journal article·2024-06

Deformation Structures and Strengthening Mechanisms Associated with κ-Carbides Precipitation in an Austenitic-Based Low-Density Steel

Qi Zhang, Xiaohui Shi, Xuejiao Wang, Zheng Zhang, Junwei Qiao

Publisher page

Abstract

To control the precipitation sites of carbides, the cold rolling, annealing, and aging processes were employed to process Fe-26Mn-10.2Al-0.98C-0.15 V (wt.%) steels with duplex structure. After aging, the alloy achieved a good combination of strength and plasticity, which had a yield strength of 1120 MPa, tensile strength of 1285 MPa, and elongation of 17%. The precipitation strengthening of the κ-carbides shows a significant contribution to the high yield strength of this alloy. The strengthening models were employed to calculate the precipitation strengthening from coherent κ-carbides, and show good prediction performance. The increase in strength slows down with increasing aging time, which is influenced by the critical grain size of the precipitated particles and the antiphase boundary energy (({gamma }_{mathrm{APB}})). Furthermore, the deformation mechanism of this alloy is influenced by the high SFE and the softening effect of the intragranular κ-carbide sliding surface. The analyses of the deformed structure revealed that the plastic deformation was dominated by the planar slip, resulting in the formation of the Taylor lattice, a special dislocation substructure.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Microstructure and Mechanical Properties of Steels · Metal Alloys Wear and Properties · High Temperature Alloys and Creep

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (59)

Show source-provided references
1. P.-C. Chen, C.-G. Chao, and T.-F. Liu, A Novel High-Strength, High-Ductility and High-Corrosion-Resistance FeAlMnC Low-Density Alloy, Scr. Mater., 2013, 68(6), p 380-383.10.1016/j.scriptamat.2012.10.034 ↗
2. L.L. Wei, G.H. Gao, J. Kim, R.D.K. Misra, C.G. Yang, and X.J. Jin, Ultrahigh Strength-High Ductility 1 GPa Low Density Austenitic Steel with Ordered Precipitation Strengthening Phase and Dynamic Slip Band Refinement, Mater Sci Eng A, 2022, 838, p 142829.10.1016/j.msea.2022.142829 ↗
3. J. Kim, S.-J. Lee, and B.C. De Cooman, Effect of Al on the Stacking Fault Energy of Fe-18Mn-06C Twinning-Induced Plasticity, Scr. Mater., 2011, 65(4), p 363-366.10.1016/j.scriptamat.2011.05.014 ↗
4. S.C. Cao, L. Zhu, J. Liu, G. Wu, W. Huang, and J. Lu, Light-Weight Isometric-Phase Steels with Superior Strength-Hardness-Ductility Combination, Scr. Mater., 2018, 154, p 230-235.10.1016/j.scriptamat.2018.06.012 ↗
5. T. Wegener, C. Haase, A. Liehr, and T. Niendorf, On the Influence of ϰ-Carbides on the Low-Cycle Fatigue Behavior of High-Mn Light-Weight Steels, Int J Fatigue, 2021, 150, p 106327.10.1016/j.ijfatigue.2021.106327 ↗
6. W. Peng, J. Wang, H. Zhang, X. Hong, Z. Wu, Y. Xu, J. Li, and X. Xiao, Insights into the Role of Grain Refinement on High-Temperature initial Oxidation Phase Transformation and Oxides Evolution in High Aluminium Fe-Mn-Al-C Duplex Lightweight Steel, Corros. Sci., 2017, 126, p 197-207.10.1016/j.corsci.2017.07.002 ↗
7. W. Peng, Z. Wu, Y. Xu, Q. Ran, W. Xu, J. Li, and X. Xiao, Internal Oxidation Behaviour of Fe-Mn-Al-C Duplex Light-Weight Steels with Good Combination of Strength and Ductility, Corros. Sci., 2017, 120, p 148-157.10.1016/j.corsci.2017.03.005 ↗
