Thermodynamic descriptions of the Cu–Zn system
Source abstract
Abstract
Cu–Zn is an important binary alloy system. In the interested temperature range from 300 to 1500 K, there are eight phases, liquid, Cu, β, β′, γ, δ, ϵ, and Zn phases. The thermodynamic descriptions of the Cu–Zn system are reassessed using the CALPHAD method. A new description of liquid phase and simplified description of body-centered cubic (bcc) phase are proposed. Good agreement has been found among the calculated thermodynamic properties, phase diagram, and the experimental information.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Electronic Packaging and Soldering Technologies · Metallurgical and Alloy Processes · Thermodynamic and Structural Properties of Metals and Alloys
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (45)
Show source-provided references
1. 10.1007/BF0267196110.1007/BF02671961 ↗
2. 10.1016/0364-5916(86)90020-910.1016/0364-5916(86)90020-9 ↗
3. 39 PURE 4.4 SGTE Pure Elements (Unary) Database (Scientific Group Thermodata Europe, 1991–2006)
4. The vapour pressure of zinc in brasses.
5. The diffusion and vapour pressure in zinc in brasses.
6. Variation in the composition dependence of the activity coefficient terminal solid solution of Ag–Zn, Ag–Cd and Cu–Zn.10.1007/BF03038413 ↗
7. On the thermodynamic properties of liquid copper–zinc alloys.
8. 10.1021/j150581a03610.1021/j150581a036 ↗
9. Evaporation of metals and alloys under atmospheric pressure.
10. Mass spectrometric study of the partial characteristics of zinc in copper–zinc system.
11. Activities of ink and cadmium in liquid copper base alloys.
12. 10.1016/0001-6160(64)90146-410.1016/0001-6160(64)90146-4 ↗
13. 10.1016/0001-6160(57)90102-510.1016/0001-6160(57)90102-5 ↗
14. Vapour pressure of zinc and cadmium over their binary liquid alloys with copper, silver and gold.
15. A calorimetric study of silver–zinc and copper–zinc alloys.
16. 10.1002/zaac.1937232031110.1002/zaac.19372320311 ↗
17. 10.1039/tf965610212610.1039/tf9656102126 ↗
18. 10.1016/0001-6160(62)90171-210.1016/0001-6160(62)90171-2 ↗
19. Heat capacity and heat of formation of molten alloys.
20. 10.2320/matertrans1960.1.5410.2320/matertrans1960.1.54 ↗
21. Massalski · 1986
22. 10.1002/zaac.1929184011410.1002/zaac.19291840114 ↗
23. Fitzner · 2006
24. 10.1557/jmr.2006.022910.1557/jmr.2006.0229 ↗
25. 1987
26. 2 Campbell W. : A note on the constitution of certain tin-bearing brasses. ASTM Proc., 105, (1920).
27. 10.1039/TF958540079910.1039/TF9585400799 ↗
28. 10.1016/S0364-5916(98)00040-610.1016/S0364-5916(98)00040-6 ↗
29. An equilibrium study in the Cu–Zn system.
30. Hansen · 1936 · 652–672
31. On the thermochemistry of alloys, III—Heat of formation of binary cast alloys of iron–antimony, cobalt–antimony, nickel–antimony, cobalt–tin, nickel–tin, copper–tin and copper–zinc.
32. 10.1007/BF0325721510.1007/BF03257215 ↗
33. Vapour pressure and thermodynamic behaviour of liquid zinc–copper alloys at 1150 °C.
34. 10.1016/j.actamat.2006.01.01410.1016/j.actamat.2006.01.014 ↗
35. An electrochemical investigation of brasses.
36. Thermodynamic activity measurements using atomic absorption: copper–zinc.
37. 42ThermoCalc v. R., (Foundation of Computational Thermodynamics, Stockholm, Sweden, 2006).
38. 12 Raynor G.V. : Annotated Equilibrium Diagram Series,, No. 3 (The Institute of Metals, London, 1944)
39. Activity of zinc in molten copper and copper–gold alloys.
40. Der aufbau der kupfer–zinklegierungen.
41. 45 Atkins P.W. , de Paula J. : Atkins’ Physical Chemistry, 7th ed. (Oxford University Press, 2001)
42. The constitution of aluminum–copper–magnesium–zinc alloys. at 460 °C.
43. On the copper-rich kalchoids.
44. 43 Pandat, CompuTherm LLC, 437 S. Yellowstone Dr., Suite 217, Madison, WI 53719
45. Constitution of brasses below 500 °C.