2D nanomaterials in 3D/4D-printed biomedical devices
Source abstract
Abstract
Two-dimensional materials are becoming a new sensation in the chemical, electrical, energy storage, and biomedical industries. Since the invention of graphene, scientists worldwide have been attempting to explore novel 2D materials. High surface-to-volume ratio, lightweight, anisotropy, and multi-functionality are some special features of these 2D materials. Such characteristics can be merged with the fabrication flexibility of 3D printing to develop complex structures including shape, size, and functionality. These complex 3D-printed 2D materials can be used in novel biomedical applications, including the advancement of targeted drug delivery, cancer therapy, tissue engineering, and biosensors. This review article focuses on the recent development of 3D/4D printed complex structures from 2D nanomaterials in biomedical applications. We have assessed the concept of hybridization of existing 2D nanomaterials and discussed the significance of computational modeling in 2D nanomaterials. Current trends, challenges, and prospects of 3D/4D-printed 2D nanomaterials in the biomedical field are also delineated.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Graphene and Nanomaterials Applications · MXene and MAX Phase Materials · Graphene research and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
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1. P.M.J. Ferlay, M. Ervik, F. Lam, M. Colombet, L. Mery, Global cancer observatory: cancer today. Int. Agency Res. Cancer (2020).
2. R.S. Ambekar, B. Kandasubramanian, A polydopamine-based platform for anti-cancer drug delivery. Biomater. Sci. 7(5), 1776 (2019)10.1039/C8BM01642A ↗
3. E. Oh, R. Liu, A. Nel, K.B. Gemill, M. Bilal, Y. Cohen, I.L. Medintz, Meta-analysis of cellular toxicity for cadmium-containing quantum dots. Nat. Nanotechnol. 11(5), 479 (2016)10.1038/nnano.2015.338 ↗
4. K.S. Novoselov, V.I. Fal’ko, L. Colombo, P.R. Gellert, M.G. Schwab, K. Kim, A roadmap for graphene. Nature 490(7419), 192–200 (2012)10.1038/nature11458 ↗
5. L. Lin, H. Peng, Z. Liu, Synthesis Challenges for Graphene Industry. Nat. Mater. 18, 520 (2019)10.1038/s41563-019-0341-4 ↗
6. A. Bolotsky, D. Butler, C. Dong, K. Gerace, N.R. Glavin, C. Muratore, J.A. Robinson, A. Ebrahimi, Two-dimensional materials in biosensing and healthcare: from in vitro diagnostics to optogenetics and beyond. ACS Nano 13(9), 9781 (2019)10.1021/acsnano.9b03632 ↗
7. K. Akada, T.O. Terasawa, G. Imamura, S. Obata, K. Saiki, Control of work function of graphene by plasma assisted nitrogen doping. Appl. Phys. Lett. 104(13), 131602 (2014)10.1063/1.4870424 ↗
