journal article·2024-05

Experimental Analysis of Ultra-High Strength NiTiHfPd Shape Memory Alloys

Emre Acar, Soheil Saedi, Haluk E. Karaca

Publisher page

Abstract

Ultra-high strength of NiTiHfPd alloys have been promising for specific application areas of SMAs. Thus, the main objective of this study is to further understand the high strength behavior of the alloys through experimental and theoretical studies. Shape memory response of an ultra-high strength Ni45.3Ti29.7Hf20Pd5 alloy was systematically investigated after aging at 550 °C for 5 h via constant-stress temperature cycling and constant-temperature stress cycling experiments. Shape memory behavior under a wide range of compressive stress levels from 300 to 1200 MPa was reported before and after stress cycling of 5000 times. The alloys showed a reversible strain of 1.3% against an ultra-high stress of 2 GPa. It is concluded that the combination of high strength and temperature capability mainly stems from high chemical complexity in addition to aging and will be quite advantageous in practical applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Shape Memory Alloy Transformations · Titanium Alloys Microstructure and Properties · High Entropy Alloys Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (31)

Show source-provided references
1. K. Otsuka and X. Ren, Physical Metallurgy of Ti-Ni-Based Shape Memory Alloys, Prog. Mater. Sci., 2005, 50, p 511–678.10.1016/j.pmatsci.2004.10.001 ↗
2. J. Ma, I. Karaman, and R.D. Noebe, High Temperature Shape Memory Alloys, Int. Mater. Rev., 2010, 55, p 257–315.10.1179/095066010X12646898728363 ↗
3. H.E. Karaca, S.M. Saghaian, H. Tobe, E. Acar, B. Basaran, M. Nagasako, R. Kainuma, and R.D. Noebe, Diffusionless Phase Transformation Characteristics of Mn75.7Pt24.3, J. Alloys Compd., 2014, 589, p 412–415.10.1016/j.jallcom.2013.11.174 ↗
4. D.N. AbuJudom, P.E. Thoma, M. Kao, and D.R. Angst, High Transformation Temperature Shape Memory Alloy, United States Patents, Alexandria, 1990.
5. H.E. Karaca, E. Acar, H. Tobe, and S.M. Saghaian, NiTiHf-Based Shape Memory Alloys, Mater. Sci. Technol., 2014, 30, p 1530–1544.10.1179/1743284714Y.0000000598 ↗
6. X.L. Meng, W. Cai, Y.F. Zheng, and L.C. Zhao, Phase Transformation and Precipitation in aged Ti-Ni-Hf High-Temperature Shape Memory Alloys, Mater. Sci. Eng. A, 2006, 438–440, p 666–670.10.1016/j.msea.2006.01.099 ↗
7. X.L. Meng, W. Cai, F. Chen, and L.C. Zhao, Effect of Aging on Martensitic Transformation and Microstructure in Ni-rich TiNiHf Shape Memory Alloy, Scr. Mater., 2006, 54, p 1599–1604.10.1016/j.scriptamat.2006.01.017 ↗
8. S.M. Saghaian, H.E. Karaca, H. Tobe, A.S. Turabi, S. Saedi, S.E. Saghaian, Y.I. Chumlyakov, and R.D. Noebe, High Strength NiTiHf Shape Memory Alloys with Tailorable Properties, Acta Mater., 2017, 134, p 211–220.10.1016/j.actamat.2017.05.065 ↗
9. S.M. Saghaian, H.E. Karaca, H. Tobe, J. Pons, R. Santamarta, Y.I. Chumlyakov, and R.D. Noebe, Effects of Ni Content on the Shape Memory Properties and Microstructure of Ni-Rich NiTi-20Hf Alloys, Smart Mater. Struct., 2016, 25, p 095029.10.1088/0964-1726/25/9/095029 ↗
10. E. Acar, Dynamic Mechanical Response of a Ni45.7Ti29.3Hf20Pd5 Alloy, Mater. Sci. Eng. A, 2015, 633, p 169–175.10.1016/j.msea.2015.03.023 ↗
11. E. Acar, H.E. Karaca, H. Tobe, R.D. Noebe, and Y.I. Chumlyakov, Orientation Dependence of the Shape Memory Properties in Aged Ni45.3Ti29.7Hf20Pd5 Single Crystals, Intermetallics, 2014, 54, p 60–68.10.1016/j.intermet.2014.04.011 ↗
12. E. Acar, O.E. Ozbulut, and H.E. Karaca, Experimental Investigation and Modeling of the Loading Rate and Temperature Dependent Superelastic Response of a High Performance Shape-Memory Alloy, Smart Mater. Struct., 2015, 24, p 075020.10.1088/0964-1726/24/7/075020 ↗
13. I. Kaya, H. Tobe, H.E. Karaca, E. Acar, and Y.I. Chumlyakov, Shape Memory Behavior of [111]-Oriented NiTi Single Crystals After Stress-Assisted Aging, Acta Metall. Sin. Eng. Lett., 2016, 29, p 282–286. https://doi.org/10.1007/s40195-016-0386-110.1007/s40195-016-0386-1 ↗