8. S.H. Kim, H. Kim, and N.J. Kim, Brittle Intermetallic Compound Makes Ultrastrong Low-Density Steel with Large Ductility, Nature, 2015, 518(7537), p 77-79.10.1038/nature14144 ↗
9. M.X. Yang, F.P. Yuan, Q.G. Xie, Y.D. Wang, E. Ma, and X.L. Wu, Strain Hardening in Fe-16Mn-10Al-0.86C-5Ni High Specific Strength Steel, Acta Mater., 2016, 109, p 213-222.10.1016/j.actamat.2016.02.044 ↗
10. J.H. Hwang, T.T.T. Trang, O. Lee, G. Park, A. Zargaran, and N.J. Kim, Improvement of Strength–Ductility Balance of B2-Strengthened Lightweight Steel, Acta Mater., 2020, 191, p 1-12.10.1016/j.actamat.2020.03.022 ↗
11. H. Song, J. Yoo, S.-H. Kim, S.S. Sohn, M. Koo, N.J. Kim, and S. Lee, Novel Ultra-High-Strength Cu-Containing Medium-Mn Duplex Lightweight Steels, Acta Mater., 2017, 135, p 215-225.10.1016/j.actamat.2017.06.035 ↗
12. Z. Wang, W. Lu, H. Zhao, J. He, K. Wang, B. Zhou, D. Ponge, D. Raabe, and Z. Li, Formation Mechanism of κ-Carbides and Deformation Behavior in Si-Alloyed FeMnAlC Lightweight Steels, Acta Mater., 2020, 198, p 258-270.10.1016/j.actamat.2020.08.003 ↗
13. J. Moon, H.-Y. Ha, S.-J. Park, T.-H. Lee, J.H. Jang, C.-H. Lee, H.N. Han, and H.-U. Hong, Effect of Mo and Cr Additions on the Microstructure, Mechanical Properties and Pitting Corrosion Resistance of Austenitic Fe-30Mn-10.5Al-1.1C Lightweight Steels, J. Alloys Compd., 2019, 775, p 1136-1146.10.1016/j.jallcom.2018.10.253 ↗
14. M.J. Yao, E. Welsch, D. Ponge, S.M.H. Haghighat, S. Sandlöbes, P. Choi, M. Herbig, I. Bleskov, T. Hickel, M. Lipinska-Chwalek, P. Shanthraj, C. Scheu, S. Zaefferer, B. Gault, and D. Raabe, Strengthening and Strain Hardening Mechanisms in a Precipitation-Hardened high-Mn Lightweight Steel, Acta Mater., 2017, 140, p 258-273.10.1016/j.actamat.2017.08.049 ↗
15. H.R. Abedi, A. Zarei Hanzaki, N. Nemati, and D.-E. Kim, Trading off Between Dynamic Strain Aging and Substructure Evolution in κ-Carbide-Free Lightweight Steel at Room Temperature, Scr. Mater., 2018, 157, p 110-114.10.1016/j.scriptamat.2018.07.044 ↗
16. K. Choi, C.-H. Seo, H. Lee, S.K. Kim, J.H. Kwak, K.G. Chin, K.-T. Park, and N.J. Kim, Effect of Aging on the Microstructure and Deformation Behavior of Austenite Base Lightweight Fe-28Mn-9Al-08C Steel, Scr Mater., 2010, 63(10), p 1028-1031.10.1016/j.scriptamat.2010.07.036 ↗
17. P. Chen, X. Li, and H. Yi, The κ-Carbides in Low-Density Fe-Mn-Al-C Steels: A Review on Their Structure, Precipitation and Deformation Mechanism, Metals, 2020, 10(8), p 1021.10.3390/met10081021 ↗
18. I. Gutierrez-Urrutia and D. Raabe, Influence of Al Content and Precipitation State on the Mechanical Behavior of Austenitic High-Mn Low-Density Steels, Scr. Mater., 2013, 68(6), p 343-347.10.1016/j.scriptamat.2012.08.038 ↗
19. J. Jeong, C.-Y. Lee, I.-J. Park, and Y.-K. Lee, Isothermal Precipitation Behavior of κ-Carbide in the Fe-9Mn-6Al-0.15C Lightweight Steel with a Multiphase Microstructure, J. Alloys Compd., 2013, 574, p 299-304.10.1016/j.jallcom.2013.05.138 ↗
20. L. Zhang, R. Song, C. Zhao, F. Yang, Y. Xu, and S. Peng, Evolution of the Microstructure and Mechanical Properties of an Austenite-Ferrite Fe-Mn-Al-C Steel, Mater. Sci. Eng. A, 2015, 643, p 183-193.10.1016/j.msea.2015.07.043 ↗
