journal article·2023-11Open access

The Effect of Ta, Mg, and Zn Content on the Properties of Ti-Ta-Mg and Ti-Ta-Zn Alloys Prepared by Mechanical Alloying and Hot Pressing

Mikołaj Kozłowski, Grzegorz Adamek, Piotr Siwak, Jaroslaw Jakubowicz

Abstract

Abstract The main goal of this study was to achieve poreless titanium alloys with nanocrystalline structure. To this end, the influence of Ta, Mg and Zn content on the properties of Ti alloys was investigated. At first, nanocrystalline powders of TixTayMg and TixTayZn, where x = (30 and 40 wt.%) and y = (3 and 5 wt.%), were prepared using the mechanical alloying process at room temperature. Then, hot-pressing at 750 °C under vacuum was applied for 10 s to consolidate powders. The structure, microstructure, chemical composition, mechanical properties, corrosion resistance, wettability and MTT assay have been investigated. Alloys with Mg were allowed to undergo a shorter mechanical alloying process, achieve greater grain refinement after consolidation and improve mechanical properties. In all cases with increasing amounts of additives in titanium, more Ti-β phase was available. Furthermore, with increasing elements content, hot-pressed alloys consisting of Mg tended to have a more hydrophobic surface. According to the MTT test, all new alloys show non-toxic properties. Among all alloys tested in this study, Ti40Ta5Mg had the most interesting properties for biomedical applications, the highest content of Ti-β phase (81.3%), lowest porosity (0.07%), lowest Young modulus (102.1 GPa) and the lowest surface free energy (38.45 mN/m).
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Research context

OpenAlex topics: Titanium Alloys Microstructure and Properties · Magnesium Alloys: Properties and Applications · Metal and Thin Film Mechanics

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References (78)

Show source-provided references
1. M. Abdel-Hady Gepreel and M. Niinomi, Biocompatibility of Ti-Alloys for Long-Term Implantation, J. Mech. Behav. Biomed. Mater., 2013, 20, p 407–415. https://doi.org/10.1016/j.jmbbm.2012.11.01410.1016/j.jmbbm.2012.11.014 ↗
2. A. Sidambe, Biocompatibility of Advanced Manufactured Titanium Implants—A Review, Materials, 2014, 7(12), p 8168–8188. https://doi.org/10.3390/ma712816810.3390/ma7128168 ↗
3. P.R. Walker, J. LeBlanc, and M. Sikorska, Effects of Aluminum and Other Cations on the Structure of Brain and Liver Chromatin, Biochemistry, 1989, 28(9), p 3911–3915. https://doi.org/10.1021/bi00435a04310.1021/bi00435a043 ↗
4. S. Rao, T. Ushida, T. Tateishi, Y. Okazaki, and S. Asao, Effect of Ti, Al, and V Ions on the Relative Growth Rate of Fibroblasts (L929) and Osteoblasts (MC3T3-E1) Cells, Biomed. Mater. Eng., 1996, 6(2), p 79–86. https://doi.org/10.3233/BME-1996-620210.3233/BME-1996-6202 ↗
