Mechanical Properties of Intermetallic Compounds in the Au–Sn System

The mechanical properties of intermetallic compounds in the Au–Sn system were investigated by nanoindentation. Measurements of hardness and elastic modulus were obtained for all of the confirmed room-temperature intermetallics in this system as well as the β phase (8 at.% Sn) and AuSn₄. Overall, it was found that the Au–Sn compounds have lower hardness and stiffness than common Cu–Sn compounds found in solder joints. This finding is in contrast to common knowledge of “Au embrittlement” due to the formation of either AuSn₄ or (Au,Ni)Sn₄ intermetallic compounds. This difference in understanding of mechanical properties of these phases and the resulting joint strength is discussed in terms of reliability and possible failure mechanisms related to interface strength or microstructural effects. Indentation creep measurements performed on Au₅Sn, Au–Sn eutectic (29 at.% Sn) and AuSn indicate that these alloys are significantly more creep resistant than common soft solders, in keeping with typical observations of actual joint performance.