21. S.S. Sohn, H. Song, B.-C. Suh, J.-H. Kwak, B.-J. Lee, N.J. Kim, and S. Lee, Novel Ultra-High-Strength (Ferrite + Austenite) Duplex Lightweight Steels Achieved by Fine Dislocation Substructures (Taylor lattices), Grain Refinement, and Partial Recrystallization, Acta Mater., 2015, 96, p 301-310.10.1016/j.actamat.2015.06.024 ↗
22. M.C. Ha, J.-M. Koo, J.-K. Lee, S.W. Hwang, and K.-T. Park, Tensile Deformation of a Low Density Fe-27Mn-12Al-0.8C Duplex Steel in Association with Ordered Phases at Ambient Temperature, Mater. Sci. Eng. A, 2013, 586, p 276-283.10.1016/j.msea.2013.07.094 ↗
23. S.W. Hwang, J.H. Ji, E.G. Lee, and K.-T. Park, Tensile Deformation of a Duplex Fe-20Mn-9Al-0.6C Steel Having the Reduced Specific Weight, Mater. Sci. Eng. A, 2011, 528(15), p 5196-5203.10.1016/j.msea.2011.03.045 ↗
24. J. Zhang, D. Raabe, and C.C. Tasan, Designing Duplex, Ultrafine-Grained Fe-Mn-Al-C Steels by Tuning Phase Transformation and Recrystallization Kinetics, Acta Mater., 2017, 141, p 374-387.10.1016/j.actamat.2017.09.026 ↗
25. J. Moon, S.-J. Park, J.H. Jang, T.-H. Lee, C.-H. Lee, H.-U. Hong, H.N. Han, J. Lee, B.H. Lee, and C. Lee, Investigations of the Microstructure Evolution and Tensile Deformation Behavior of Austenitic Fe-Mn-Al-C Lightweight Steels and the Effect of Mo Addition, Acta Mater., 2018, 147, p 226-235.10.1016/j.actamat.2018.01.051 ↗
26. M.J. Yao, P. Dey, J.B. Seol, P. Choi, M. Herbig, R.K.W. Marceau, T. Hickel, J. Neugebauer, and D. Raabe, Combined Atom Probe Tomography and Density Functional Theory Investigation of the Al off-Stoichiometry of κ-Carbides in an Austenitic Fe-Mn-Al-C Low Density Steel, Acta Mater., 2016, 106, p 229-238.10.1016/j.actamat.2016.01.007 ↗
27. E. Welsch, D. Ponge, S.M. Hafez Haghighat, S. Sandlöbes, P. Choi, M. Herbig, S. Zaefferer, and D. Raabe, Strain Hardening by Dynamic Slip Band Refinement in a High-Mn Lightweight Steel, Acta Mater, 2016, 116, p 188-199.10.1016/j.actamat.2016.06.037 ↗
28. C. Haase, C. Zehnder, T. Ingendahl, A. Bikar, F. Tang, B. Hallstedt, W. Hu, W. Bleck, and D.A. Molodov, On the Deformation Behavior of κ-Carbide-Free and κ-Carbide-Containing High-Mn Light-Weight Steel, Acta Mater., 2017, 122, p 332-343.10.1016/j.actamat.2016.10.006 ↗
29. R.S. Ulrich Bohnenkamp, Evaluation of the Density of Steels, Steel Res, 2000, 71, p 88-93.10.1002/srin.200005695 ↗
30. S. Chen, R. Rana, A. Haldar, and R.K. Ray, Current State of Fe-Mn-Al-C Low Density Steels, Prog. Mater Sci., 2017, 89, p 345-391.10.1016/j.pmatsci.2017.05.002 ↗
31. Z.Q. Wu, H. Ding, H.Y. Li, M.L. Huang, and F.R. Cao, Microstructural Evolution and Strain Hardening Behavior During Plastic Deformation of Fe-12Mn-8Al-0.8C Steel, Mater Sci Eng A, 2013, 584, p 150-155.10.1016/j.msea.2013.07.023 ↗
32. W.J. Lu, X.F. Zhang, and R.S. Qin, Structure and Properties of κ-Carbides in Duplex Lightweight Steels, Ironmak. Steelmak., 2015, 42(8), p 626-631.10.1179/1743281215Y.0000000007 ↗
33. K. Lee, S.-J. Park, J. Lee, J. Moon, J.-Y. Kang, D.-I. Kim, J.-Y. Suh, and H.N. Han, Effect of Aging Treatment on Microstructure and Intrinsic Mechanical Behavior of Fe-314Mn-11.4Al-0.89C Lightweight Steel, J. Alloys Compd., 2016, 656, p 805-811.10.1016/j.jallcom.2015.10.016 ↗
34. Y.-C. Lin, Structures and Superparamagnetic Properties of Overaged Fe±Al±Mn±c Alloys, Acta Metall., 1999, 47, p 4665-4681.