14. H.E. Karaca, E. Acar, B. Basaran, R.D. Noebe, and Y.I. Chumlyakov, Superelastic Response and Damping Capacity Of Ultrahigh-Strength [111]-Oriented NiTiHfPd Single Crystals, Scr. Mater., 2012, 67, p 447–450.10.1016/j.scriptamat.2012.05.044 ↗
15. H.E. Karaca, E. Acar, G.S. Ded, B. Basaran, H. Tobe, R.D. Noebe, G. Bigelow, and Y.I. Chumlyakov, Shape Memory Behavior of High Strength NiTiHfPd Polycrystalline Alloys, Acta Mater., 2013, 61, p 5036–5049.10.1016/j.actamat.2013.04.039 ↗
16. E. Acar, M. Çalışkan, and H.E. Karaca, Differential Scanning Calorimetry Response of Aged NiTiHfPd Shape Memory Alloys, Appl. Phys. A, 2019, 125, p 239.10.1007/s00339-019-2543-7 ↗
17. E. Acar, H. Tobe, H.E. Karaca, and Y.I. Chumlyakov, On the Stress-Assisted Aging in NiTiHfPd Single Crystal Shape Memory Alloys, Mater. Sci. Eng. A, 2018, 725, p 51–56.10.1016/j.msea.2018.03.125 ↗
18. P. Wollants, J.R. Roos, and L. Delaey, Thermally- and Stress-Induced Thermoelastic Martensitic Transformations in the Reference Frame of Equilibrium Thermodynamics, Prog. Mater. Sci., 1993, 37, p 227–288.10.1016/0079-6425(93)90005-6 ↗
19. S. Miyazaki, Y. Igo, and K. Otsuka, Effect of Thermal Cycling on the Transformation Temperatures of TiNi Alloys, Acta Metall., 1986, 34, p 2045–2051.10.1016/0001-6160(86)90263-4 ↗
20. Z. Xie, Y. Liu, and J. Van Humbeeck, Microstructure of NiTi Shape Memory Alloy Due to Tension–Compression Cyclic Deformation, Acta Mater., 1998, 46, p 1989–2000.10.1016/S1359-6454(97)00379-0 ↗
21. I. Kaya, H. Tobe, H.E. Karaca, B. Basaran, M. Nagasako, R. Kainuma, and Y.I. Chumlyakov, Effects of Aging on the Shape Memory and Superelasticity Behavior of Ultra-High Strength Ni54Ti46 Alloys Under Compression, Mater. Sci. Eng. A, 2016, 678, p 93–100.10.1016/j.msea.2016.09.078 ↗
22. J. Ma, I. Karaman, H.J. Maier, and Y.I. Chumlyakov, Superelastic Cycling and Room Temperature Recovery of Ti74Nb26 Shape Memory Alloy, Acta Mater., 2010, 58, p 2216–2224.10.1016/j.actamat.2009.12.009 ↗
23. N. Jost and E. Hornbogen, Influence of Prior Plastic Deformation on the Thermal-Martensitic-Transformation in an Fe-Ni-Al Alloy, J. Mater. Sci. Lett., 1987, 6, p 491–494.10.1007/BF01756809 ↗
24. H. Sehitoglu, R. Hamilton, D. Canadinc, X.Y. Zhang, K. Gall, I. Karaman, Y.I. Chumlyakov, and H.J. Maier, Detwinning in NiTi Alloys, Metall. Mater. Trans. A, 2003, 34, p 5–13.10.1007/s11661-003-0203-0 ↗
25. I. Kaya, H. Tobe, H.E. Karaca, M. Nagasako, R. Kainuma, and Y.I. Chumlyakov, Positive and Negative Two-Way Shape Memory Effect in [111]-Oriented Ni51Ti49 Single Crystals, Mater. Sci. Eng. A, 2015, 639, p 42–53.10.1016/j.msea.2015.04.087 ↗
26. A. Nagasawa, K. Enami, Y. Ishino, Y. Abe, and S. Nenno, Reversible Shape Memory Effect, Scr. Metall., 1974, 8, p 1055–1060.10.1016/S0036-9748(74)80003-7 ↗
27. J. Perkins and R.O. Sponholz, Stress-Induced Martensitic Transformation Cycling and Two-Way Shape Memory Training in Cu-Zn-Al Alloys, Metall. Trans. A, 1984, 15, p 313–321.10.1007/BF02645117 ↗
28. H.E. Karaca, E. Acar, G.S. Ded, S.M. Saghaian, B. Basaran, H. Tobe, M. Kok, H.J. Maier, R.D. Noebe, and Y.I. Chumlyakov, Microstructure and Transformation Related Behaviors of a Ni45.3Ti297Hf20Cu5 High Temperature Shape Memory Alloy, Mater. Sci. Eng. A, 2015, 627, p 82–94.10.1016/j.msea.2014.12.111 ↗
29. H.Y. Kim, T. Jinguu, T. Nam, and S. Miyazaki, Cold Workability and Shape Memory Properties of Novel Ti-Ni-Hf-Nb High-Temperature Shape Memory Alloys, Scr. Mater., 2011, 65, p 846–849.10.1016/j.scriptamat.2011.07.049 ↗
30. O. Benafan, D.J. Gaydosh, R.D. Noebe, S. Qiu, and R. Vaidyanathan, In Situ Neutron Diffraction Study of NiTi-21Pt High-Temperature Shape Memory Alloys, Shape Mem. Superelast., 2016, 2, p 337–346.10.1007/s40830-016-0095-7 ↗
31. G.S. Bigelow, S.A. Padula, A. Garg, D. Gaydosh, and R.D. Noebe, Characterization of Ternary NiTiPd High-Temperature Shape-Memory Alloys under Load-Biased Thermal Cycling, Metall. Mater. Trans. A, 2010, 41, p 3065–3079.10.1007/s11661-010-0365-5 ↗