5. Y.-Y. Chang, H.-L. Huang, H.-J. Chen, C.-H. Lai, and C.-Y. Wen, Antibacterial Properties and Cytocompatibility of Tantalum Oxide Coatings, Surf. Coat. Technol., 2014, 259(PB), p 193–198. https://doi.org/10.1016/j.surfcoat.2014.03.06110.1016/j.surfcoat.2014.03.061 ↗
6. C. Yang, J. Li, C. Zhu, Q. Zhang, J. Yu, J. Wang, Q. Wang, J. Tang, H. Zhou, and H. Shen, Advanced Antibacterial Activity of Biocompatible Tantalum Nanofilm via Enhanced Local Innate Immunity, Acta Biomater., 2019, 89, p 403–418. https://doi.org/10.1016/j.actbio.2019.03.02710.1016/j.actbio.2019.03.027 ↗
7. Y.-L. Zhou, M. Niinomi, T. Akahori, M. Nakai, and H. Fukui, Comparison of Various Properties between Titanium-Tantalum Alloy and Pure Titanium for Biomedical Applications, Mater. Trans., 2007, 48(3), p 380–384. https://doi.org/10.2320/matertrans.48.38010.2320/matertrans.48.380 ↗
8. P.J. Little, R. Bhattacharya, A.E. Moreyra, and I.L. Korichneva, Zinc and Cardiovascular Disease, Nutrition, 2010, 26(11–12), p 1050–1057. https://doi.org/10.1016/j.nut.2010.03.00710.1016/j.nut.2010.03.007 ↗
9. E. Mostaed, M. Sikora-Jasinska, J.W. Drelich, and M. Vedani, Zinc-Based Alloys for Degradable Vascular Stent Applications, Acta Biomater., 2018, 71, p 1–23. https://doi.org/10.1016/j.actbio.2018.03.00510.1016/j.actbio.2018.03.005 ↗
10. Y. Chen, Z. Xu, C. Smith, and J. Sankar, Recent Advances on the Development of Magnesium Alloys for Biodegradable Implants, Acta Biomater., 2014, 10(11), p 4561–4573. https://doi.org/10.1016/j.actbio.2014.07.00510.1016/j.actbio.2014.07.005 ↗
11. M. Balog, A.M.H. Ibrahim, P. Krizik, O. Bajana, A. Klimova, A. Catic, and Z. Schauperl, Bioactive Ti + Mg Composites Fabricated by Powder Metallurgy: The Relation Between the Microstructure and Mechanical Properties, J. Mech. Behav. Biomed. Mater., 2019, 90(October 2018), p 45–53. https://doi.org/10.1016/j.jmbbm.2018.10.00810.1016/j.jmbbm.2018.10.008 ↗
12. I. Matuła, G. Dercz, M. Zubko, K. Prusik, and L. Pająk, Influence of High Energy Milling Time on the Ti-50Ta Biomedical Alloy Structure, Acta Phys. Pol. A, 2016, 130(4), p 1033–1036. https://doi.org/10.12693/APhysPolA.130.103310.12693/APhysPolA.130.1033 ↗
13. G. Chen, J. Yin, S. Zhao, H. Tang, and X. Qu, Microstructure and Tensile Properties of a Ti-28Ta Alloy Studied by Transmission Electron Microscopy and Digital Image Correlation, Int. J. Refract. Met. Hard Mater., 2019, 81(February), p 71–77. https://doi.org/10.1016/j.ijrmhm.2019.02.02010.1016/j.ijrmhm.2019.02.020 ↗
14. Y. Liu, K. Li, H. Wu, M. Song, W. Wang, N. Li, and H. Tang, Synthesis of Ti–Ta Alloys with Dual Structure by Incomplete Diffusion Between Elemental Powders, J. Mech. Behav. Biomed. Mater., 2015, 51, p 302–312. https://doi.org/10.1016/j.jmbbm.2015.07.00410.1016/j.jmbbm.2015.07.004 ↗