8. Y. Shao, J. Wang, H. Wu, J. Liu, I.A. Aksay, Y. Lin, Graphene based electrochemical sensors and biosensors: a review. Electroanalysis 22, 1027 (2010)10.1002/elan.200900571 ↗
9. K. Kalantar-Zadeh, J.Z. Ou, ACS Sens. 1, 5 (2016)10.1021/acssensors.5b00142 ↗
10. Q.H. Wang, K. Kalantar-Zadeh, A. Kis, J.N. Coleman, M.S. Strano, Electronics and optoelectronics of two-dimensional transition metal dichalcogenides. Nat. Nanotechnol. 7, 699 (2012)10.1038/nnano.2012.193 ↗
11. Y. Cai, G. Zhang, Y.W. Zhang, Layer-dependent band alignment and work function of few-layer phosphorene. Sci. Rep. 4, 6677 (2014)10.1038/srep06677 ↗
12. S. Jin, Y. Jiang, H. Ji, Y. Yu, Advanced 3D current collectors for lithium-based batteries. Adv. Mater. 30(48), 1802014 (2018)10.1002/adma.201802014 ↗
13. N. Yousefi, X. Lu, M. Elimelech, N. Tufenkji, Environmental performance of graphene-based 3D macrostructures. Nat. Nanotechnol. 14, 107 (2019)10.1038/s41565-018-0325-6 ↗
14. W. Li, M.C. Tekell, C. Liu, J.A. Hethcock, D. Fan, Flexible all-solid-state supercapacitors of high areal capacitance enabled by porous graphite foams with diverging microtubes. Adv. Funct. Mater. 28(29), 1800601 (2018)10.1002/adfm.201800601 ↗
15. W. Li, X. Xu, C. Liu, M.C. Tekell, J. Ning, J. Guo, J. Zhang, D. Fan, Ultralight and binder-free all-solid-state flexible supercapacitors for powering wearable strain sensors. Adv. Funct. Mater. 27(39), 1702738 (2017)10.1002/adfm.201702738 ↗
16. A. Nieto, R. Dua, C. Zhang, B. Boesl, S. Ramaswamy, A. Agarwal, Three dimensional graphene foam/polymer hybrid as a high strength biocompatible scaffold. Adv. Funct. Mater. 25(25), 3916 (2015)10.1002/adfm.201500876 ↗
17. Y. Cai, J. Shen, Z. Dai, X. Zang, Q. Dong, G. Guan, L.J. Li, W. Huang, X. Dong, Extraordinarily stretchable all-carbon collaborative nanoarchitectures for epidermal sensors. Adv. Mater. 29(31), 1606411 (2017)10.1002/adma.201606411 ↗
18. K. Shehzad, Y. Xu, C. Gao, X. Duan, Three-dimensional macro-structures of two-dimensional nanomaterials. Chem. Soc. Rev. 45, 5541 (2016)10.1039/C6CS00218H ↗
19. J.E. Kim, J.H. Oh, M. Kotal, N. Koratkar, I.K. Oh, Self-assembly and morphological control of three-dimensional macroporous architectures built of two-dimensional materials. Nano Today 14, 100 (2017)10.1016/j.nantod.2017.04.008 ↗
20. J.-Y. Lee, J. An, C.K. Chua, Fundamentals and applications of 3D printing for novel materials. Appl. Mater. Today 7, 120 (2017)10.1016/j.apmt.2017.02.004 ↗
21. R.S. Ambekar, E.F. Oliveira, B. Kushwaha, V. Pal, L.D. Machado, M. Sajadi, R.H. Baughman, P.M. Ajayan, A.K. Roy, D.S. Galvao, C.S. Tiwary, On the mechanical properties of atomic and 3D printed zeolite-templated carbon nanotube networks. Addit. Manuf. (2020). https://doi.org/10.1016/j.addma.2020.10162810.1016/j.addma.2020.101628 ↗
