journal article·2025-01

Effect of Nano WC on Wear and Corrosion Resistances of CoCrFeNiTi High Entropy Alloy Coating

Juncheng Wang, Jiao Man, Qingtian Wang, Genggen Liu, Shichen Xiao, Ning Dong

Publisher page

Abstract

The CoCrFeNiTi high-entropy alloy exhibits outstanding comprehensive performance, rendering it suitable for surface protective coatings on critical equipment components. To further enhance its performance, a mechanical powder mixing approach was utilized to pre-process CoCrFeNiTi and CoCrFeNiTi + WC (5% mass fraction) high-entropy alloy powders. These powders were subsequently laser-cladded onto 45# steel substrates, enabling a comparative investigation into the microstructure, mechanical properties, and corrosion resistance of the two coatings. The results distinctly highlight the superiority of the CoCrFeNiTi + WC (5%) coating: the average microhardness increased from 750 to 900 HV. In friction and wear tests, the coefficient of friction decreased from 0.75 to 0.68, resulting in a reduction of wear by 0.82 mg, representing the least amount of wear. Electrochemical examinations revealed an elevation of the self-corrosion potential by 0.039 V and a magnitude decrease in self-corrosion current density. Notably, a significant reduction in surface corrosion pits was observed, indicating the mildest degree of corrosion. The incorporation of nano-sized WC effectively enhances the wear and corrosion resistance of the CoCrFeNiTi high-entropy alloy coating.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Advanced materials and composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, C.H. Tsau, and S.Y. Chang, Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes, Adv. Eng. Mater., 2004, 6, p 299–303.10.1002/adem.200300567 ↗
2. H. Yao, K. Chen, K. Kondoh, X. Dong, M. Wang, X. Hua, and A. Shan, Microstructure and Mechanical Properties of Friction Stir Lap Welds Between FeCoCrNiMn High Entropy Alloy and 6061 Al Alloy, Mater. Des., 2022, 224, p 111411.10.1016/j.matdes.2022.111411 ↗
3. O. Samoilova, N. Shaburova, A.O. Moghaddam, and E. Trofimov, Al0.25CoCrFeNiSi0.6 High Entropy Alloy with High Hardness and Improved Wear Resistance, Mater. Lett., 2022, 328, p 133190.10.1016/j.matlet.2022.133190 ↗
4. M. Karimzadeh, M. Malekan, H. Mirzadeh, L. Li, and N. Saini, Effects of Titanium Addition on the Microstructure and Mechanical Properties of Quaternary CoCrFeNi High Entropy Alloy, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 2022, 856, p 143971.10.1016/j.msea.2022.143971 ↗
5. T. Wang, C. Wang, J. Li, L. Chai, C. Deng, J. Luo, and Y. Huang, Microstructure and Properties of Laser-Clad High Entropy Alloy Coating on Inconel 718 Alloy, Mater Charact, 2022, 193, p 112314.10.1016/j.matchar.2022.112314 ↗
6. K. Kuwabara, T. Kimura, M. Chen, H. Shiratori, K. Shinagawa, and Y. Daigo, Microstructural Transformation and Corrosion Property Improvement of CoCrFeNiTi-Based Multi-Principal Element Alloys Fabricated via Laser Powder Bed Fusion, Adv. Eng. Mater., 2022, 24, p 2101272.10.1002/adem.202101272 ↗
7. Q. Lu, X. Chen, W. Tian, H. Wang, P. Liu, H. Zhou, S. Fu, Y. Gao, M. Wan, and X. Wang, Corrosion Behavior of a Non-equiatomic CoCrFeNiTi High-Entropy alloy: A Comparison with 304 Stainless Steel in Simulated Body Fluids, J. Alloy. Compd., 2022, 897, p 163036.10.1016/j.jallcom.2021.163036 ↗
8. H. Liu, W. Gao, J. Liu, X. Du, X. Li, and H. Yang, Microstructure and Properties of CoCrFeNiTi High-Entropy Alloy Coating Fabricated by Laser Cladding, J. Mater. Eng. Perform., 2020, 29, p 7170–7178.10.1007/s11665-020-05204-y ↗
9. Y. Gao, H. Chen, J. Zhou, W. Tian, H. Nie, W. Wang, and J. Liang, Microstructures and Wear Behaviors of WC Particle Reinforced Nickel-Based Composites Fabricated by Selective Laser Melting, J. Manuf. Process., 2023, 95, p 291–301.10.1016/j.jmapro.2023.03.075 ↗
10. K. Zhang, H. Ju, F. Xing, W. Wang, Q. Li, X. Yu, and W. Liu, Microstructure and Properties of Composite Coatings by Laser Cladding Inconel 625 and Reinforced WC Particles on Non-magnetic Steel, Opt. Laser Technol., 2023, 163, p 109321.10.1016/j.optlastec.2023.109321 ↗
11. Q. Ma, Y. Li, J. Wang, and K. Liu, Microstructure Evolution and Growth Control of Ceramic Particles in Wide-Band Laser Clad Ni60/WC Composite Coatings, Mater. Des., 2016, 92, p 897–905.10.1016/j.matdes.2015.12.121 ↗
12. X.H. Wang, M. Zhang, B.S. Du, and S. Li, Microstructure and Wear Properties of Laser Clad TiB2 + TiC/Fe Composite Coating, Surf. Rev. Lett., 2012, 19, p 1250052.10.1142/S0218625X12500527 ↗