15. S. Xu, Y. Liu, C. Yang, H. Zhao, B. Liu, J. Li, and M. Song, Compositionally Gradient Ti-Ta Metal-Metal Composite with Ultra-High Strength, Mater. Sci. Eng. A, 2017, 2018(712), p 386–393. https://doi.org/10.1016/j.msea.2017.11.08910.1016/j.msea.2017.11.089 ↗
16. Y.L. Zhou, M. Niinomi, and T. Akahori, Effects of Ta Content on Young’s Modulus and Tensile Properties of Binary Ti–Ta Alloys for Biomedical Applications, Mater. Sci. Eng. A, 2004, 371(1–2), p 283–290. https://doi.org/10.1016/j.msea.2003.12.01110.1016/j.msea.2003.12.011 ↗
17. S.L. Sing, W.Y. Yeong, and F.E. Wiria, Selective Laser Melting of Titanium Alloy with 50 Wt% Tantalum: Microstructure and Mechanical Properties, J. Alloys Compd., 2016, 660, p 461–470. https://doi.org/10.1016/j.jallcom.2015.11.14110.1016/j.jallcom.2015.11.141 ↗
18. A. Bahador, S. Kariya, J. Umeda, E. Hamzah, and K. Kondoh, Tailoring Microstructure and Properties of a Superelastic Ti-Ta Alloy by Incorporating Spark Plasma Sintering with Thermomechanical Processing, J. Mater. Eng. Perform., 2019, 28(5), p 3012–3020. https://doi.org/10.1007/s11665-019-04061-810.1007/s11665-019-04061-8 ↗
19. Y.-L. Zhou and M. Niinomi, Ti-25Ta Alloy with the Best Mechanical Compatibility in Ti-Ta Alloys for Biomedical Applications, Mater. Sci. Eng. C, 2009, 29(3), p 1061–1065. https://doi.org/10.1016/j.msec.2008.09.01210.1016/j.msec.2008.09.012 ↗
20. G. Dercz, I. Matuła, M. Zubko, A. Kazek-Kęsik, J. Maszybrocka, W. Simka, J. Dercz, P. Świec, and I. Jendrzejewska, Synthesis of Porous Ti-50Ta Alloy by Powder Metallurgy, Mater. Charact., 2018, 142(October 2017), p 124–136. https://doi.org/10.1016/j.matchar.2018.05.03310.1016/j.matchar.2018.05.033 ↗
21. J. Kesteven, M.B. Kannan, R. Walter, H. Khakbaz, and H.-C. Choe, Low Elastic Modulus Ti–Ta Alloys for Load-Bearing Permanent Implants: Enhancing the Biodegradation Resistance by Electrochemical Surface Engineering, Mater. Sci. Eng. C, 2015, 46, p 226–231. https://doi.org/10.1016/j.msec.2014.10.03810.1016/j.msec.2014.10.038 ↗
22. W. Wei, S. Berger, N. Shrestha, and P. Schmuki, Ideal Hexagonal Order: Formation of Self-Organized Anodic Oxide Nanotubes and Nanopores on a Ti-35Ta Alloy, J. Electrochem. Soc., 2010, 157(12), p C409. https://doi.org/10.1149/1.349042410.1149/1.3490424 ↗
23. W.G. Kim, H.C. Choe, and Y.M. Ko, Electrochemical Characteristics of Osteoblast Cultured Ti-Ta Alloy for Dental Implant, J. Korean Inst. Surf. Eng., 2008, 41(2), p 69–75. https://doi.org/10.5695/JKISE.2008.41.2.06910.5695/JKISE.2008.41.2.069 ↗
24. Y.L. Zhou, M. Niinomi, T. Akahori, H. Fukui, and H. Toda, Corrosion Resistance and Biocompatibility of Ti-Ta Alloys for Biomedical Applications, Mater. Sci. Eng. A, 2005, 398(1–2), p 28–36. https://doi.org/10.1016/j.msea.2005.03.03210.1016/j.msea.2005.03.032 ↗