22. S.M. Sajadi, P.S. Owuor, S. Schara, C.F. Woellner, V. Rodrigues, R. Vajtai, J. Lou, D.S. Galvão, C.S. Tiwary, P.M. Ajayan, Multiscale geometric design principles applied to 3D printed Schwarzites. Adv. Mater. 30(1), 1704820 (2018)10.1002/adma.201704820 ↗
23. B. Kushwaha, K. Dwivedi, R.S. Ambekar, V. Pal, D.P. Jena, D.R. Mahapatra, C.S. Tiwary, Mechanical and acoustic behavior of 3D printed hierarchical mathematical fractal Menger sponge. Adv. Eng. Mater. (2021). https://doi.org/10.1002/adem.20200147110.1002/adem.202001471 ↗
24. R. Yang, J. Zhou, C. Yang, L. Qiu, H. Cheng, Recent Progress in 3D Printing of 2D Material-Based Macrostructures. Adv. Mater. Technol. 5, 1901066 (2020)10.1002/admt.201901066 ↗
25. Z. Tehrani, S.P. Whelan, A.B. Mostert, J.V. Paulin, M.M. Ali, E.D. Ahmadi, C.F.O. Graeff, O.J. Guy, D.T. Gethin, Printable and flexible graphene pH sensors utilising thin film melanin for physiological applications. 2D Mater. 7(2), 024008 (2020)10.1088/2053-1583/ab72d5 ↗
26. S.K. Tuteja, C. Ormsby, S. Neethirajan, Noninvasive label-free detection of cortisol and lactate using graphene embedded screen-printed electrode. Nano-Micro Lett. 10(3), 41 (2018)10.1007/s40820-018-0193-5 ↗
27. P.K. Chakraborty, J. Azadmanjiri, C.L.P. Pavithra, X. Wang, S.H. Masood, S.R. Dey, J. Wang, Advancements in therapeutics via 3D printed multifunctional architectures from dispersed 2D nanomaterial inks. Small 16(49), 1 (2020)10.1002/smll.202004900 ↗
28. M. Ashton, J. Paul, S.B. Sinnott, R.G. Hennig, Topology-scaling identification of layered solids and stable exfoliated 2D materials. Phys. Rev. Lett. 118(10), 106101 (2017)10.1103/PhysRevLett.118.106101 ↗
29. S. Dang, Q.L. Zhu, Q. Xu, Nanomaterials derived from metal-organic frameworks. Nat. Rev. Mater. 3(1), 17075 (2017)10.1038/natrevmats.2017.75 ↗
30. L. Li, Y. Yu, G.J. Ye, Q. Ge, X. Ou, H. Wu, D. Feng, X.H. Chen, Y. Zhang, Black phosphorus field-effect transistors. Nat. Nanotechnol. 9(5), 372 (2014)10.1038/nnano.2014.35 ↗
31. B. Radisavljevic, A. Radenovic, J. Brivio, V. Giacometti, A. Kis, Single-layer MoS2 transistors. Nat. Nanotechnol. 6(3), 147 (2011)10.1038/nnano.2010.279 ↗
32. H. Li, Z. Yin, Q. He, H. Li, X. Huang, G. Lu, D.W.H. Fam, A.I.Y. Tok, Q. Zhang, H. Zhang, Fabrication of single- and multilayer MoS 2 film-based field-effect transistors for sensing NO at room temperature. Small 8(1), 63 (2012)10.1002/smll.201101016 ↗
33. D.J. Late, Y.K. Huang, B. Liu, J. Acharya, S.N. Shirodkar, J. Luo, A. Yan, D. Charles, U.V. Waghmare, V.P. Dravid, C.N.R. Rao, Sensing behavior of atomically thin-layered MoS2 transistors. ACS Nano 7(6), 4879 (2013)10.1021/nn400026u ↗
34. F.K. Perkins, A.L. Friedman, E. Cobas, P.M. Campbell, G.G. Jernigan, B.T. Jonker, Chemical vapor sensing with monolayer MoS2. Nano Lett. 13(2), 668 (2013)10.1021/nl3043079 ↗
