.1016/j.matlet.2014.07.150 ↗
50. C. Wang, J. Xu, M.F. Yuen, J. Zhang, Y. Li, X. Chen, W. Zhang, Hierarchical composite electrodes of nickel oxide nanoflake 3D graphene for high-performance pseudocapacitors. Adv. Funct. Mater. 24, 6372 (2014)10.1002/adfm.201401216 ↗
51. G.S. Gund, D.P. Dubal, S.S. Shinde, C.D. Lokhande, Architectured morphologies of chemically prepared NiO/MWCNTs nanohybrid thin films for high performance supercapacitors. ACS Appl. Mater. Inter. 6, 3176 (2014)10.1021/am404422g ↗
52. Z. Li, M. Shao, L. Zhou, R. Zhang, C. Zhang, J. Han, M. Wei, D.G. Evans, X. Duan, A flexible all-solid-state micro-supercapacitor based on hierarchical CuO@ layered double hydroxide core–shell nanoarrays. Nano Energy 20, 294 (2016)10.1016/j.nanoen.2015.12.030 ↗
53. K. Krishnamoorthy, S.-J. Kim, Growth: Characterization and electrochemical properties of hierarchical CuO nanostructures for supercapacitor applications. Mater. Res. Bull. 48, 3136 (2013)10.1016/j.materresbull.2013.04.082 ↗
54. M.B. Gholivand, H. Heydari, A. Abdolmaleki, H. Hosseini, Nanostructured CuO/PANI composite as supercapacitor electrode material. Mater. Sci. Semicon. Proc. 30, 157 (2015)10.1016/j.mssp.2014.09.047 ↗
55. S. Shinde, H. Yadav, G. Ghodake, A. Kadam, V. Kumbhar, J. Yang, K. Hwang, A. Jagadale, S. Kumar, D. Kim, Using chemical bath deposition to create nanosheet-like CuO electrodes for supercapacitor applications. Colloid Surf. B 181, 1004 (2019)10.1016/j.colsurfb.2019.05.079 ↗
56. Y. Wang, C. Shen, L. Niu, R. Li, H. Guo, Y. Shi, C. Li, X. Liu, Y. Gong, Hydrothermal synthesis of CuCo2O4/CuO nanowire arrays and RGO/Fe2O3 composites for high-performance aqueous asymmetric supercapacitors. J. Mater. Chem. A 4, 9977 (2016)10.1039/C6TA02950G ↗
57. Y. Feng, W. Liu, Y. Wang, W. Gao, J. Li, K. Liu, X. Wang, J. Jiang, Oxygen vacancies enhance supercapacitive performance of CuCo2O4 in high-energy-density asymmetric supercapacitors. J. Power Sources 458, 228005 (2020)10.1016/j.jpowsour.2020.228005 ↗
58. S.M. Pawar, B.S. Pawar, P.T. Babar, A.T.A. Ahmed, H.S. Chavan, Y. Jo, S. Cho, J. Kim, B. Hou, A.I. Inamdar, Nanoporous CuCo2O4 nanosheets as a highly efficient bifunctional electrode for supercapacitors and water oxidation catalysis. Appl. Surf. Sci 470, 360 (2019)10.1016/j.apsusc.2018.11.151 ↗
59. L. Abbasi, M. Arvand, Engineering hierarchical ultrathin CuCo2O4 nanosheets array on Ni foam by rapid electrodeposition method toward high-performance binder-free supercapacitors. Appl. Surf. Sci 445, 272 (2018)10.1016/j.apsusc.2018.03.193 ↗
60. A. Bera, A. Maitra, A.K. Das, L. Halder, S. Paria, S.K. Si, A. De, S. Ojha, B.B. Khatua, A quasi-solid-state asymmetric supercapacitor device based on honeycomb-like nickel–copper–carbonate–hydroxide as a positive and iron oxide as a negative electrode with superior electrochemical performances. ACS Appl. Electron. Mater 2, 177 (2020)10.1021/acsaelm.9b00677 ↗
61. Q. Zhou, T. Wei, Z. Liu, L. Zhang, B. Yuan, Z. Fan, Nickel hexacyanoferrate on graphene sheets for high-performance asymmetric supercapacitors in neutral aqueous electrolyte. Electrochim. Acta 303, 40 (2019)10.1016/j.electacta.2019.02.070 ↗
62. L. Zhang, H. Gong, Unravelling the correlation between nickel to copper ratio of binary oxides and their superior supercapacitor performance. Electrochim. Acta 234, 82 (2017)10.1016/j.electacta.2017.03.070 ↗
63. S. Song, L. Zhang, H. Shi, Facile synthesis of three-dimensional nanostructured Ni(HCO3)2/(Cu0.2Ni0.8) O as high-performance pseudo-capacitance electrode. J. Alloy. Compd 763, 791 (2018)10.1016/j.jallcom.2018.05.292 ↗
64. S. Kumar, G. Saeed, L. Zhu, K.N. Hui, N.H. Kim, J.H. Lee, 0D to 3D carbon-based networks combined with pseudocapacitive electrode material for high energy density supercapacitor: A review. Chem. Eng. J 403, 126352 (2020)10.1016/j.cej.2020.126352 ↗
65. H.-G. Jung, N. Venugopal, B. Scrosati, Y.-K. Sun, A high energy and power density hybrid supercapacitor based on an advanced carbon-coated Li4Ti5O12 electrode. J. Power Sources 221, 266 (2013)10.1016/j.jpowsour.2012.08.039 ↗
66. Q. Qu, P. Zhang, B. Wang, Y. Chen, S. Tian, Y. Wu, R. Holze, Electrochemical performance of MnO2 nanorods in neutral aqueous electrolytes as a cathode for asymmetric supercapacitors. J. Phys. Chem. C 113, 14020 (2009)10.1021/jp8113094 ↗
67. Y.-H. Lee, K.-H. Chang, C.-C. Hu, Differentiate the pseudocapacitance and double-layer capacitance contributions for nitrogen-doped reduced graphene oxide in acidic and alkaline electrolytes. J. Power Sources 227, 300 (2013)10.1016/j.jpowsour.2012.11.026 ↗
68. J. Huang, P. Xu, D. Cao, X. Zhou, S. Yang, Y. Li, G. Wang, Asymmetric supercapacitors based on β-Ni(OH)2 nanosheets and activated carbon with high energy density. J. Power Sources 246, 371 (2014)10.1016/j.jpowsour.2013.07.105 ↗