35. W.-C. Cheng, C.-Y. Cheng, C.-W. Hsu, and D.E. Laughlin, Phase Transformation of the L1 2 Phase to Kappa-Carbide After Spinodal Decomposition and Ordering in an Fe-C-Mn-Al Austenitic Steel, Mater Sci Eng A, 2015, 642, p 128-135.10.1016/j.msea.2015.06.096 ↗
36. P. Ren, X.P. Chen, L. Mei, Y.Y. Nie, W.Q. Cao, and Q. Liu, Intragranular Brittle Precipitates Improve Strain Hardening Capability of Fe-30Mn-11Al-1.2C Low-Density Steel, Mater. Sci. Eng. A, 2020, 775, p 138984.10.1016/j.msea.2020.138984 ↗
37. B. Du, Z. Hu, L. Sheng, C. Cui, J. Yang, Y. Zheng, and X. Sun, Tensile, Creep Behavior and Microstructure Evolution of an As-Cast Ni-Based K417G Polycrystalline Superalloy, J. Mater. Sci. Technol., 2018, 34(10), p 1805-1816.10.1016/j.jmst.2018.02.007 ↗
38. J. Wang, L. Zhou, L. Sheng, and J. Guo, The Microstructure Evolution and its Effect on the Mechanical Properties of a Hot-Corrosion Resistant Ni-Based Superalloy During Long-Term Thermal Exposure, Mater. Des., 2012, 39, p 55-62.10.1016/j.matdes.2012.02.020 ↗
39. J. Moon, S.-J. Park, J.H. Jang, T.-H. Lee, C.-H. Lee, H.-U. Hong, D.-W. Suh, S.H. Kim, H.N. Han, and B.H. Lee, Atomistic Investigations of κ-Carbide Precipitation in Austenitic Fe-Mn-Al-C Lightweight Steels and the Effect of Mo Addition, Scr. Mater., 2017, 127, p 97-101.10.1016/j.scriptamat.2016.08.036 ↗
40. Y.-U. Heo, A Strategy for Phase Identification of Precipitates in High Al-containing Austenitic and Ferritic Steels Using Electron Diffraction, Appl. Microsc., 2014, 44(4), p 144-149.10.9729/AM.2014.44.4.144 ↗
41. K.-T. Park, S.W. Hwang, C.Y. Son, and J.-K. Lee, Effects of Heat Treatment on Microstructure and Tensile Properties of a Fe-27Mn-12Al-0.8C Low-Density Steel, JOM, 2014, 66(9), p 1828-1836.10.1007/s11837-014-1064-2 ↗
42. C. Kim, M. Terner, H.-U. Hong, C.-H. Lee, S.-J. Park, and J. Moon, Influence of Inter/intra-Granular κ-Carbides on the Deformation Mechanism in Lightweight Fe-20Mn-11.5Al-1.2C Steel, Mater Charact, 2020, 161, p 110142.10.1016/j.matchar.2020.110142 ↗
43. X.P. Chen, Y.P. Xu, P. Ren, W.J. Li, W.Q. Cao, and Q. Liu, Aging Hardening Response and β-Mn Transformation Behavior of High Carbon High Manganese Austenitic Low-Density Fe-30Mn-10Al-2C steel, Mater. Sci. Eng. A, 2017, 703, p 167-172.10.1016/j.msea.2017.07.055 ↗
44. W.J. Lu, X.F. Zhang, and R.S. Qin, κ-Carbide Hardening in a Low-Density High-Al High-Mn Multiphase Steel, Mater. Lett., 2015, 138, p 96-99.10.1016/j.matlet.2014.09.104 ↗
45. B.N. Du, Z.Y. Hu, L.Y. Sheng, D.K. Xu, Y.X. Qiao, B.J. Wang, J. Wang, Y.F. Zheng, and T.F. Xi, Microstructural Characteristics and Mechanical Properties of the Hot Extruded Mg-Zn-Y-Nd Alloys, J. Mater. Sci. Technol., 2021, 60, p 44-55.10.1016/j.jmst.2020.05.021 ↗
46. P.J. Gregson, and H.M. Flower, Microstructural Control of Toughness in Aluminium-Lithium Alloys, Acta Metallurgica, 1985, 33(3), p 527-537.10.1016/0001-6160(85)90095-1 ↗
47. C.W. Kim, M. Terner, J.H. Lee, H.U. Hong, J. Moon, S.J. Park, J.H. Jang, C.H. Lee, B.H. Lee, and Y.J. Lee, Partitioning of C into κ-Carbides by Si Addition and its Effect on the Initial Deformation Mechanism of Fe-Mn-Al-C Lightweight Steels, J. Alloys Compd., 2019, 775, p 554-564.10.1016/j.jallcom.2018.10.104 ↗