35. W. Zhu, M.N. Yogeesh, S. Yang, S.H. Aldave, J.S. Kim, S. Sonde, L. Tao, N. Lu, D. Akinwande, Flexible black phosphorus ambipolar transistors, circuits and AM demodulator. Nano Lett. 15(3), 1883 (2015)10.1021/nl5047329 ↗
36. O. Lopez-Sanchez, D. Lembke, M. Kayci, A. Radenovic, A. Kis, Ultrasensitive photodetectors based on monolayer MoS 2. Nat. Nanotechnol. 8(7), 497 (2013)10.1038/nnano.2013.100 ↗
37. M. Bernardi, M. Palummo, J.C. Grossman, Extraordinary sunlight absorption and one nanometer thick photovoltaics using two-dimensional monolayer materials. Nano Lett. 13(8), 3664 (2013)10.1021/nl401544y ↗
38. W. Zhang, C.P. Chuu, J.K. Huang, C.H. Chen, M.L. Tsai, Y.H. Chang, C. Te Liang, Y.Z. Chen, Y.L. Chueh, J.H. He, M.Y. Chou, L.J. Li, Ultrahigh-gain photodetectors based on atomically thin graphene-MoS2 heterostructures. Sci. Rep. 4(1), 1 (2015)
39. X. Yang, C. Cheng, Y. Wang, L. Qiu, D. Li, Liquid-mediated dense integration of graphene materials for compact capacitive energy storage. Science (-80). 341(6145), 534 (2013)10.1126/science.1239089 ↗
40. J. Hassoun, F. Bonaccorso, M. Agostini, M. Angelucci, M.G. Betti, R. Cingolani, M. Gemmi, C. Mariani, S. Panero, V. Pellegrini, B. Scrosati, An advanced lithium-ion battery based on a graphene anode and a lithium iron phosphate cathode. Nano Lett. 14(8), 4901 (2014)10.1021/nl502429m ↗
41. Y. Tao, X. Xie, W. Lv, D.M. Tang, D. Kong, Z. Huang, H. Nishihara, T. Ishii, B. Li, D. Golberg, F. Kang, T. Kyotani, Q.H. Yang, Towards ultrahigh volumetric capacitance: graphene derived highly dense but porous carbons for supercapacitors. Sci. Rep. 3(1), 1 (2013)
42. M. Acerce, D. Voiry, M. Chhowalla, Metallic 1T phase MoS2 nanosheets as supercapacitor electrode materials. Nat. Nanotechnol. 10(4), 313 (2015)10.1038/nnano.2015.40 ↗
43. V. Fatemi, S. Wu, Y. Cao, L. Bretheau, Q.D. Gibson, K. Watanabe, T. Taniguchi, R.J. Cava, P. Jarillo-Herrero, Electrically tunable low-density superconductivity in a monolayer topological insulator. Science (-80). 362(6417), 926 (2018)10.1126/science.aar4642 ↗
44. E. Sajadi, T. Palomaki, Z. Fei, W. Zhao, P. Bement, C. Olsen, S. Luescher, X. Xu, J.A. Folk, D.H. Cobden, Gate-induced superconductivity in a monolayer topological insulator. Science (-80). 362(6417), 922 (2018)10.1126/science.aar4426 ↗
45. A. Molle, J. Goldberger, M. Houssa, Y. Xu, S.C. Zhang, D. Akinwande, Buckled two-dimensional Xene sheets. Nat. Mater. 16, 163 (2017)10.1038/nmat4802 ↗
46. K.S. Novoselov, D. Jiang, F. Schedin, T.J. Booth, V.V. Khotkevich, S.V. Morozov, A.K. Geim, Two-dimensional atomic crystals. Proc. Natl. Acad. Sci. U.S.A. 102(30), 10451 (2005)10.1073/pnas.0502848102 ↗
47. K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva, A.A. Firsov, Electric field in atomically thin carbon films. Science (-80). 306(5696), 666 (2004)10.1126/science.1102896 ↗