25. D. Mareci, R. Chelariu, D.-M. Gordin, G. Ungureanu, and T. Gloriant, Comparative Corrosion Study of Ti-Ta Alloys for Dental Applications, Acta Biomater., 2009, 5(9), p 3625–3639. https://doi.org/10.1016/j.actbio.2009.05.03710.1016/j.actbio.2009.05.037 ↗
26. N. Soro, H. Attar, E. Brodie, M. Veidt, A. Molotnikov, and M.S. Dargusch, Evaluation of the Mechanical Compatibility of Additively Manufactured Porous Ti–25Ta Alloy for Load-Bearing Implant Applications, J. Mech. Behav. Biomed. Mater., 2019, 97(May), p 149–158. https://doi.org/10.1016/j.jmbbm.2019.05.01910.1016/j.jmbbm.2019.05.019 ↗
27. N. Taniguchi, S. Fujibayashi, M. Takemoto, K. Sasaki, B. Otsuki, T. Nakamura, T. Matsushita, T. Kokubo, and S. Matsuda, Effect of Pore Size on Bone Ingrowth into Porous Titanium Implants Fabricated by Additive Manufacturing: An in Vivo Experiment, Mater. Sci. Eng. C, 2016, 59, p 690–701. https://doi.org/10.1016/j.msec.2015.10.06910.1016/j.msec.2015.10.069 ↗
28. Y.Q. Ma, W.J. Jin, S.Y. Yang, J. Bin Zhang, Y.X. Huang, and X.J. Liu, Microstructure and Shape Memory Properties of Biomedical Ti-(40–65) Ta (Wt.%) Alloys, Mater. Sci. Forum, 2009, 610–613, p 1382–1386. https://doi.org/10.4028/www.scientific.net/MSF.610-613.138210.4028/www.scientific.net/MSF.610-613.1382 ↗
29. M. Sopata, T.M. Karpiński, J. Jakubowicz, and M. Sopata, Development of Tantalum with Highly Hydrophilic Surface and Antimicrobial Properties Obtained by Micro-arc Oxidation Process, J. Biomed. Mater. Res. B Appl. Biomater., 2021, 109(6), p 829–840. https://doi.org/10.1002/jbm.b.3474810.1002/jbm.b.34748 ↗
30. M.P. Staiger, A.M. Pietak, J. Huadmai, and G. Dias, Magnesium and Its Alloys as Orthopedic Biomaterials: A Review, Biomaterials, 2006, 27(9), p 1728–1734. https://doi.org/10.1016/j.biomaterials.2005.10.00310.1016/j.biomaterials.2005.10.003 ↗
31. J. Wang, L. Liu, Y. Wu, M.F. Maitz, Z. Wang, Y. Koo, A. Zhao, J. Sankar, D. Kong, N. Huang, and Y. Yun, Ex Vivo Blood Vessel Bioreactor for Analysis of the Biodegradation of Magnesium Stent Models With and Without Vessel Wall Integration, Acta Biomater., 2017, 50, p 546–555. https://doi.org/10.1016/j.actbio.2016.12.03910.1016/j.actbio.2016.12.039 ↗
32. D.M.J. Wilkes, P.S. Goodwin, C.M. Ward-Close, K. Bagnall, and J. Steeds, Solid Solution of Mg in Ti by Mechanical Alloying, Mater. Lett., 1996, 27(1–2), p 47–52. https://doi.org/10.1016/0167-577X(95)00265-010.1016/0167-577X(95)00265-0 ↗
33. C.M. Ward-Close and P.G. Partridge, The Production of Titanium-Magnesium Alloys by Vapour Quenching, Mater. Lett., 1991, 11(8–9), p 295–300. https://doi.org/10.1016/0167-577X(91)90206-L10.1016/0167-577X(91)90206-L ↗
34. J.L. Murray, The Mg-Ti (Magnesium-Titanium) System, Bull. Alloy Phase Diagr., 1986, 7(3), p 245–248. https://doi.org/10.1007/BF0286899910.1007/BF02868999 ↗