13. W. Zhang, M. Zhang, Y. Peng, L. Wang, Y. Liu, S. Hu, and Y. Hu, Interfacial Structures and Mechanical Properties of a High Entropy Alloy-Diamond Composite, Int. J. Refract. Met. Hard Mat., 2020, 86, p 105109.10.1016/j.ijrmhm.2019.105109 ↗
14. M. Ren, R. Li, X. Zhang, J. Gu, and C. Jiao, Effect of WC Particles Preparation Method on Microstructure and Properties of Laser Cladded Ni60-WC Coatings, J. Mater. Res. Technol-JMRT, 2023, 22, p 605–616.10.1016/j.jmrt.2022.11.120 ↗
15. J. Xia, Y. Feng, Z. Ling, and K. Wang, Influence of WC Particle Content of Fe-Based Powder-Cored Wire on Microstructure and Properties of Plasma Cladding Reinforced Layers, J. Alloy. Compd., 2022, 922, p 166148.10.1016/j.jallcom.2022.166148 ↗
16. S. Zhang, C.L. Wu, J.Z. Yi, and C.H. Zhang, Synthesis and Characterization of FeCoCrAlCu High-Entropy Alloy Coating by Laser Surface Alloying, Surf. Coat. Technol., 2015, 262, p 64–69.10.1016/j.surfcoat.2014.12.013 ↗
17. Z. Peng, Z. Fan, M.R. Abdullah, C. Ren, J. Li, and P. Gong, Corrosion Resistance Enhancement of CoCrFeMnNi High-Entropy Alloy with WC Particle Reinforcements via Laser Melting Deposition, Materials, 2023, 16, p 4701.10.3390/ma16134701 ↗
18. A. Vyas, J. Menghani, and H. Natu, Influence of WC Particle on the Metallurgical, Mechanical, and Corrosion Behavior of AlFeCuCrCoNi-WCx High-Entropy Alloy Coatings, J. Mater. Eng. Perform., 2021, 30, p 2449–2461.10.1007/s11665-021-05523-8 ↗
19. X. Wang, Q. Liu, Y. Huang, L. Xie, Q. Xu, and T. Zhao, Effect of Ti Content on the Microstructure and Corrosion Resistance of CoCrFeNiTix High Entropy Alloys Prepared by Laser Cladding, Materials, 2020, 13, p 2209.10.3390/ma13102209 ↗
20. Y. Li, Y. Hu, D. Zhang, and W. Cong, Laser Remelting of CoCrFeNiTi High Entropy Alloy Coatings Fabricated by Directed Energy Deposition: Effects of Remelting Laser Power, Opt. Laser Technol., 2023, 158, p 108871.10.1016/j.optlastec.2022.108871 ↗
21. D. Li, K. Chen, X. Fu, and Z. Hua, Effect of WC Content on Microstructure and Properties of CrFeMoNiTi(WC)(x) High-Entropy Alloys Composite Coatings Prepared by Selective Laser Melting, Mater. Corros., 2022, 73, p 1676–1686.10.1002/maco.202213228 ↗
22. R. Zhou, G. Chen, B. Liu, J. Wang, L. Han, and Y. Liu, Microstructures and Wear Behaviour of (FeCoCrNi)(1–x)(WC)(x) High Entropy Alloy Composites, Int. J. Refract. Met. Hard Mat., 2018, 75, p 56–62.10.1016/j.ijrmhm.2018.03.019 ↗
23. S. Gorsse, M.H. Nguyen, O.N. Senkov, and D.B. Miracle, database on the Mechanical Properties of High Entropy Alloys and Complex Concentrated Alloys, Data Brief, 2020, 32, p 2664–2678.10.1016/j.dib.2020.106216 ↗
24. C. Shang, E. Axinte, W. Ge, Z. Zhang, and Y. Wang, High-Entropy Alloy Coatings with Excellent Mechanical, Corrosion Resistance and Magnetic Properties Prepared by Mechanical Alloying and Hot Pressing Sintering, Surf. Interfaces, 2017, 9, p 36–43.10.1016/j.surfin.2017.06.012 ↗
25. Q. Fan, C. Chen, C. Fan, Z. Liu, X. Cai, S. Lin, and C. Yang, Ultrasonic Induces Grain Refinement in Gas Tungsten Arc Cladding AlCoCrFeNi High-Entropy Alloy Coatings, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 2021, 821, p 141607.10.1016/j.msea.2021.141607 ↗
26. D.H. Jeong, U. Erb, K.T. Aust, and G. Palumbo, The Relationship Between Hardness and Abrasive Wear Resistance of Electrodeposited Nanocrystalline Ni-P Coatings, Scr. Mater., 2003, 48, p 1067–1072.10.1016/S1359-6462(02)00633-4 ↗
27. D.H. Jeong, F. Gonzalez, G. Palumbo, K.T. Aust, and U. Erb, The Effect of Grain Size on the Wear Properties of Electrodeposited Nanocrystalline Nickel Coatings, Scr. Mater., 2001, 44, p 493–499.10.1016/S1359-6462(00)00625-4 ↗
28. H. Luo, X. Wang, C. Dong, K. Xiao, and X. Li, Effect of Cold Deformation on the Corrosion Behaviour of UNS S31803 Duplex Stainless Steel in Simulated Concrete Pore Solution, Corrosion Sci., 2017, 124, p 178–192.10.1016/j.corsci.2017.05.021 ↗
29. Y.L. Chou, J.W. Yeh, and H.C. Shih, The Effect of Molybdenum on the Corrosion Behaviour of the High-Entropy Alloys Co1.5CrFeNi1.5Ti0.5Mox in Aqueous Environments, Corrosion Sci., 2010, 52, p 2571–2581.10.1016/j.corsci.2010.04.004 ↗
30. M. Laleh, A.E. Hughes, W. Xu, I. Gibson, and M.Y. Tan, Unexpected Erosion-Corrosion Behaviour of 316L Stainless Steel Produced by Selective Laser Melting, Corrosion Sci., 2019, 155, p 67–74.10.1016/j.corsci.2019.04.028 ↗