48. E. Pop, V. Varshney, A.K. Roy, Thermal properties of graphene: fundamentals and applications. MRS Bull. 37(12), 1273 (2012)10.1557/mrs.2012.203 ↗
49. C. Lee, X. Wei, J.W. Kysar, J. Hone, Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science (80-) 321(5887), 385 (2008)10.1126/science.1157996 ↗
50. K. Cao, S. Feng, Y. Han, L. Gao, T. Hue Ly, Z. Xu, Y. Lu, Elastic straining of free-standing monolayer graphene. Nat. Commun. 11(1), 1 (2020)10.1038/s41467-019-13993-7 ↗
51. B.D. Briggs, B. Nagabhirava, G. Rao, R. Geer, H. Gao, Y. Xu, B. Yu, Electromechanical robustness of monolayer graphene with extreme bending. Appl. Phys. Lett. 97(22), 223102 (2010)10.1063/1.3519982 ↗
52. P. Zhang, L. Ma, F. Fan, Z. Zeng, C. Peng, P.E. Loya, Z. Liu, Y. Gong, J. Zhang, X. Zhang, P.M. Ajayan, T. Zhu, J. Lou, Fracture toughness of graphene. Nat. Commun. 5(1), 1 (2014)
53. F. Bonaccorso, L. Colombo, G. Yu, M. Stoller, V. Tozzini, A.C. Ferrari, R.S. Ruoff, V. Pellegrini, Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage. Science 347(6217), 1246501 (2015)10.1126/science.1246501 ↗
54. G. Lalwani, M. D’Agati, A.M. Khan, B. Sitharaman, Adv. Drug Deliv. Rev. 105, 109 (2016)10.1016/j.addr.2016.04.028 ↗
55. S. Joshi, R. Siddiqui, P. Sharma, R. Kumar, G. Verma, A. Saini, Green synthesis of peptide functionalized reduced graphene oxide (rGO) nano bioconjugate with enhanced antibacterial activity. Sci. Rep. 10(1), 1 (2020)10.1038/s41598-019-56847-4 ↗
56. Y. Talukdar, J.T. Rashkow, G. Lalwani, S. Kanakia, B. Sitharaman, The effects of graphene nanostructures on mesenchymal stem cells. Biomaterials 35(18), 4863 (2014)10.1016/j.biomaterials.2014.02.054 ↗
57. W.S. Hummers, R.E. Offeman, Preparation of graphitic oxide. J. Am. Chem. Soc. 80(6), 1339 (1958)10.1021/ja01539a017 ↗
58. H.V. Kumar, S.J. Woltornist, D.H. Adamson, Fractionation and characterization of graphene oxide by oxidation extent through emulsion stabilization. Carbon N. Y. 98, 491 (2016)10.1016/j.carbon.2015.10.083 ↗
59. H.V. Kumar, K.Y.S. Huang, S.P. Ward, D.H. Adamson, Altering and investigating the surfactant properties of graphene oxide. J. Colloid Interface Sci. 493, 365 (2017)10.1016/j.jcis.2017.01.043 ↗
60. C. Gómez-Navarro, R.T. Weitz, A.M. Bittner, M. Scolari, A. Mews, M. Burghard, K. Kern, Electronic transport properties of individual chemically reduced graphene oxide sheets. Nano Lett. 7(11), 3499 (2007)10.1021/nl072090c ↗
61. H.C. Schniepp, J.L. Li, M.J. McAllister, H. Sai, M. Herrera-Alonson, D.H. Adamson, R.K. Prud’homme, R. Car, D.A. Seville, I.A. Aksay, Functionalized single graphene sheets derived from splitting graphite oxide. J. Phys. Chem. B 110(17), 8535 (2006)10.1021/jp060936f ↗