35. G. Liang and R. Schulz, Synthesis of Mg-Ti Alloy by Mechanical Alloying, J. Mater. Sci., 2003, 38, p 1179–1184. https://doi.org/10.1023/A:102288910036010.1023/A:1022889100360 ↗
36. C. Suryanarayana and F.H. Froes, Nanocrystalline Titanium-Magnesium Alloys Through Mechanical Alloying, J. Mater. Res., 1990, 5(9), p 1880–1886. https://doi.org/10.1557/JMR.1990.188010.1557/JMR.1990.1880 ↗
37. R.H. Taylor, S. Curtarolo, and G.L.W. Hart, Guiding the Experimental Discovery of Magnesium Alloys, Phys. Rev. B, 2011, 84(8), p 084101. https://doi.org/10.1103/PhysRevB.84.08410110.1103/PhysRevB.84.084101 ↗
38. R.M. German, P. Suri, and S.J. Park, Review: Liquid Phase Sintering, J. Mater. Sci., 2009, 44(1), p 1–39. https://doi.org/10.1007/s10853-008-3008-010.1007/s10853-008-3008-0 ↗
39. G. Adamek, M. Kozlowski, M. Jurczyk, P. Wirstlein, J. Zurawski, and J. Jakubowicz, Formation and Properties of Biomedical Ti-Ta Foams Prepared from Nanoprecursors by Thermal Dealloying Process, Materials, 2019, 12(17), p 2668. https://doi.org/10.3390/ma1217266810.3390/ma12172668 ↗
40. H. Okamoto, Ti-Zn (Titanium-Zinc), J. Phase Equilibria Diffus., 2008, 29(2), p 211–212. https://doi.org/10.1007/s11669-008-9271-610.1007/s11669-008-9271-6 ↗
41. M.H. Qi, J.L. Xu, T. Lai, J. Huang, Y.C. Ma, J.M. Luo, and Y.F. Zheng, Novel Bioactive Ti-Zn Alloys with High Strength and Low Modulus for Biomedical Applications, J. Alloys Compd., 2023, 931, p 167555. https://doi.org/10.1016/j.jallcom.2022.16755510.1016/j.jallcom.2022.167555 ↗
42. A.J. Drelich, S. Zhao, R.J. Guillory, J.W. Drelich, and J. Goldman, Long-Term Surveillance of Zinc Implant in Murine Artery: Surprisingly Steady Biocorrosion Rate, Acta Biomater., 2017, 58, p 539–549. https://doi.org/10.1016/j.actbio.2017.05.04510.1016/j.actbio.2017.05.045 ↗
43. H. Yang, C. Wang, C. Liu, H. Chen, Y. Wu, J. Han, Z. Jia, W. Lin, D. Zhang, W. Li, W. Yuan, H. Guo, H. Li, G. Yang, D. Kong, D. Zhu, K. Takashima, L. Ruan, J. Nie, X. Li, and Y. Zheng, Evolution of the Degradation Mechanism of Pure Zinc Stent in the One-Year Study of Rabbit Abdominal Aorta Model, Biomaterials, 2017, 145, p 92–105. https://doi.org/10.1016/j.biomaterials.2017.08.02210.1016/j.biomaterials.2017.08.022 ↗
44. J. Venezuela and M.S. Dargusch, The Influence of Alloying and Fabrication Techniques on the Mechanical Properties, Biodegradability and Biocompatibility of Zinc: A Comprehensive Review, Acta Biomater., 2019, 87, p 1–40. https://doi.org/10.1016/j.actbio.2019.01.03510.1016/j.actbio.2019.01.035 ↗
45. D. Vojtěch, J. Kubásek, J. Šerák, and P. Novák, Mechanical and Corrosion Properties of Newly Developed Biodegradable Zn-Based Alloys for Bone Fixation, Acta Biomater., 2011, 7(9), p 3515–3522. https://doi.org/10.1016/j.actbio.2011.05.00810.1016/j.actbio.2011.05.008 ↗