48. Z. Wang, W. Lu, F. An, M. Song, D. Ponge, D. Raabe, and Z. Li, High Stress Twinning in a Compositionally Complex Steel of Very High Stacking Fault Energy, Nat Commun, 2022, 13(1), p 3598.10.1038/s41467-022-31315-2 ↗
49. S. Allain, J.P. Chateau, O. Bouaziz, S. Migot, and N. Guelton, Correlations Between the Calculated Stacking Fault Energy and the Plasticity Mechanisms in Fe-Mn-C Alloys, Mater. Sci. Eng. A, 2004, 387-389, p 158-162.10.1016/j.msea.2004.01.059 ↗
50. W.G. Nöhring and W.A. Curtin, Dislocation Cross-Slip in FCC Solid Solution Alloys, Acta Mater., 2017, 128, p 135-148.10.1016/j.actamat.2017.02.027 ↗
51. Y. Feng, R. Song, Y. Wang, and Z. Pei, The Synergistic Effect of Deformation Twins and Polycrystalline Structure on Strain Hardening in a High-SFE Fe-Mn-Al-C Austenitic cast Steel in Compression, Mater. Lett, 2020, 272, p 127814.10.1016/j.matlet.2020.127814 ↗
52. M.I. Latypov, S. Shin, B.C. De Cooman, and H.S. Kim, Micromechanical Finite Element Analysis of Strain Partitioning in Multiphase Medium Manganese TWIP+TRIP Steel, Acta Mater., 2016, 108, p 219-228.10.1016/j.actamat.2016.02.001 ↗
53. M. Niu, G. Zhou, W. Wang, M.B. Shahzad, Y. Shan, and K. Yang, Precipitate Evolution and Strengthening Behavior During Aging Process in a 2.5 GPa Grade Maraging Steel, Acta Mater, 2019, 179, p 296-307.10.1016/j.actamat.2019.08.042 ↗
54. J. Lee, S. Park, H. Kim, S.-J. Park, K. Lee, M.-Y. Kim, P.P. Madakashira, and H.N. Han, Simulation of κ-Carbide Precipitation Kinetics in Aged Low-Density Fe-Mn-Al-C Steels and Its Effects on Strengthening, Met. Mater. Int., 2018, 24(4), p 702-710.10.1007/s12540-018-0089-4 ↗
55. D. Liu, H. Ding, D. Han, M. Cai, and Y.-K. Lee, Microstructural Evolution and Tensile Properties of Fe-11Mn-10Al-12.C Medium-Mn Lightweight Steel, Mater. Sci. Eng. A, 2020, 797, p 140256.10.1016/j.msea.2020.140256 ↗
56. C.W. Kim, S.I. Kwon, B.H. Lee, J.O. Moon, S.J. Park, J.H. Lee, and H.U. Hong, Atomistic Study of Nano-Sized κ-Carbide Formation and its Interaction with Dislocations in a Cast Si Added FeMnAlC Lightweight Steel, Mater. Sci. Eng. A, 2016, 673, p 108-113.10.1016/j.msea.2016.07.029 ↗
57. J. Zhang, Y. Liu, C. Hu, Y. Jiang, A. Addad, G. Ji, C. Song, and Q. Zhai, The Effect of Cr Content on Intragranular κ-Carbide Precipitation in Fe-Mn-Al-(Cr)-C Low-Density Steels: A Multiscale Investigation, Mater. Charact., 2022, 186, p 111801.10.1016/j.matchar.2022.111801 ↗
58. D. Liu, H. Ding, D. Han, and M. Cai, Improvement of the Yield Strength of Fe-11Mn-xAl-yC Medium-Mn Lightweight Steels by Tuning Partial Recrystallization and Intra-Granular κ-Carbide Strengthening, Mater. Sci. Eng. A, 2022, 833, p 142553.10.1016/j.msea.2021.142553 ↗
59. S.-W. Park, J.Y. Park, K.M. Cho, J.H. Jang, S.-J. Park, J. Moon, T.-H. Lee, and J.-H. Shin, Effect of Mn and C on Age Hardening of Fe-Mn-Al-C Lightweight Steels, Met. Mater. Int., 2018, 25(3), p 683-696.10.1007/s12540-018-00230-x ↗