62. E.S. Bober, Final report on reverse osmosis membranes containing graphitic oxide. U.S. Dept. Inter. 116 (1970).
63. W. Gao, M. Majumder, L.B. Alemany, T.N. Narayanan, M.A. Ibarra, B.K. Pradhan, P.M. Ajayan, Engineered graphite oxide materials for application in water purification. ACS Appl. Mater. Interfaces 3(6), 1821 (2011)10.1021/am200300u ↗
64. R. Mukherjee, A.V. Thomas, A. Krishnamurthy, N. Koratkar, Photothermally reduced graphene as high-power anodes for lithium-ion batteries. ACS Nano 6(9), 7867 (2012)10.1021/nn303145j ↗
65. L. David, G. Singh, Reduced graphene oxide paper electrode: opposing effect of thermal annealing on Li and Na cyclability. J. Phys. Chem. C 118(49), 28401 (2014)10.1021/jp5080847 ↗
66. Z. Yuan, H.J. Peng, J.Q. Huang, X.Y. Liu, D.W. Wang, X.B. Cheng, Q. Zhang, Hierarchical free-standing carbon-nanotube paper electrodes with ultrahigh sulfur-loading for lithium-sulfur batteries. Adv. Funct. Mater. 24(39), 6105 (2014)10.1002/adfm.201401501 ↗
67. S.C. Ray, Application of Graphene and Graphene-Oxide Based Nanomaterials. (2015), pp. 39–5510.1016/B978-0-323-37521-4.00002-9 ↗
68. A.T. Smith, A.M. LaChance, S. Zeng, B. Liu, L. Sun, Synthesis, properties, and applications of graphene oxide/reduced graphene oxide and their nanocomposites. Nano Mater. Sci. 1(1), 31 (2019)10.1016/j.nanoms.2019.02.004 ↗
69. J. Kim, J.H. Jeon, H.J. Kim, H. Lim, I.K. Oh, Durable and water-floatable ionic polymer actuator with hydrophobic and asymmetrically laser-scribed reduced graphene oxide paper electrodes. ACS Nano 8(3), 2986 (2014)10.1021/nn500283q ↗
70. G. Eda, G. Fanchini, M. Chhowalla, Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material. Nat. Nanotechnol. 3(5), 270 (2008)10.1038/nnano.2008.83 ↗
71. S. Pei, J. Zhao, J. Du, W. Ren, H.M. Cheng, Direct reduction of graphene oxide films into highly conductive and flexible graphene films by hydrohalic acids. Carbon N. Y. 48(15), 4466 (2010)10.1016/j.carbon.2010.08.006 ↗
72. C. Bin Kim, J. Lee, J. Cho, M. Goh, Thermal conductivity enhancement of reduced graphene oxide via chemical defect healing for efficient heat dissipation. Carbon N. Y. 139, 386 (2018)10.1016/j.carbon.2018.07.008 ↗
73. J.D. Renteria, S. Ramirez, H. Malekpour, B. Alonso, A. Centeno, A. Zurutuza, A.I. Cocemasov, D.L. Nika, A.A. Balandin, Strongly anisotropic thermal conductivity of free-standing reduced graphene oxide films annealed at high temperature. Adv. Funct. Mater. 25(29), 4664 (2015)10.1002/adfm.201501429 ↗
74. A.E. Jakus, E.B. Secor, A.L. Rutz, S.W. Jordan, M.C. Hersam, R.N. Shah, Three-dimensional printing of high-content graphene scaffolds for electronic and biomedical applications. ACS Nano 9(4), 4636 (2015)10.1021/acsnano.5b01179 ↗
75. W. He, Y. Sun, J. Xi, A.A.M. Abdurhman, J. Ren, H. Duan, Printing graphene-carbon nanotube-ionic liquid gel on graphene paper: towards flexible electrodes with efficient loading of PtAu alloy nanoparticles for electrochemical sensing of blood glucose. Anal. Chim. Acta 903, 61 (2016)10.1016/j.aca.2015.11.019 ↗