46. G. Li, H. Yang, Y. Zheng, X.-H. Chen, J.-A. Yang, D. Zhu, L. Ruan, and K. Takashima, Challenges in the Use of Zinc and Its Alloys as Biodegradable Metals: Perspective from Biomechanical Compatibility, Acta Biomater., 2019, 97(5), p 23–45. https://doi.org/10.1016/j.actbio.2019.07.03810.1016/j.actbio.2019.07.038 ↗
47. F. Witte, H. Ulrich, M. Rudert, and E. Willbold, Biodegradable Magnesium Scaffolds: Part 1: Appropriate Inflammatory Response, J. Biomed. Mater. Res. A, 2007, 81A(3), p 748–756. https://doi.org/10.1002/jbm.a.3117010.1002/jbm.a.31170 ↗
48. K. Kaur, R. Gupta, S.A. Saraf, and S.K. Saraf, Zinc: The Metal of Life, Compr. Rev. Food Sci. Food Saf., 2014, 13(4), p 358–376. https://doi.org/10.1111/1541-4337.1206710.1111/1541-4337.12067 ↗
49. A.S. Prasad, B. Bao, F.W.J. Beck, and F.H. Sarkar, Zinc Enhances the Expression of Interleukin-2 and Interleukin-2 Receptors in HUT-78 Cells by Way of NF-ΚB Activation, J. Lab. Clin. Med., 2002, 140(4), p 272–289. https://doi.org/10.1067/mlc.2002.12790810.1067/mlc.2002.127908 ↗
50. J. Jakubowcz, G. Adamek, M. Sopata, J.K. Kope, and P. Siwak, Hot Pressing of Nanocrystalline Tantalum Using High Frequency Induction Heating and Pulse Plasma Sintering, IOP Conf. Ser. Mater. Sci. Eng., 2017, 283(1), p 012001. https://doi.org/10.1088/1757-899X/283/1/01200110.1088/1757-899X/283/1/012001 ↗
51. H. Yu, J. Zhou, R. Wang, Q. Su, S. Zhang, J. Wu, X. Wang, and L. Hu, Effects of Hot Pressing Temperature and Annealing Temperature on Microstructure and Compressive Properties of a Bulk Nanocrystalline AZ61 Magnesium Alloy Contain Ti, J. Alloys Compd., 2021, 888, p 161533. https://doi.org/10.1016/j.jallcom.2021.16153310.1016/j.jallcom.2021.161533 ↗
52. Standard ISO 14577-1:2015. Metallic Materials-Instrumented Indentation Test for Hardness and Materials Parameters—Part 1: Test Method, International Organization for Standardization, (Geneva, Switzerland), 2015.
53. P. Salwa and T. Goryczka, Influence of Milling Time on Formation of NiTi Alloy Produced by High-Energy Ball Milling, Arch. Metall. Mater., 2019 https://doi.org/10.24425/amm.2019.12948910.24425/amm.2019.129489 ↗
54. A. Şelte and B. Özkal, Crystallite Size and Strain Calculations of Hard Particle Reinforced Composite Powders (Cu/Ni/Fe–WC) Synthesized via Mechanical Alloying, Proc. Est. Acad. Sci., 2019, 68(1), p 66–78. https://doi.org/10.3176/proc.2019.1.0210.3176/proc.2019.1.02 ↗
55. P. Sochacka, A. Miklaszewski, and M. Jurczyk, Development of β-Type Ti-x at.% Mo Alloys by Mechanical Alloying and Powder Metallurgy: Phase Evolution and Mechanical Properties (10 ≤ x ≤ 35), J. Alloys Compd., 2019, 776, p 370–378. https://doi.org/10.1016/j.jallcom.2018.10.21710.1016/j.jallcom.2018.10.217 ↗
56. V. Mote, Y. Purushotham, and B. Dole, Williamson–Hall Analysis in Estimation of Lattice Strain in Nanometer-Sized ZnO Particles, J. Theor. Appl. Phys., 2012, 6(1), p 6. https://doi.org/10.1186/2251-7235-6-610.1186/2251-7235-6-6 ↗
