Additive Manufacturing and size-dependent mechanical properties of three-dimensional microarchitected, high-temperature ceramic metamaterials

3D microarchitected metamaterials exhibit unique, desirable properties influenced by their small length scales and architected layout, unachievable by their solid counterparts and random cellular configurations. However, few of them can be used in high-temperature applications, which could benefit significantly from their ultra-lightweight, ultrastiff properties. Existing high-temperature ceramic materials are often heavy and difficult to process into complex, microscale features. Inspired by this limitation, we fabricated polymer-derived ceramic metamaterials with controlled solid strut size varying from 10-µm scale to a few millimeters with relative densities ranging from as low as 1 to 22%. We found that these high-temperature architected ceramics of identical 3D topologies exhibit size-dependent strength influenced by both strut diameter and strut length. Weibull theory is utilized to map this dependency with varying single strut volumes. These observations demonstrate the structural benefits of increasing feature resolution in additive manufacturing of ceramic materials. Through capitalizing upon the reduction of unit strut volumes within the architecture, high-temperature ceramics could achieve high specific strength with only fraction of the weight of their solid counterparts.