76. S.K. Misra, F. Ostadhossein, R. Babu, J. Kus, D. Tankasala, A. Sutrisno, K.A. Walsh, C.R. Bromfield, D. Pan, 3D-Printed multidrug-eluting stent from graphene-nanoplatelet-doped biodegradable polymer composite. Adv. Healthc. Mater. 6(11), 1700008 (2017)10.1002/adhm.201700008 ↗
77. K. Parate, S.V. Rangnekar, D. Jing, D.L. Mendivelso-Perez, S. Ding, E.B. Secor, E.A. Smith, J.M. Hostetter, M.C. Hersam, J.C. Claussen, Aerosol-jet-printed graphene immunosensor for label-free cytokine monitoring in serum. ACS Appl. Mater. Interfaces 12(7), 8592 (2020)10.1021/acsami.9b22183 ↗
78. X. Zhou, M. Nowicki, H. Cui, W. Zhu, X. Fang, S. Miao, S.J. Lee, M. Keidar, L.G. Zhang, 3D bioprinted graphene oxide-incorporated matrix for promoting chondrogenic differentiation of human bone marrow mesenchymal stem cells. Carbon N. Y. 116, 615 (2017)10.1016/j.carbon.2017.02.049 ↗
79. H. Belaid, S. Nagarajan, C. Teyssier, C. Barou, J. Barés, S. Balme, H. Garay, V. Huon, D. Cornu, V. Cavaillès, M. Bechelany, Development of new biocompatible 3D printed graphene oxide-based scaffolds. Mater. Sci. Eng. C 110, 110595 (2020)10.1016/j.msec.2019.110595 ↗
80. S. Vijayavenkataraman, S. Thaharah, S. Zhang, W.F. Lu, J.Y.H. Fuh, 3D-printed PCL/rGO conductive scaffolds for peripheral nerve injury repair. Artif. Organs 43(5), 515 (2019)10.1111/aor.13360 ↗
81. V.A.O.P. Silva, W.S. Fernandes-Junior, D.P. Rocha, J.S. Stefano, R.A.A. Munoz, J.A. Bonacin, B.C. Janegitz, 3D-printed reduced graphene oxide/polylactic acid electrodes: a new prototyped platform for sensing and biosensing applications. Biosens. Bioelectron. 170, 112684 (2020)10.1016/j.bios.2020.112684 ↗
82. M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J. Niu, M. Heon, L. Hultman, Y. Gogotsi, M.W. Barsoum, Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv. Mater. 23(37), 4248 (2011)10.1002/adma.201102306 ↗
83. M. Naguib, V.N. Mochalin, M.W. Barsoum, Y. Gogotsi, 25th anniversary article: MXenes: a new family of two-dimensional materials. Adv. Mater. 26(7), 992 (2014)10.1002/adma.201304138 ↗
84. A.N. Enyashin, A.L. Ivanovskii, Structural and electronic properties and stability of MX enes Ti 2C and Ti3C2 functionalized by methoxy groups. J. Phys. Chem. C 117(26), 13637 (2013)10.1021/jp401820b ↗
85. Y. Xie, P.R.C. Kent, Hybrid density functional study of structural and electronic properties of functionalized Tin+1Xn (X=C, N) monolayers. Phys. Rev. B 87(23), 235441 (2013)10.1103/PhysRevB.87.235441 ↗
86. M. Khazaei, M. Arai, T. Sasaki, C.-Y. Chung, N.S. Venkataramanan, M. Estili, Y. Sakka, Y. Kawazoe, Novel electronic and magnetic properties of two-dimensional transition metal carbides and nitrides. Adv. Funct. Mater. 23(17), 2185 (2013)10.1002/adfm.201202502 ↗
87. Q. Tang, Z. Zhou, P. Shen, Are MXenes promising anode materials for Li ion batteries? Computational studies on electronic properties and Li storage capability of Ti 3C 2 and Ti 3C 2X 2 (X = F, OH) monolayer. J. Am. Chem. Soc. 134(40), 16909 (2012)10.1021/ja308463r ↗