57. M. Rabiei, A. Palevicius, A. Monshi, S. Nasiri, A. Vilkauskas, and G. Janusas, Comparing Methods for Calculating Nano Crystal Size of Natural Hydroxyapatite Using X-Ray Diffraction, Nanomaterials, 2020, 10(9), p 1627. https://doi.org/10.3390/nano1009162710.3390/nano10091627 ↗
58. B.W. Levinger, Lattice Parameter of Beta Titanium at Room Temperature, JOM, 1953, 5(2), p 195–195. https://doi.org/10.1007/BF0339747410.1007/BF03397474 ↗
59. J. Zemann, Crystal Structures, Acta Crystallogr., 1965, 18(1), p 139–139. https://doi.org/10.1107/s0365110x6500036110.1107/s0365110x65000361 ↗
60. J.C. Slater, Atomic Radii in Crystals, J. Chem. Phys., 1964, 41(10), p 3199–3204. https://doi.org/10.1063/1.172569710.1063/1.1725697 ↗
61. J. Hieda, M. Niinomi, M. Nakai, and K. Cho, In Vitro Biocompatibility of Ti-Mg Alloys Fabricated by Direct Current Magnetron Sputtering, Mater. Sci. Eng. C, 2015, 54, p 1–7. https://doi.org/10.1016/j.msec.2015.04.02910.1016/j.msec.2015.04.029 ↗
62. A.S. Gornakova, A.B. Straumal, I.I. Khodos, I.B. Gnesin, A.A. Mazilkin, N.S. Afonikova, and B.B. Straumal, Effect of Composition, Annealing Temperature, and High Pressure Torsion on Structure and Hardness of Ti-V and Ti-V-Al Alloys, J. Appl. Phys., 2019, 125(8), p 082522. https://doi.org/10.1063/1.505393710.1063/1.5053937 ↗
63. A.S. Gornakova, S.I. Prokofiev, B.B. Straumal, and K.I. Kolesnikova, Growth of (ΑTi) Grain-Boundary Layers in Ti-Co Alloys, Russ. J. Non-Ferr. Met., 2016, 57(7), p 703–709. https://doi.org/10.3103/S106782121607009910.3103/S1067821216070099 ↗
64. A.S. Gornakova, S.I. Prokofiev, K.I. Kolesnikova, and B.B. Straumal, Formation Regularities of Grain-Boundary Interlayers of the α-Ti Phase in Binary Titanium Alloys, Russ. J. Non-Ferr. Met., 2016, 57(3), p 229–235. https://doi.org/10.3103/S106782121603007X10.3103/S106782121603007X ↗
65. B.B. Straumal, A.R. Kilmametov, Yu. Ivanisenko, A.S. Gornakova, A.A. Mazilkin, M.J. Kriegel, O.B. Fabrichnaya, B. Baretzky, and H. Hahn, Phase Transformations in Ti-Fe Alloys Induced by High-Pressure Torsion, Adv. Eng. Mater., 2015, 17(12), p 1835–1841. https://doi.org/10.1002/adem.20150014310.1002/adem.201500143 ↗
66. S. Mendis, W. Xu, H.P. Tang, L.A. Jones, D. Liang, R. Thompson, P. Choong, M. Brandt, and M. Qian, Characteristics of Oxide Films on Ti-(10-75)Ta Alloys and Their Corrosion Performance in an Aerated Hank’s Balanced Salt Solution, Appl Surf Sci, 2020, 506(November 2019), p 145013. https://doi.org/10.1016/j.apsusc.2019.14501310.1016/j.apsusc.2019.145013 ↗
67. Y. Liu, K. Li, T. Luo, M. Song, H. Wu, J. Xiao, Y. Tan, M. Cheng, B. Chen, X. Niu, R. Hu, X. Li, and H. Tang, Powder Metallurgical Low-Modulus Ti-Mg Alloys for Biomedical Applications, Mater. Sci. Eng. C, 2015, 56, p 241–250. https://doi.org/10.1016/j.msec.2015.06.01010.1016/j.msec.2015.06.010 ↗