88. M. Ghidiu, M.R. Lukatskaya, M.Q. Zhao, Y. Gogotsi, M.W. Barsoum, Conductive two-dimensional titanium carbide “clay” with high volumetric capacitance. Nature 516(7529), 78 (2015)10.1038/nature13970 ↗
89. J. Halim, M.R. Lukatskaya, K.M. Cook, J. Lu, C.R. Smith, L.Å. Näslund, S.J. May, L. Hultman, Y. Gogotsi, P. Eklund, M.W. Barsoum, Transparent conductive two-dimensional titanium carbide epitaxial thin films. Chem. Mater. 26(7), 2374 (2014)10.1021/cm500641a ↗
90. G. Deysher, C.E. Shuck, K. Hantanasirisakul, N.C. Frey, A.C. Foucher, K. Maleski, A. Sarycheva, V.B. Shenoy, E.A. Stach, B. Anasori, Y. Gogotsi, Synthesis of Mo4VAlC4 MAX phase and two-dimensional Mo4VC4 MXene with five atomic layers of transition metals. ACS Nano 14(1), 204 (2020)10.1021/acsnano.9b07708 ↗
91. A. Ostadhossein, J. Guo, F. Simeski, M. Ihme, Functionalization of 2D materials for enhancing OER/ORR catalytic activity in Li–oxygen batteries. Commun. Chem. 2(1), 1 (2019)10.1038/s42004-019-0196-2 ↗
92. O. Mashtalir, K.M. Cook, V.N. Mochalin, M. Crowe, M.W. Barsoum, Y. Gogotsi, Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media. J. Mater. Chem. A 2(35), 14334 (2014)10.1039/C4TA02638A ↗
93. P. Khakbaz, M. Moshayedi, S. Hajian, M. Soleimani, B.B. Narakathu, B.J. Bazuin, M. Pourfath, M.Z. Atashbar, Titanium carbide MXene as NH3 sensor: realistic first-principles study. J. Phys. Chem. C 123(49), 29794 (2019)10.1021/acs.jpcc.9b09823 ↗
94. J. Chen, K. Chen, D. Tong, Y. Huang, J. Zhang, J. Xue, Q. Huang, T. Chen, CO2 and temperature dual responsive “smart” MXene phases. Chem. Commun. 51(2), 314 (2015)10.1039/C4CC07220K ↗
95. Y. Dong, S.S.K. Mallineni, K. Maleski, H. Behlow, V.N. Mochalin, A.M. Rao, Y. Gogotsi, R. Podila, Metallic MXenes: a new family of materials for flexible triboelectric nanogenerators. Nano Energy 44, 103 (2018)10.1016/j.nanoen.2017.11.044 ↗
96. N. Driscoll, A.G. Richardson, K. Maleski, B. Anasori, O. Adewole, P. Lelyukh, L. Escobedo, D.K. Cullen, T.H. Lucas, Y. Gogotsi, F. Vitale, Two-Dimensional Ti3C2 MXene for high-resolution neural interfaces. ACS Nano 12(10), 10419–10429 (2018)10.1021/acsnano.8b06014 ↗
97. A. Sarycheva, T. Makaryan, K. Maleski, E. Satheeshkumar, A. Melikyan, H. Minassian, M. Yoshimura, Y. Gogotsi, Two-dimensional titanium carbide (MXene) as surface-enhanced Raman scattering substrate. J. Phys. Chem. C 121(36), 19983 (2017)10.1021/acs.jpcc.7b08180 ↗
98. P. Salles, D. Pinto, K. Hantanasirisakul, K. Maleski, C.E. Shuck, Y. Gogotsi, Electrochromic effect in titanium carbide MXene thin films produced by dip-coating. Adv. Funct. Mater. 29(17), 1809223 (2019)10.1002/adfm.201809223 ↗
99. H. Rastin, B. Zhang, A. Mazinani, K. Hassan, J. Bi, T.T. Tung, D. Losic, 3D bioprinting of cell-laden electroconductive MXene nanocomposite bioinks. Nanoscale 12(30), 16069 (2020)10.1039/D0NR02581J ↗
100. S. Pan, J. Yin, L. Yu, C. Zhang, Y. Zhu, Y. Gao, Y. Chen, 2D MXene-integrated 3D-printing scaffolds for augmented osteosarcoma phototherapy and accelerated tissue reconstruction. Adv. Sci. 7(2), 1901511 (2020)10.1002/advs.201901511 ↗