68. S. Minagar, C. Berndt, and C. Wen, Fabrication and Characterization of Nanoporous Niobia, and Nanotubular Tantala, Titania and Zirconia via Anodization, J. Funct. Biomater., 2015, 6(2), p 153–170. https://doi.org/10.3390/jfb602015310.3390/jfb6020153 ↗
69. C.P. Hao, N.J. Cao, Y.H. Zhu, and W. Wang, The Osseointegration and Stability of Dental Implants with Different Surface Treatments in Animal Models: A Network Meta-Analysis, Sci. Rep., 2021, 11(1), p 1–12. https://doi.org/10.1038/s41598-021-93307-410.1038/s41598-021-93307-4 ↗
70. M. Ferrari, F. Cirisano, and M.C. Morán, Mammalian Cell Behavior on Hydrophobic Substrates: Influence of Surface Properties, Colloids Interfaces, 2019, 3(2), p 48. https://doi.org/10.3390/colloids302004810.3390/colloids3020048 ↗
71. H. Garbacz, P. Wieciński, D. Kuczyńska, D. Kubacka, and K.J. Kurzydłowski, The Effect of Grain Size on the Surface Properties of Titanium Grade 2 after Different Treatments, Surf. Coat. Technol., 2018, 335(December 2017), p 13–24. https://doi.org/10.1016/j.surfcoat.2017.12.00510.1016/j.surfcoat.2017.12.005 ↗
72. X.H. Wu, Y.K. Liew, C.-W. Mai, and Y.Y. Then, Potential of Superhydrophobic Surface for Blood-Contacting Medical Devices, Int. J. Mol. Sci., 2021, 22(7), p 3341. https://doi.org/10.3390/ijms2207334110.3390/ijms22073341 ↗
73. J. Jakubowicz, G. Adamek, and L. Smardz, Porous Surface State Analysis of Anodized Titanium for Biomedical Applications, Metall. Mater. Trans. A, 2022, 53(1), p 86–94. https://doi.org/10.1007/s11661-021-06492-210.1007/s11661-021-06492-2 ↗
74. N. Baig, I. Kammakakam, and W. Falath, Nanomaterials: A Review of Synthesis Methods, Properties, Recent Progress, and Challenges, Mater. Adv., 2021, 2(6), p 1821–1871. https://doi.org/10.1039/D0MA00807A10.1039/D0MA00807A ↗
75. C.A. Charitidis, P. Georgiou, M.A. Koklioti, A.-F. Trompeta, and V. Markakis, Manufacturing Nanomaterials: From Research to Industry, Manuf. Rev. (Les Ulis), 2014, 1, p 11. https://doi.org/10.1051/mfreview/201400910.1051/mfreview/2014009 ↗
76. M. Long and H.J. Rack, Titanium Alloys in Total Joint Replacement—A Materials Science Perspective, Biomaterials, 1998, 19(18), p 1621–1639. https://doi.org/10.1016/S0142-9612(97)00146-410.1016/S0142-9612(97)00146-4 ↗
77. M. Marczewski, A. Miklaszewski, and M. Jurczyk, Structure Evolution Analysis in Ultrafine-Grained Zr and Nb-Based Beta Titanium Alloys, J. Alloys Compd., 2018, 765, p 459–469. https://doi.org/10.1016/j.jallcom.2018.06.22410.1016/j.jallcom.2018.06.224 ↗
78. M. Marczewski, A. Miklaszewski, X. Maeder, and M. Jurczyk, Crystal Structure Evolution, Microstructure Formation, and Properties of Mechanically Alloyed Ultrafine-Grained Ti-Zr-Nb Alloys at 36 ≤ Ti ≤ 70 (at.%), Materials, 2020, 13(3), p 87. https://doi.org/10.3390/ma1303058710.3390/ma13030587 ↗